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2013 | OriginalPaper | Buchkapitel

Nanostructured Polymeric Ionic Liquids

verfasst von : Benjamin Kerscher, Fabian Schüler, Anna-Katharina Appel, Kristina Schadt, Rolf Mülhaupt

Erschienen in: Hierarchical Macromolecular Structures: 60 Years after the Staudinger Nobel Prize II

Verlag: Springer International Publishing

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Abstract

Nanophase separation, self-assembly, and molecular nanostructure design of liquid polyelectrolytes afford new families of ionic liquids containing nanometer-scaled compartments. Key intermediates of nanostructured polymeric ionic liquids (nanoPILs) are PILs with micelle-like topologies, block copolymers and polymer electrolytes dissolved in ionic liquids (ILs), and nanoparticle dispersions. In contrast to micellar ILs, micelle-like nanoPILs consist of a nonionic hyperbranched polyether core with low glass transition temperature and covalently attached alkyl-substituted IL moieties in its periphery. Such hyperbranched nanoPILs are thermally stable dispersants, nanoreactors, and transporters that are useful in nanoparticle synthesis and polymer melt compounding. As new molecular carbon/polyelectrolyte composite materials, tree-like nanoPILs are grafted onto functionalized graphene. Here, we highlight recent progress made in nanoPIL science and engineering, illustrated by selected examples.

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Titel: Nanostructured Polymeric Ionic Liquids
verfasst von: Benjamin Kerscher
Fabian Schüler
Anna-Katharina Appel
Kristina Schadt
Rolf Mülhaupt
Verlag: Springer International Publishing
Buch: Hierarchical Macromolecular Structures: 60 Years after the Staudinger Nobel Prize II
Print ISBN: 978-3-319-03718-9

Electronic ISBN: 978-3-319-03719-6

Copyright-Jahr: 2013
DOI: https://doi.org/10.1007/12_2013_256

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