nach oben

Polymer Bulletin

Erschienen in:

01.01.2012 | Original paper

The preparation of carbon nanotube/poly(ethylene oxide) composites using amphiphilic block copolymers

verfasst von: Chantal Semaan, Gilles Pecastaings, Michèle Schappacher, Alain Soum

Erschienen in: Polymer Bulletin | Ausgabe 2/2012

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Polymer/multiwall carbon nanotube (MWCNT) composites were prepared by using amphiphilic block copolymers as dispersant. First, MWCNTs were wrapped with amphiphilic block copolymers in aqueous solution. Poly(ethylene oxide) was selected as the hydrophilic block because of its strong affinity with water while one of the following polymers: poly(ethylene), poly(butadiene), poly(styrene), poly(propylene oxide), or poly(thiophene) was used as the hydrophobic block of the copolymers. The dispersions were characterized by optical microscopy and transmission electron microscopy along with UV–Visible adsorption and dynamic light scattering. Based on the results, we could assess the effect on CNT dispersion quality of both, the molar mass of copolymers, the nature of the hydrophobic block and the length of hydrophilic block. The crystallization behavior of composites prepared from these dispersions was investigated. Results were related to the dispersion of the nanoparticles in the polymer matrix.

Vorheriger Artikel Synthesis and properties of 2-(10,11-dihydrodibenz[b,f]azepine-5-yl)carbazole-based monomers and polymers

Nächster Artikel Preparation and properties of polyethylene-octene elastomer (POE)/organoclay nanocomposites

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Iijima S (1991) Helical microtubules of graphitic carbon. Nature 354:56–58CrossRef

Poncharal P, Wang ZL, Ugarte D, de Heer WA (1999) Electrostatic deflections and electromechanical resonances of carbon nanotubes. Science 283(5407):1513–1516. doi:10.1126/science.283.5407.1513 CrossRef

Collins PG, Avouris P (2000) Nanotubes for electronics. Sci Am 283(6):62–69CrossRef

Pan X, Fan Z, Chen W, Ding Y, Luo H, Bao X (2007) Enhanced ethanol production inside carbon-nanotube reactors containing catalytic particles. Nat Mater 6(7):507–511CrossRef

Calvert P (1999) Nanotube composites: a recipe for strength. Nature 399(6733):210–211CrossRef

Steurer P, Wissert R, Thomann R, Mülhaupt R (2009) Functionalized graphenes and thermoplastic nanocomposites based upon expanded graphite oxide. Macromol Rapid Commun 30(4–5):316–327CrossRef

Wu Z, Chen Z, Du X, Logan JM, Sippel J, Nikolou M, Kamaras K, Reynolds JR, Tanner DB, Hebard AF, Rinzler AG (2004) Transparent, conductive carbon nanotube films. Science 305(5688):1273–1276. doi:10.1126/science.1101243 CrossRef

Lu F, Gu L, Meziani MJ, Wang X, Luo PG, Veca LM, Cao L, Sun Y-P (2009) Advances in bioapplications of carbon nanotubes. Adv Mater (Weinheim, Germany) 21(2):139–152CrossRef

Pastorin G (2009) Crucial functionalizations of carbon nanotubes for improved drug delivery: a valuable option? Pharm Res 26(4):746–769CrossRef

10.

Lin Y, Meziani MJ, Sun Y-P (2007) Functionalized carbon nanotubes for polymeric nanocomposites. J Mater Chem 17(12):1143–1148CrossRef

11.

Moniruzzaman M, Winey KI (2006) Polymer nanocomposites containing carbon nanotubes. Macromolecules 39(16):5194–5205. doi:10.1021/ma060733p CrossRef

12.

Besancon BM, Green PF (2005) Polystyrene-based single-walled carbon nanotube nanocomposite thin films: dynamics of structural instabilities. Macromolecules 38(1):110–115. doi:10.1021/ma049008+ CrossRef

13.

Ugur Ş, Yargi Ö, Pekcan Ö (2010) Conductivity percolation of carbon nanotubes (CNT) in polystyrene (PS) latex film. Can J Chem 88(3):267–276CrossRef

14.

Milo SP, Shaffer AHW (1999) Fabrication and characterization of carbon nanotube/poly(vinyl alcohol) composites. Adv Mater (Weinheim, Germany) 11(11):937–941CrossRef

15.

Pecastaings G, Delhaes G, Derre P, Saadaoui A, Carmona H, Cui F (2004) Role of interfacial effects in carbon nanotube/epoxy nanocomposite behavior. J Nanosci Nanotechnol 4:838–843CrossRef

16.

Chen GZ, Shaffer MSP, Coleby D, Dixon G, Zhou W, Fray DJ, Windle AH (2000) Carbon nanotube and polypyrrole composites: coating and doping. Adv Mater (Weinheim, Germany) 12(7):522–526CrossRef

17.

