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16.02.2023 | Original Article

MoO₃/C-supported Pd nanoparticles as an efficient bifunctional electrocatalyst for ethanol oxidation and oxygen reduction reactions

verfasst von: Mei-Ling Wang, Jin Zhao, Jin-Jin Wang, Jun-Ming Zhang, Yu-Zhu Tian, Zhi-Zhu Yue, Dong Li, Tian-Jun Hu, Jian-Feng Jia, Hai-Shun Wu

Erschienen in: Rare Metals | Ausgabe 5/2023

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Abstract

metal oxide electronic interactions in composite electrocatalysts have a considerable impact on their catalytic capability. In this study, we successfully synthesized an electrocatalytic material composed of MoO₃/C species-supported Pd nanoparticles (Pd-MoO₃/C) using a convenient hydrothermal method, which exhibited excellent catalytic activities for both ethanol oxidation and oxygen reduction in KOH media. The specific activity of Pd-MoO₃/C toward ethanol oxidation with MoO₃ loading (40 wt%) was ~ 2.6 times greater than that for the commercial Pd/C (10 wt%) with the same Pd content. In particular, the activity could effectively hold up to ~ 60% of its maximum activity after 500-cycle tests, demonstrating improved cyclical stability. Notably, the fast electron transfer kinetics toward oxygen reduction for Pd-MoO₃/C (40%) were also comparable to those of commercial Pt/C (20 wt%) catalysts. These superior electrochemical features are primarily derived from the stronger electronic coupling between Pd and MoO₃ through charge transfer, which can supply more active centers and improve the anti-poisoning ability. Meanwhile, the MoO₃ species in the Pd-MoO₃/C composite may provide additional benefits in terms of electrical conductivity and dispersion.

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Vorheriger Artikel Surface amorphization oxygen vacancy-rich porous Sn3Ox nanosheets for boosted photoelectrocatalytic bacterial inactivation

Nächster Artikel FeCo-N encapsuled in nitrogen-doped carbon nanotubes as bifunctional electrocatalysts with a high stability for zinc air batteries

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[1]

Karuppasamy L, Chen CY, Anandan S, Wu JJ. Low- and high-index faceted Pd nanocrystals embedded in various oxygen-deficient WO_x nanostructures for electrocatalytic oxidation of alcohol (EOA) and carbon monoxide (CO). ACS Appl Mater Interfaces. 2019;11(10):10028. https://doi.org/10.1021/acsami.8b22722.CrossRef

[2]

Vigier F, Rousseau S, Coutanceau C, Leger JM, Lamy C. Electrocatalysis for the direct alcohol fuel cell. Top Catal. 2006;40(1):111. https://doi.org/10.1007/s11244-006-0113-7.CrossRef

[3]

Akhairi MAF, Kamarudin SK. Catalysts in direct ethanol fuel cell (DEFC): an overview. Int J Hydrogen Energy. 2016;41(7):4214. https://doi.org/10.1016/j.ijhydene.2015.12.145.CrossRef

[4]

Ong BC, Kamarudin SK, Basri S. Direct liquid fuel cells: a review. Int J Hydrogen Energy. 2017;42(15):10142. https://doi.org/10.1016/j.ijhydene.2017.01.117.CrossRef

[5]

Luo MC, Zhao ZL, Zhang YL, Sun YJ, Xing Y, Lv F, Yang Y, Zhang X, Wang SH, Qin YN, Ma JY, Lin F, Su D, Lu G, Guo SJ. PdMo bimetallene for oxygen reduction catalysis. Nature. 2019;574(7776):81. https://doi.org/10.1038/s41586-019-1603-7.CrossRef

[6]

Xu X, Zhang X, Sun H, Yang Y, Dai X, Gao J, Li X, Zhang P, Wang HH, Yu NF, Sun SG. Synthesis of Pt–Ni alloy nanocrystals with high-index facets and enhanced electrocatalytic properties. Angew Chem. 2014;126(46):12730. https://doi.org/10.1002/ange.201406497.CrossRef

[7]

Stamenkovic VR, Fowler B, Mun BS, Wang GF, Ross PN, Lucas CA, Markovic NM. Improved oxygen reduction activity on Pt₃Ni (111) via increased surface site availability. Science. 2007;315(5811):493. https://doi.org/10.1126/science.1135941.CrossRef

[8]

Chen XX, Zhen XJ, Gong HY, Li L, Xiao JW, Xu Z, Yan DY, Xiao GY, Yang RZ. Cobalt and nitrogen codoped porous carbon as superior bifunctional electrocatalyst for oxygen reduction and hydrogen evolution reaction in alkaline medium. Chin Chem Lett. 2019;30(3):681. https://doi.org/10.1016/j.cclet.2018.09.017.CrossRef

