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Metallurgical and Materials Transactions A
Erschienen in: Metallurgical and Materials Transactions A 9/2022

28.06.2022 | Brief Communication

Nitrogen-Induced Phase Separation in Equiatomic FeNiCo Medium Entropy Alloy

verfasst von: S. A. R. Qadri, K. N. Sasidhar, E. A. Jagle, G. Miyamoto, S. R. Meka

Erschienen in: Metallurgical and Materials Transactions A | Ausgabe 9/2022

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Abstract

We report the first observation of isothermal phase separation triggered by inwardly diffusing interstitial nitrogen atoms during nitriding of an equiatomic FeNiCo medium entropy alloy. Detailed microstructural characterization revealed a phase-separated microstructure within the nitrided region containing two FCC solid solution phases with one enriched in Fe and N while other enriched in Co and Ni. This demonstrates the potential utilization of interstitial N alloying to tailor the microstructure of multi-principal element alloys.

Graphical Abstract

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Fußnoten
1
The phase diagram in Figure 5 (a) is metastable because it has been obtained after suppressing the formation of the equilibrium \({\gamma }^{^{\prime}}\) Fe4N type nitride and ε-Fe3-x N type nitride. Please see supplementary information for details of the equilibrium phase diagram and compositions of equilibrium phases.
 
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Metadaten
Titel
Nitrogen-Induced Phase Separation in Equiatomic FeNiCo Medium Entropy Alloy
verfasst von
S. A. R. Qadri
K. N. Sasidhar
E. A. Jagle
G. Miyamoto
S. R. Meka
Publikationsdatum
28.06.2022
Verlag
Springer US
Erschienen in
Metallurgical and Materials Transactions A / Ausgabe 9/2022
Print ISSN: 1073-5623
Elektronische ISSN: 1543-1940
DOI
https://doi.org/10.1007/s11661-022-06746-7

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