Chang TE, Jensen LR, Kisliuk A, Pipes RB, Pyrz R, Sokolov AP (2005) Microscopic mechanism of reinforcement in single-wall carbon nanotube/polypropylene nanocomposite. Polymer 46(2):439–444CrossRef

18.

Andreas H (2002) Functionalization of single-walled carbon nanotubes. Angew Chem 41(11):1853–1859CrossRef

19.

Barber AH, Cohen SR, Wagner HD (2003) Measurement of carbon nanotube–polymer interfacial strength. Appl Phys Lett 82(23):4140–4142CrossRef

20.

O’Connell MJ, Boul P, Ericson LM, Huffman C, Wang Y, Haroz E, Kuper C, Tour J, Ausman KD, Smalley RE (2001) Reversible water-solubilization of single-walled carbon nanotubes by polymer wrapping. Chem Phys Lett 342(3–4):265–271CrossRef

21.

Zheng M, Jagota A, Semke ED, Diner BA, McLean RS, Lustig SR, Richardson RE, Tassi NG (2003) DNA-assisted dispersion and separation of carbon nanotubes. Nat Mater 2(5):338–342CrossRef

22.

Zheng M, Jagota A, Strano MS, Santos AP, Barone P, Chou SG, Diner BA, Dresselhaus MS, McLean RS, Onoa GB, Samsonidze GG, Semke ED, Usrey M, Walls DJ (2003) Structure-based carbon nanotube sorting by sequence-dependent DNA assembly. Science 302(5650):1545–1548. doi:10.1126/science.1091911 CrossRef

23.

Kim O-K, Je J, Baldwin JW, Kooi S, Pehrsson PE, Buckley LJ (2003) Solubilization of single-wall carbon nanotubes by supramolecular encapsulation of helical amylose. J Am Chem Soc 125(15):4426–4427. doi:10.1021/ja029233b CrossRef

24.

Richard C, Balavoine F, Schultz P, Ebbesen TW, Mioskowski C (2003) Supramolecular self-assembly of lipid derivatives on carbon nanotubes. Science 300(5620):775–778. doi:10.1126/science.1080848 CrossRef

25.

Park C, Lee S, Lee JH, Lim J, Lee SC, Park M, Lee S-S, Kim J, Park CR, Kim C (2007) Controlled assembly of carbon nanotubes encapsulated with amphiphilic block copolymer. Carbon 45(10):2072–2078CrossRef

26.

Alcantar NA, Aydil ES, Israelachvili JN (2000) Polyethylene glycol-coated biocompatible surfaces. J Biomed Mater Res 51(3):343–351CrossRef

27.

Cheng J, Fernando KAS, Veca LM, Sun Y-P, Lamond AI, Lam YW, Cheng SH (2008) Reversible accumulation of PEGylated single-walled carbon nanotubes in the mammalian nucleus. ACS Nano 2(10):2085–2094. doi:10.1021/nn800461u CrossRef

28.

Aranda P, Mosqueda Y, Pérez-Cappe E, Ruiz-Hitzky E (2003) Electrical characterization of poly(ethylene oxide)-clay nanocomposites prepared by microwave irradiation. J Polym Sci Part B: Polym Phys 41(24):3249–3263CrossRef

29.

Kitiyanan B, Alvarez WE, Harwell JH, Resasco DE (2000) Controlled production of single-wall carbon nanotubes by catalytic decomposition of CO on bimetallic Co-Mo catalysts. Chem Phys Lett 317(3–5):497–503CrossRef

30.

Philippe R, Caussat B, Falqui A, Kihn Y, Kalck P, Bordère S, Plee D, Gaillard P, Bernard D, Serp P (2009) An original growth mode of MWCNTs on alumina supported iron catalysts. J Catal 263(2):345–358CrossRef

31.

Lee JU, Huh J, Kim KH, Park C, Jo WH (2007) Aqueous suspension of carbon nanotubes via non-covalent functionalization with oligothiophene-terminated poly(ethylene glycol). Carbon 45(5):1051–1057CrossRef

32.

Hou P-X, Liu C, Cheng H-M (2008) Purification of carbon nanotubes. Carbon 46(15):2003–2025CrossRef

33.

Vairavapandian D, Vichchulada P, Lay MD (2008) Preparation and modification of carbon nanotubes: review of recent advances and applications in catalysis and sensing. Anal Chim Acta 626(2):119–129CrossRef

34.

Tohji K, Takahashi H, Shinoda Y, Shimizu N, Jeyadevan B, Matsuoka I, Saito Y, Kasuya A, Ito S, Nishina Y (1997) Purification procedure for single-walled nanotubes. J Phys Chem B 101(11):1974–1978. doi:10.1021/jp962888c CrossRef

35.