[9]

Ehsani A, Heidari A, Asgari R. Electrocatalytic oxidation of ethanol on the surface of graphene based nanocomposites: an introduction and review to it in recent studies. Chem Rec. 2019;19(11):2341. https://doi.org/10.1002/tcr.201800176.CrossRef

[10]

Chen W, Kim JM, Sun SH, Chen SW. Electrocatalytic reduction of oxygen by FePt alloy nanoparticles. J Phys Chem C. 2008;112(10):3891. https://doi.org/10.1021/jp7110204.CrossRef

[11]

Guo MX, Du JC, Li H, Zhang XJ, Zhang AM, Zhao YK. New research progress on precious metal catalysts for methane combustion. Chin J Rare Met. 2021;45(9):1133. https://doi.org/10.13373/j.cnki.cjrm.XY19110015.CrossRef

[12]

Mondal S, Choutipalli VSK, Jena BK, Subramanian V, Raj CR. Bifunctional electrocatalytic activity of ordered intermetallics based on Pd and Sn. J Phys Chem C. 2020;124(18):9631. https://doi.org/10.1021/acs.jpcc.9b10417.CrossRef

[13]

Bianchini C, Shen PK. Palladium-based electrocatalysts for alcohol oxidation in half cells and in direct alcohol fuel cells. Chem Rev. 2009;109(9):4183. https://doi.org/10.1021/cr9000995.CrossRef

[14]

Antolini E. Palladium in fuel cell catalysis. Energy Environ Sci. 2009;2(9):915. https://doi.org/10.1039/B820837A.CrossRef

[15]

Poon KC, Tan DC, Vo TD, Khezri B, Su H, Webster RD, Sato H. Newly developed stepwise electroless deposition enables a remarkably facile synthesis of highly active and stable amorphous Pd nanoparticle electrocatalysts for oxygen reduction reaction. J Am Chem Soc. 2014;136(14):5217. https://doi.org/10.1021/ja500275r.CrossRef

[16]

Zhang ZJ, Zhou DB, Wu XW, Bao XJ, Liao JJ, Zhang FF. One-pot synthesis of Pd-ZnO/C by microwave sintering method as an efficient electrocatalyst for ethanol oxidation reaction. Int J Hydrogen Energy. 2019;44(13):6608. https://doi.org/10.1016/j.ijhydene.2019.01.184.CrossRef

[17]

Lu YZ, Jiang YY, Gao XH, Wang XD, Chen W. Strongly coupled Pd nanotetrahedron/tungsten oxide nanosheet hybrids with enhanced catalytic activity and stability as oxygen reduction electrocatalysts. J Am Chem Soc. 2014;136(33):11687. https://doi.org/10.1021/ja5041094.CrossRef

[18]

Wang W, Yang Y, Liu YQ, Zhang Z, Dong WK, Lei ZQ. Hybrid NiCoO_x adjacent to Pd nanoparticles as a synergistic electrocatalyst for ethanol oxidation. J Power Sources. 2015;273:631. https://doi.org/10.1016/j.jpowsour.2014.09.120.CrossRef

[19]

Tan Q, Zhu HY, Guo SW, Chen YZ, Jiang T, Shu CY, Chong SK, Hultman B, Liu YN, Wu G. Quasi-zero-dimensional cobalt-doped CeO₂ dots on Pd catalysts for alcohol electrooxidation with enhanced poisoning tolerance. Nanoscale. 2017;9(34):12565. https://doi.org/10.1039/C7NR03262E.CrossRef

[20]

Zhang Y, Yuan XL, Lyu FL, Wang XC, Jiang XJ, Cao MH, Zhang Q. Facile one-step synthesis of PdPb nanochains for high-performance electrocatalytic ethanol oxidation. Rare Met. 2020;39(7):792. https://doi.org/10.1007/s12598-020-01442-0.CrossRef

[21]

Wang ZP, Shen SJ, Lin ZP, Tao WY, Zhang QH, Meng FQ, Gu L, Zhong WW. Regulating the local spin state and band structure in Ni₃S₂ nanosheet for improved oxygen evolution activity. Adv Funct Mater. 2022;32(18):2112832. https://doi.org/10.1002/adfm.202112832.CrossRef

[22]

Shen SJ, Wang ZP, Lin ZP, Song K, Zhang QH, Meng FQ, Gu L, Zhong WW. Crystalline-amorphous interfaces coupling of CoSe₂/CoP with optimized d-band center and boosted electrocatalytic hydrogen evolution. Adv Mater. 2022;34(13):2110631. https://doi.org/10.1002/adma.202110631.CrossRef

