Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Materials Science
Erschienen in: Journal of Materials Science 19/2018

22.06.2018 | Chemical routes to materials

One-step liquid-phase reaction to synthesize LiNi0.8Co0.15Al0.05O2 cathode material

verfasst von: Yingjie Zhang, Zhenping Qiu, Peng Dong, Jianguo Duan, Shubiao Xia

Erschienen in: Journal of Materials Science | Ausgabe 19/2018

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

LiNi0.8Co0.15Al0.05O2 cathode material in lithium-ion batteries has been synthesized in a facile one-step liquid-phase reaction. The effects of sintering on the structural and electrochemical properties of LiNi0.8Co0.15Al0.05O2 are investigated. X-ray diffraction (XRD) test and XRD Rietveld refinement results indicate that LiNi0.8Co0.15Al0.05O2 cathode material prepared by one-step liquid-phase reaction is a hexagonal phase with low Li/Ni mixing degree. Scanning electron microscope and energy-dispersive spectrometer are applied to investigate the morphology of the samples and the distribution of metal ions, respectively. Transmission electron microscope measurement shows good crystallinity with well-fined lattice fringes corresponding to (003) planes. The surface information of the samples is investigated by X-ray photoelectron spectroscopy. Electrochemical data demonstrate that the sample sintered at 790 °C exhibits the best electrochemical performance. The sample shows a high initial discharge capacity of 193.5 mAh g−1 at 0.2 C and an accepted cycle performance (84.7% capacity retention after 100 cycles). In addition, it displays outstanding rate capacity (152.5 mAh g−1 at a rate of 10 C). The lithium-ion diffusion coefficients are obtained by different methods. The results of this paper provide a facile method to synthesize Ni-rich layered oxides for lithium-ion batteries.
Vorheriger Artikel Numerical model for particle size effects on flash sintering temperature of ionic nanoparticles
Nächster Artikel Low-temperature treatment for preservation and separation of graphene dispersions