Ahir SV, Huang YY, Terentjev EM (2008) Polymers with aligned carbon nanotubes: active composite materials. Polymer 49(18):3841–3854CrossRef

36.

Hilding J, Grulke EA, Zhang ZG, Lockwood F (2003) Dispersion of carbon nanotubes in liquids. J Dispersion Sci Technol 24(1):1–41CrossRef

37.

Badaire S, Poulin P, Maugey M, Zakri C (2004) In situ measurements of nanotube dimensions in suspensions by depolarized dynamic light scattering. Langmuir 20(24):10367–10370. doi:10.1021/la049096r CrossRef

38.

Kalyanasundaram K, Thomas JK (1977) Environmental effects on vibronic band intensities in pyrene monomer fluorescence and their application in studies of micellar systems. J Am Chem Soc 99(7):2039–2044. doi:10.1021/ja00449a004 CrossRef

39.

Lucas A, Zakri Cc, Maugey M, Pasquali M, Schoot Pvd, Poulin P (2009) Kinetics of nanotube and microfiber scission under sonication. J Phys Chem C 113(48):20599–20605. doi:10.1021/jp906296y CrossRef

40.

Naseh MV, Khodadadi AA, Mortazavi Y, Pourfayaz F, Alizadeh O, Maghrebi M (2010) Fast and clean functionalization of carbon nanotubes by dielectric barrier discharge plasma in air compared to acid treatment. Carbon 48(5):1369–1379CrossRef

41.

Nativ-Roth E, Shvartzman-Cohen R, Bounioux C, Florent M, Zhang D, Szleifer I, Yerushalmi-Rozen R (2007) physical adsorption of block copolymers to SWNT and MWNT: a nonwrapping mechanism. Macromolecules 40(10):3676–3685. doi:10.1021/ma0705366 CrossRef

42.

Hamley IW (2005) Block copolymers in solutions. Wiley, Chichester

43.

Chu B, Zhou Z (1996) Physical chemistry of polyoxyalkylene block copolymer surfactants. In: Nace VM (ed) Nonionic surfactants: polyoxyalkylene block copolymers. Marcel Dekker, New York

44.

Broersma S (1960) Rotational diffusion constant of a cylindrical particle. J Chem Phys 32(6):1626–1631CrossRef

45.

Abraham TN, Debdatta R, Siengchin S, Karger-Kocsis J (2008) Rheological and thermal properties of poly(ethylene oxide)/multiwall carbon nanotube composites. J Appl Polym Sci 110(4):2094–2101CrossRef

46.

Chen H-W, Chang F-C (2001) The novel polymer electrolyte nanocomposite composed of poly(ethylene oxide), lithium triflate and mineral clay. Polymer 42(24):9763–9769CrossRef

47.

Valentini L, Biagiotti J, Kenny JM, Santucci S (2003) Morphological characterization of single-walled carbon nanotubes-PP composites. Compos Sci Technol 63(8):1149–1153CrossRef

48.

Assouline E, Lustiger A, Barber AH, Cooper CA, Klein E, Wachtel E, Wagner HD (2003) Nucleation ability of multiwall carbon nanotubes in polypropylene composites. J Polym Sci Part B: Polym Phys 41(5):520–527CrossRef

49.

Chatterjee T, Yurekli K, Hadjiev VG, Krishnamoorti R (2005) Single-walled carbon nanotube dispersions in poly(ethylene oxide). Adv Funct Mater 15(11):1832–1838CrossRef

Titel: The preparation of carbon nanotube/poly(ethylene oxide) composites using amphiphilic block copolymers
verfasst von: Chantal Semaan
Gilles Pecastaings
Michèle Schappacher
Alain Soum
Publikationsdatum: 01.01.2012
Verlag: Springer-Verlag
Erschienen in: Polymer Bulletin / Ausgabe 2/2012
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-011-0569-x

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 2/2012

Synthesis of poly(urethane-urea) varnish bearing azobenzene chromophoric pendants

Electromagnetic interference shielding effects of polyaniline-coated multi-wall carbon nanotubes/maghemite nanocomposites

Synthesis and properties of novel donor–acceptor copolymers based on thiophene and squaraine moieties

Competitive mechanism of poly(ethylene glycol) with poly(vinyl methyl ether) in complexing water molecules revealed with elastic light scattering spectroscopy

Influence of selected photoinitiators type II on tack, peel adhesion, and shear strength of UV-crosslinked solvent-borne acrylic pressure-sensitive adhesives used for medical applications

Evaluation of polypropylene grafted with maleic anhydride and styrene as a compatibilizer for polypropylene/clay nanocomposites

Premium Partner

Marktübersichten