[23]

Eshghi A, Behbahani ES, Kheirmand M, Ghaedi M. Pd, Pd−Ni and Pd−Ni−Fe nanoparticles anchored on MnO₂/Vulcan as efficient ethanol electro-oxidation anode catalysts. Int J Hydrogen Energy. 2019;44(52):28194. https://doi.org/10.1016/j.ijhydene.2019.08.236.CrossRef

[24]

Huang JZ, Han JC, Wu T, Feng K, Yao T, Wang XJ, Liu SW, Zhong J, Zhang ZH, Zhang YM, Song B. Boosting hydrogen transfer during volmer reaction at oxides/metal nanocomposites for efficient alkaline hydrogen evolution. ACS Energy Lett. 2019;4(12):3002. https://doi.org/10.1021/acsenergylett.9b02359.CrossRef

[25]

Vélez CA, Corchado-García J, Rojas-Pérez A, Serrano-Alejandro EJ, Santos-Homs C, Soto-Pérez JJ, Cabrera CR. Manufacture of Pd/carbon vulcan XC-72R nanoflakes catalysts for ethanol oxidation reaction in alkaline media by RoDSE method. J Electrochem Soc. 2017;164(14):D1015. https://doi.org/10.1149/2.1041714jes.CrossRef

[26]

Yi QF, Sun LZ. In situ synthesis of palladium nanoparticles on multi-walled carbon nanotubes and their electroactivity for ethanol oxidation. Rare Met. 2013;32(6):586. https://doi.org/10.1007/s12598-013-0179-x.CrossRef

[27]

Xiao H, Zhang JJ, Zhao M, Hu TJ, Jia JF, Wu HS. Hydrogenated graphene as support of Pd nanoparticles with improved electrocatalytic activity for ethanol oxidation reaction in alkaline media. Electrochim Acta. 2019;297:856. https://doi.org/10.1016/j.electacta.2018.12.058.CrossRef

[28]

Chen YZ, Zhou M, Huang YF, Ma YY, Yan LY, Zhou XW, Ma XZ, Zhao XL, Chen C, Bai J, Lin DH. Enhanced ethanol oxidation over Pd nanoparticles supported porous graphene-doped MXene using polystyrene particles as sacrificial templates. Rare Met. 2022;41(9):3170. https://doi.org/10.1007/s12598-022-02039-5.CrossRef

[29]

Singh BK, Lee S, Na K. An overview on metal-related catalysts: metal oxides, nanoporous metals and supported metal nanoparticles on metal organic frameworks and zeolites. Rare Met. 2020;39(7):751. https://doi.org/10.1007/s12598-019-01205-6.CrossRef

[30]

Yang SD, Zhang XG, Huang JS, Sun JY. Pd-Ni/MWCNT electrocatalysts for ethylene glycol electro-oxidation in alkaline medium. Acta Phys Chim Sin. 2007;23(08):1224. https://doi.org/10.3866/PKU.WHXB20070816.CrossRef

[31]

Yan D, Wang W, Luo X, Chen C, Zeng Y, Zhu Z. NiCo₂O₄ with oxygen vacancies as better performance electrode material for supercapacitor. Chem Eng J. 2018;334:864. https://doi.org/10.1016/j.cej.2017.10.128.CrossRef

[32]

Moulder JF, Stickle WF, Sobol, PE, Bomben, KD, Chastian, J. X-ray photoelectron spectroscopy. Handbook of X-ray Photoelectron Spectroscopy. Perkin-Elmer Corp. Eden Prairie, MN, USA, 1992.

[33]

Xie SH, Dai HX, Deng JG, Liu YX, Yang HG, Jiang Y, Tan W, Ao A, Guo GS. Au/3DOM Co₃O₄: highly active nanocatalysts for the oxidation of carbon monoxide and toluene. Nanoscale. 2013;5(22):11207. https://doi.org/10.1039/C3NR04126C.CrossRef

[34]

Qing C, Yang CX, Chen MY, Li WH, Wang SY, Tang YW. Design of oxygen-deficient NiMoO₄ nanoflake and nanorod arrays with enhanced supercapacitive performance. Chem Eng J. 2018;354:182. https://doi.org/10.1016/j.cej.2018.08.005.CrossRef

[35]

Gobal F, Arab R. A preliminary study of the electro-catalytic reduction of oxygen on Cu-Pd alloys in alkaline solution. J Electroanal Chem. 2010;647(1):66. https://doi.org/10.1016/j.jelechem.2010.05.009.CrossRef