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Chang Z, Wang XJ, Yang YQ, Gao J, Li MX, Liu LL, Wu YP (2014) Rechargeable Li//Br battery: a promising platform for post lithium ion batteries. J Mater Chem A 2:19444–19450CrossRef
2.
Wang XJ, Hou YY, Zhu YS, Wu YP, Holze R (2013) An aqueous rechargeable lithium battery using coated Li metal as anode. Sci Rep 3(7439):1401–1406CrossRef
3.
4.
Lee MJ, Lee S, Oh P, Kim Y, Cho J (2014) High performance LiMn2O4 cathode materials grown with epitaxial layered nanostructure for Li-ion batteries. Nano Lett 14:993–999CrossRef
5.
6.
Liu H, Strobridge FC, Borkiewicz OF, Wiaderek KM, Chapman KW, Chupas PJ, Clare PG (2014) Capturing metastable structures during high-rate cycling of LiFePO4 nanoparticle electrodes. Science 344:1451–1452CrossRef
7.
Rong HG, Dawson JA, Harding JH (2014) Effect of cationic substitution on structural defects in layered cathode materials LiNiO2. J Mater Chem A 2:7988–7996CrossRef
8.
Ghatak K, Kumar H, Nadimpalli S, Datta D (2017) Effect of decreasing cobalt content on the electrochemical properties and structural stability of Li1-xNiyCozAl0.05O2 type cathode materials. arXiv:​1704.​08413
9.
Park TJ, Lim JB, Son JT (2014) Effect of calcination temperature of size controlled microstructure of LiNi0.8Co0.15Al0.05O2 cathode for rechargeable lithium battery. Bull Kor Chem Soc 35:357–364CrossRef
10.
Xia SB, Zhang YJ, Dong P, Zhang YN (2014) Synthesis cathode material LiNi0.80Co0.15Al0.05O2 with two step solid-state method under air stream. Eur Phys J Appl Phys 65(1):152–154CrossRef
11.
Han CJ, Yoon JH, Cho WI, Jang H (2004) Electrochemical properties of LiNi0.8Co0.2−xAlxO2 prepared by a sol–gel method. J Power Sources 136:132–138CrossRef
12.
13.
Ju SH, Jang HC, Kang YC (2007) Al-doped Ni-rich cathode powders prepared from the precursor powders with fine size and spherical shape. Electrochim Acta 52:7286–7292CrossRef
14.
Wang L, Wu BR, Mu DB, Liu XJ, Peng YY, Xu HL, Liu Q, Gai L, Feng Wu (2016) Single-crystal LiNi0.6Co0.2Mn0.2O2 as high performance cathode materials for Li-ion batteries. J Alloy Compd 674:360–367CrossRef
15.
Wu NT, Wu H, Yuan W, Liu SJ, Liao JY, Zhang Y (2015) Facile synthesis of one-dimensional LiNi0.8Co0.15Al0.05O2 microrods as advanced cathode materials for lithium ion batteries. J Mater Chem A 3:13648–13652CrossRef
16.
Zhou PF, Meng HJ, Zhang Z, Chen CC, Lu YY, Cao J, Cheng FY, Chen J (2017) Stable layered Ni-rich LiNi0.9Co0.07Al0.03O2 microspheres assembled with nanoparticles as high-performance cathode materials for lithium-ion batteries. J Mater Chem A 5:2724–2731CrossRef
17.
Liu WM, Hu GR, Peng ZD, Du K, Cao YB, Liu Q (2011) Synthesis of spherical LiNi0.8Co0.15Al0.05O2 cathode materials for lithium-ion batteries by a co-oxidation-controlled crystallization method. Chin Chem Lett 22:1099–1102CrossRef
18.
Zhu Z, Yan H, Zhang D, Li W, Lu Q (2013) Preparation of 4.7 V cathode material LiNi0.5Mn1.5O4 by an oxalic acid-pretreated solid-state method for lithium-ion secondary battery. J Power Sources 224:13–19CrossRef
19.
Liu ZS, Jiang YM, Zeng XY, Xiao G, Song HY, Liao SJ (2014) Two-step oxalate approach for the preparation of high performance LiNi0.5Mn1.5O4 cathode material with high voltage. J Power Sources 247:437–443CrossRef
20.
Fu LJ, Liu H, Li C, Wu YP, Rahm E, Holze R, Wu HQ (2005) Electrode materials for lithium secondary batteries prepared by sol–gel methods. Prog Mater Sci 50:881–928CrossRef
21.
Hu GR, Liu WM, Peng ZD, Du K, Cao YB (2012) Synthesis and electrochemical properties of LiNi0.8Co0.15Al0.05O2 prepared from the precursor Ni0.8Co0.15Al0.05OOH. J Power Sources 198:258–263CrossRef
22.
Hsieh CT, Hsu HH, Hsu JP, Chen YF, Chang JK (2016) Infrared-assisted synthesis of lithium nickel cobalt alumina oxide powders as electrode material for lithium-ion batteries. Electrochim Acta 206:207–216CrossRef
23.
Zheng XB, Li XH, Zhang B, Wang ZX, Guo HJ, Huang ZJ, Yan GC, Wang D, Xu Y (2016) Enhanced electrochemical performance of LiNi0.8Co0.1Mn0.1O2 cathode materials obtained by atomization co-precipitation method. Ceram Int 42:644–649CrossRef
