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Polymer Bulletin
Erschienen in: Polymer Bulletin 7/2021

24.06.2020 | Original Paper

Optical properties and photo-isomerization processes of PMMA–BDK–MR nanocomposite thin films doped by silica nanoparticles

verfasst von: A. M. Alsaad, Qais M. Al-Bataineh, M. Telfah, A. A. Ahmad, Zaid Albataineh, Ahmad Telfah

Erschienen in: Polymer Bulletin | Ausgabe 7/2021

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Abstract

A novel nanocomposite thin films based on azo dye methyl red (MR) hosted in polymethylmethacrylate (PMMA) incorporated with benzyl dimethyl ketal (BDK) as a photo-initiator and doped with 2.5% and 5% of silica NPs are prepared by dip coating technique on fused silica substrates. We investigate the optical, chemical and thermal properties of (PMMA–BDK–MR)/silica NPs nanocomposite thin films by performing UV–Vis spectrometer, Fourier transform infrared spectroscopy (FTIR) and Thermogravimetric analyser (TGA). The purpose of inserting the azo dye MR in the composite is to stimulate the nanocomposite to perform the cis ↔ trans cycles through illumination ↔ thermal relaxation for Write/Read/Erase optical data storage and UV-light sensors. Our UV–Vis and FTIR findings confirm the hysteresis cycle of trans- and cis-states. Consequently, (PMMA–BDK–MR)/silica NPs thin films could be successfully used in Write/Read/Erase optical data storage and UV-light sensors. The TGA measurements show that the weight loss of the nanocomposites is reversibly proportional to the silica NPs concentration indicating the reinforcement of physicochemical bonding density as the concentration of silica NPs is increased.
Nächster Artikel Synthesis of montmorillonite/modified graphene oxide filler and its effect on the properties of PP composites

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Metadaten
Titel
Optical properties and photo-isomerization processes of PMMA–BDK–MR nanocomposite thin films doped by silica nanoparticles
verfasst von
A. M. Alsaad
Qais M. Al-Bataineh
M. Telfah
A. A. Ahmad
Zaid Albataineh
Ahmad Telfah
Publikationsdatum
24.06.2020
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 7/2021
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-020-03273-6

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