[36]

Xing XL, Zhao YF, Li H, Wang CT, Li QX, Cai WB. High performance Ag rich Pd-Ag bimetallic electrocatalyst for ethylene glycol oxidation in alkaline media. J Electrochem Soc. 2018;165(15):J3259. https://doi.org/10.1149/2.0311815jes.CrossRef

[37]

Mozafari V, Parsa JB. Promoted electrocatalytic performance of palladium nanoparticles using doped-NiO supporting materials toward ethanol electro oxidation in alkaline media. Int J Hydrogen Energy. 2020;45(53):28847. https://doi.org/10.1016/j.ijhydene.2020.07.276.CrossRef

[38]

Habibi B, Mohammadyari S. Facile synthesis of Pd nanoparticles on nano carbon supports and their application as an electrocatalyst for oxidation of ethanol in alkaline media: the effect of support. Int J Hydrogen Energy. 2015;40(34):10833. https://doi.org/10.1016/j.ijhydene.2015.07.021.CrossRef

[39]

Xiong LK, Sun ZT, Zhang X, Zhao L, Huang P, Chen XW, Jin HD, Sun H, Lian YB, Deng Z, Rümmerli MH, Yin WJ, Zhang D, Wang S, Peng Y. Octahedral gold-silver nanoframes with rich crystalline defects for efficient methanol oxidation manifesting a CO-promoting effect. Nat Commun. 2019;10(1):3782. https://doi.org/10.1038/s41467-019-11766-w.CrossRef

[40]

Lv H, Sun LZ, Xu DD, Ma YH, Liu B. When ternary PdCuP alloys meet ultrathin nanowires: synergic boosting of catalytic performance in ethanol electrooxidation. Appl Catal B Environ. 2019;253:271. https://doi.org/10.1016/j.apcatb.2019.04.066.CrossRef

[41]

Zhang Y, Huang BL, Shao Q, Feng YG, Xiong LK, Peng Y, Huang XQ. Defect engineering of palladium−tin nanowires enables efficient electrocatalysts for fuel cell reactions. Nano Lett. 2019;19(10):6894. https://doi.org/10.1021/acs.nanolett.9b02137.CrossRef

[42]

Wang H, Liu RP, Li YT, Lu XJ, Wang Q, Zhao SQ, Yuan KJ, Cui ZM, Li X, Xin S, Zhang R, Lei M, Lin ZQ. Durable and efficient hollow porous oxide spinel microspheres for oxygen reduction. Joule. 2018;2(2):337. https://doi.org/10.1016/j.joule.2017.11.016.CrossRef

[43]

Yang LJ, Feng SZ, Xu GC, Wei B, Zhang L. Electrospun MOF-based FeCo nanoparticles embedded in nitrogen doped mesoporous carbon nanofibers as an efficient bifunctional catalyst for oxygen reduction and oxygen evolution reactions in zinc-air batteries. ACS Sustain Chem Eng. 2019;7(5):5462. https://doi.org/10.1021/acssuschemeng.8b06624.CrossRef

[44]

Li ZS, Lv L, Wang JS, Ao X, Ruan YJ, Zha D, Hong G, Wu QH, Lan YC, Wang CD, Jiang JJ, Liu ML. Engineering phosphorus-doped LaFeO_3-δ perovskite oxide as robust bifunctional oxygen electrocatalysts in alkaline solutions. Nano Energy. 2018;47:199. https://doi.org/10.1016/j.nanoen.2018.02.051.CrossRef

[45]

Wang X, Raghupathy RKM, Querebillo CJ, Liao ZQ, Li DQ, Lin K, Hantusch M, Sofer Z, Li BH, Zschech E, Weidinger IM, Kühne TD, Mirhosseini H, Yu MH, Feng XL. Interfacial covalent bonds regulated electron-deficient 2D black phosphorus for electrocatalytic oxygen reactions. Adv Mater. 2021;33(20):2008752. https://doi.org/10.1002/adma.202008752.CrossRef

Titel: MoO3/C-supported Pd nanoparticles as an efficient bifunctional electrocatalyst for ethanol oxidation and oxygen reduction reactions
verfasst von: Mei-Ling Wang
Jin Zhao
Jin-Jin Wang
Jun-Ming Zhang
Yu-Zhu Tian
Zhi-Zhu Yue
Dong Li
Tian-Jun Hu
Jian-Feng Jia
Hai-Shun Wu
Publikationsdatum: 16.02.2023
Verlag: Nonferrous Metals Society of China
Erschienen in: Rare Metals / Ausgabe 5/2023
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI: https://doi.org/10.1007/s12598-022-02211-x

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