24.
Xie HB, Hu GR, Du K, Peng ZD, Cao YB (2016) An improved continuous co-precipitation method to synthesize LiNi0.80Co0.15Al0.05O2 cathode material. J Alloy Compd 666:84–87CrossRef
25.
Zhou L, Tian MJ, Deng YL, Zheng QJ, Xu CG, Lin DM (2016) La2O3-coated Li1.2Mn0.54Ni0.13Co0.13O2 as cathode materials with enhanced specific capacity and cycling stability for lithium-ion batteries. Ceram Int 42:15623–15633CrossRef
26.
Matienzo LJ, Yin LI, Swrtz WE (1973) Cheminform abstract: x-ray photoelectron spectra of square planar and octahedral nickel(II) complexes. Inorg Nucl Chem Lett 9(7):731–735CrossRef
27.
Salvati L, Makovsky LE, Stencel JM, Brown FR, Hercules SM (1981) Surface spectroscopic study of tungsten-alumina catalysts using x-ray photoelectron, ion scattering, and Raman spectroscopies. J Phy Chem 85:3700–3707CrossRef
28.
Tang ZF, Bao JJ, Du QX, Shao Y, Gao MH, Zou BK, Chen CH (2016) Surface surgery of the nickel-rich cathode material LiNi0.815Co0.15Al0.035O2: toward a complete and ordered surface layered structure and better electrochemical properties. ACS Appl Mater Interface 8:34879–34887CrossRef
29.
Lv DD, Wang L, Hu PF, Sun ZP, Chen ZY, Zhang QB, Cheng WH, Ren W, Bian L, Xu JB, Chang AM (2017) Li2O–B2O3–Li2SO4 modified LiNi1/3Co1/3Mn1/3O2 cathode material for enhanced electrochemical performance. Electrochim Acta 247:803–811CrossRef
30.
Zhu L, Liu Y, Wu WY, Wu XW, Tang WP, Wu YP (2015) Surface fluorinated LiNi0.8Co0.15Al0.05O2 as a positive electrode material for lithium ion batteries. J Mater Chem A 3:15156–15162CrossRef
31.
Xiong XH, Ding D, Wang ZX, Huang B, Guo HJ, Li XH (2014) Surface modification of LiNi0.8Co0.1Mn0.1O2 with conducting polypyrrole. J Solid State Electrochem 18:2619–2624CrossRef
32.
Huang B, Li XH, Wang ZX, Guo HJ, Shen L, Wang JX (2014) A comprehensive study on electrochemical performance of Mn-surface-modified LiNi0.8Co0.15Al0.05O2 synthesized by an in situ oxidizing-coating method. J Power Sources 252:200–207CrossRef
33.
Xie HB, Du K, Hu GR, Duan JG, Peng ZD, Zhang ZJ, Cao YB (2015) Synthesis of LiNi0.8Co0.15Al0.05O2 with 5-sulfosalicylic acid as a chelating agent and its electrochemical properties. J Mater Chem A 3:20236–20243CrossRef
34.
Tian XH, Zhou YK, Tu XF, Zhang ZT, Du GD (2016) Well-dispersed LiFePO4 nanoparticles anchored on a three-dimensional graphene aerogel as high-performance positive electrode materials for lithium-ion batteries. J Power Sources 340:40–50CrossRef
35.
Shui M, Gao S, Shu J, Zheng WD, Xu D, Chen LL, Feng L, Ren YL (2012) LiNi1/3Co1/3Mn1/3O2 cathode materials for LIB prepared by spray pyrolysis. II. Li + diffusion kinetics. Ionics 19:47–52CrossRef
Metadaten
Titel
One-step liquid-phase reaction to synthesize LiNi0.8Co0.15Al0.05O2 cathode material
verfasst von
Yingjie Zhang
Zhenping Qiu
Peng Dong
Jianguo Duan
Shubiao Xia
Publikationsdatum
22.06.2018
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 19/2018
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-2568-x

Weitere Artikel der Ausgabe 19/2018

Journal of Materials Science 19/2018 Zur Ausgabe

Chemical routes to materials

Controllable synthesis of magnetic Fe3O4 encapsulated semimetal Bi nanospheres with excellent stability and catalytic activity

Mechanochemical Synthesis

Characterization of phases in the V2O5–Yb2O3 system obtained by high-energy ball milling and high-temperature treatment

Mechanochemical Synthesis

Synthesis of nickel boride by thermal explosion in ball-milled powder mixtures

Mechanochemical Synthesis

Two important periods in the history of mechanochemistry

Mechanochemical Synthesis

Information on the mechanism of mechanochemical reaction from detailed studies of the reaction kinetics

Composites

Enhanced dual-responsive shape memory nanocomposites with rapid and efficient self-healing capability

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise