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Journal of Sol-Gel Science and Technology

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15.10.2016 | Original Paper: Sol-gel and hybrid materials for optical, photonic and optoelectronic applications

Novel fluorescent terphenyl bridged crystalline silsesquioxane through self-directed assembly

verfasst von: Caixia Liu, Zhiqiang Li, Yige Wang

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 2/2017

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Abstract

A novel silsesquioxane hybrid crystal was synthesized by a facile synthesis and purification process without any structure-directing agent. fourier transform-infrared spectoscopy, X-ray diffraction, scanning electron microscopy, transmission electron microscopy, ¹³C, ²⁹Si solid-state nuclear magnetic resonance spectroscopy and photoluminescence spectroscopy were employed to characterize the obtained material. X-ray diffraction and transmission electron microscopy revealed the well-ordered features with lamellar spacings in the bridged silsesquioxanes. In addition, the formation of crystalline bridged polysilsesquioxanes with well-organized structure was attributed to self-assembly of the intermolecular hydrogen bonding between the urea groups. Interestingly, the introduction of photoactive terphenyl chromophore into silsesquioxane made bridged polysilsesquioxanes exhibit special fluorescent properties, which could provide a way to fabricate new nanomaterial.

Graphical Abstract

We successfully synthesized a novel crystalline hybrid bridged polysilsesquioxanes (BPS) with well-ordered features arising from the self-assembling of the precursors. Interestingly, the introduction of photoactive terphenyl chromophore into silsesquioxane made hybrid material BPS exhibit bright blue emission.

https://static-content.springer.com/image/art%3A10.1007%2Fs10971-016-4219-5/MediaObjects/10971_2016_4219_Figa_HTML.gif

Vorheriger Artikel Photoluminescence properties of Gd:ZnO nano phosphor

Nächster Artikel Absorption capacity, kinetics and mechanical behaviour in dry and wet states of hydrophobic DEDMS/TEOS-based silica aerogels

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Titel: Novel fluorescent terphenyl bridged crystalline silsesquioxane through self-directed assembly
verfasst von: Caixia Liu
Zhiqiang Li
Yige Wang
Publikationsdatum: 15.10.2016
Verlag: Springer US
Erschienen in: Journal of Sol-Gel Science and Technology / Ausgabe 2/2017
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI: https://doi.org/10.1007/s10971-016-4219-5

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