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Journal of Nanoparticle Research

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01.03.2013 | Research Paper

Nickel-doped zinc aluminate oxides: starch-assisted synthesis, structural, optical properties, and their catalytic activity in oxidative coupling of methane

verfasst von: Diana Visinescu, Florica Papa, Adelina C. Ianculescu, Ioan Balint, Oana Carp

Erschienen in: Journal of Nanoparticle Research | Ausgabe 3/2013

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Abstract

Nanosized nickel-substituted zinc aluminate oxides were obtained by the gradual insertion of nickel cations within the zinc aluminate lattice, using starch as active ingredient. The obtained (Ni_xZn_1−xAl₂)-starch (x = 0.1, 0.2, 0.4, 0.6, 0.8, 1) gel precursors were characterized through infrared spectroscopy and thermal analysis. The thermal behavior of the precursors are influenced by the nickel content, the DTA curves for the richer nickel samples revealing stronger, faster and overlapping exothermic reactions, that can be completed at lower temperatures. The corresponding spinelic oxides were obtained after calcination treatments at 800 °C and analyzed by means of NIR–UV–Vis spectroscopy, XRD measurements, SEM, TEM, and HRTEM investigations. The spinelic structure for all oxide samples is confirmed by XRD analysis, although small amounts of NiO cannot be neglected. TEM/HRTEM analysis revealed mesopores embedded in plate-like large (68.8 nm) particles of Ni_0.2Zn_0.8Al₂O₄ sample and smaller (15.7 nm) uniform equiaxial particles, with a more pronounced tendency of agglomeration for Ni_0.8Zn_0.2Al₂O₄ oxide. A formation mechanism for Ni_0.2Zn_0.8Al₂O₄ oxides was proposed based on DTA/TG, XRD, and SEM analyses. NIR–UV–Vis spectra for Ni_xZn_1−xAl₂O₄ showed a significant presence of tetrahedral nickel cations that augments with nickel concentration increase. CIE-L ^* a ^* b ^* color parameters shown a variation of the lightness and also of the green and blue color components with x, the best color characteristics being obtained for x = 0.6. The oxides with a substitution degree x = 0.2 and 0.8 tested in the oxidative coupled of methane reaction (OCM) showed positive catalytic activity and selectivity due to an interesting synergetic effect of Zn(II) and Ni(II) ions.

Vorheriger Artikel Nanosizing as a way to enhanced solubility of transition metals in ZnO

Nächster Artikel Mild-temperature synthesis and first-principle fluorescence simulation of GaN nanoparticles

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Titel: Nickel-doped zinc aluminate oxides: starch-assisted synthesis, structural, optical properties, and their catalytic activity in oxidative coupling of methane
verfasst von: Diana Visinescu
Florica Papa
Adelina C. Ianculescu
Ioan Balint
Oana Carp
Publikationsdatum: 01.03.2013
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 3/2013
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-013-1456-1

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