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Erschienen in: Colloid and Polymer Science 6/2010

01.04.2010 | Short Communication

Molecular imprinting polymerization by Fenton reaction

verfasst von: Giuseppe Cirillo, Francesco Puoci, Manuela Curcio, Ortensia Ilaria Parisi, Francesca Iemma, Umile Gianfranco Spizzirri, Nevio Picci

Erschienen in: Colloid and Polymer Science | Ausgabe 6/2010

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Abstract

The aim of this study is the preparation of molecularly imprinted polymers by employing a redox pair as initiator system. Bulk molecularly imprinted polymers were synthesized by using Fenton reagents as initiator system. Theophylline, methacrylic acid, and ethylene glycol dimethacrylate were employed as model template, functional monomer, and crosslinking agent, respectively. Conventional imprinted polymers were also prepared by using 2,2′-azoisobutyronitrile in order to evaluate the efficiency of the proposed initiator system. Redox molecularly imprinted polymers and conventional molecularly imprinted polymers were characterized by water uptake measurement, while the imprinting effect of synthesized polymers were evaluated by performing binding experiments in organic (acetonitrile) and in water (buffered water solution at pH = 7.4) media.

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Metadaten
Titel
Molecular imprinting polymerization by Fenton reaction
verfasst von
Giuseppe Cirillo
Francesco Puoci
Manuela Curcio
Ortensia Ilaria Parisi
Francesca Iemma
Umile Gianfranco Spizzirri
Nevio Picci
Publikationsdatum
01.04.2010
Verlag
Springer-Verlag
Erschienen in
Colloid and Polymer Science / Ausgabe 6/2010
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-010-2198-6

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