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Journal of Material Cycles and Waste Management

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24.11.2017 | ORIGINAL ARTICLE

Palladium recovery from monolithic ceramic capacitors by leaching, solvent extraction and reduction

verfasst von: Danilo Fontana, Massimiliana Pietrantonio, Stefano Pucciarmati, Giorgia Nadia Torelli, Chiara Bonomi, Federica Masi

Erschienen in: Journal of Material Cycles and Waste Management | Ausgabe 2/2018

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Abstract

Palladium finds a remarkable use in electronic devices and catalysts; therefore, an efficient and complete recovery from the containing secondary materials assumes a great relevance. The present paper discusses recovery of palladium (Pd) contained in monolithic ceramic capacitors from waste printed circuit boards (PCBs) of electrical and electronic equipment by hydrometallurgical techniques. Samples, after a milling step, were leached by aqua regia varying the operative conditions. Parameters such as lixiviant concentration, solid/liquid ratio and temperature were investigated. Pd was separated from the leach solution by solvent extraction using Aliquat 336 as an extractant in limonene. This solvent was studied as alternative to the usual ones because it is a renewable organic diluent, with low-toxicity and easily available. After the extraction the organic phase was treated with sodium borohydride to precipitate metallic palladium obtaining a recovery rate of 83% with a purity grade of 98.8%. Based on the results of the present study, a process flow sheet was proposed for industrial implementation.

Vorheriger Artikel Chemical characterization and toxicity assessment for the sustainable management of end of life cathode ray tubes

Nächster Artikel Solar pyrolysis of scrap tire: optimization of operating parameters

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Hagelüken C (2006) Markets for the catalyst metals platinum, palladium and rhodium. Metall 1–2:31–42

Report on Critical raw materials for the EU—European Commission (2014)

Cui H, Anderson CG (2016) Literature review of hydrometallurgical recycling of printed circuit boards (PCBs). J Adv Chem Eng 6(1). https://doi.org/10.4172/2090-4568.1000142

Zhang Z, Zhang FS (2014) Selective recovery of palladium from waste printed circuit boards by a novel non-acid process. J Hazard Mater 279:46–51. https://doi.org/10.1016/j.jhazmat.2014.06.045 CrossRef

Park YJ, Fray DJ (2009) Recovery of high purity precious metals from printed circuit boards. J Hazard Mater 164:1152–1158. https://doi.org/10.1016/j.jhazmat.2008.09.043 CrossRef

Prabaharan G, Barik SP, Kumar B (2016) A hydrometallurgical process for recovering total metal values from waste monolithic ceramic capacitors. Waste Manag 52:302–308. https://doi.org/10.1016/j.wasman.2016.04.010 CrossRef

Suoranta T, Zugazua O, Niemelä M, Perämäki P (2015) Recovery of palladium, platinum, rhodium and ruthenium from catalyst materials using microwave-assisted leaching and cloud point extraction. Hydromet 154:56–62. https://doi.org/10.1016/10.1016/j.hydromet.2015.03.014 CrossRef

Reddy BR, Raju B, Lee JY, Park HK (2010) Process for the separation and recovery of palladium and platinum from spent automobile catalyst leach liquor using LIX 84I and Alamina 336. J Hazard Mater 180:253–258. https://doi.org/10.1016/j.jhazmat.2010.04.022 CrossRef

Traeger J, König J, Städtke A, Holdt HJ (2012) Development of solvent extraction system with 1,2-bis(2-methoxyethylthio)benzene for the selective separation of palladium(II) from secondary raw materials. Hydromet 127–128:30–38. https://doi.org/10.1016/j.hydromet.2012.07.002 CrossRef

10.

Yamada M, Gandhi MR, Kondo Y, Shibayama A, Hamada F (2015) Feasibility studies on palladium extraction from leach liquors of automotive catalysts using p-diethylphosphonomethylthiacalix[6]arene. Separ Sci Technol 50(13):1964–1973. https://doi.org/10.1080/01496395.2015.1014913

11.

Sarioğlan S (2013) Recovery of palladium from spent activated carbon-supported palladium catalysts. Platin Met Rev 57(4):289–296. https://doi.org/10.1595/147106713x663988 CrossRef

12.

Behnamfard A, Salarirad M, Vegliò F (2013) Process development for recovery of copper and precious metals from waste printed circuit boards with emphasize on palladium and gold leaching and precipitation. Waste Manag 33:2354–2363. https://doi.org/10.1016/j.wasman.2013.07.017 CrossRef

13.

Viñals J, Juan E, Ruiz M, Ferrando E, Cruells M, Roca A, Casado J (2006) Leaching of gold and palladium with aqueous ozone in dilute chloride media. Hydromet 81:142–151. https://doi.org/10.1016/j.hydromet.2005.12.004 CrossRef

14.

Malik P, Paiva AP (2010) A novel solvent extraction route for the mutual separation of platinum, palladium and rhodium in hydrochloric acid media. Solvent Extr Ion Exc 28:49–72. https://doi.org/10.1080/07366290903408599 CrossRef

15.

Nogueira CA, Paiva AP, Oliveira PC, Costa MC, Rosa da Costa AM (2014) Oxidative leaching process with cupric ion in hydrochloric acid media for recovery of Pd and Rh from spent catalytic converters. J Hazard Mat 278:82–90. doi:https://doi.org/10.1016/j.jhazmat.2014.05.099 CrossRef

16.

Swain B, Jeong J, Kim SK, Lee JC (2010) Separation of platinum and palladium from chloride solution by solvent extraction using Alamina 300. Hydromet 104:1–7. https://doi.org/10.1016/j.hydromet.2010.03.013 CrossRef

17.

Peng CY, Tsai TH (2012) Recovery of palladium from acidic chloride solution using kerosene containing tri-n-octyl/decyl amine (Alamine 336). Desal Water Treat 47:105–111. https://doi.org/10.1080/19443994.2012.696803 CrossRef

18.

Wei W, Cho CW, Kim S, Song MH, Bediako JK, Yun YS (2016) Selective recovery of Au(III), Pt(IV), and Pd(II) from aqueous solutions by liquid-liquid extraction using ionic liquid Aliquat-336. J Molec Liq 216:18–24. https://doi.org/10.1016/j.molliq.2016.01.016 CrossRef

19.

Nguyen TH, Sonu CH, Lee MS (2015) Separation of platinum(IV) and palladium(II) from concentrated hydrochloric acid solutions by mixtures of amines with neutral extractants. J Indus Eng Chem 32:238–245. https://doi.org/10.1016/j.jiec.2015.08.022 CrossRef

20.

Rane MV, Venugopal V (2006) Study on the extraction of palladium(II) and platinum(IV) using LIX 84I. Hydromet 84:54–59. https://doi.org/10.1016/j.hydromet.2006.04.005 CrossRef

21.

Lee JY, Raju B, Kumar BN, Kumar JR, Park HK, Reddy BR (2010) Solvent extraction separation and recovery of palladium and platinum from chloride leach liquors of spent automobile catalyst. Sep Purif Technol 73:213–218. https://doi.org/10.1016/j.seppur.2010.04.003 CrossRef

22.

El-Hefny NE, Daoud JA (2013) Solvent extraction of palladium(II) from aqueous chloride medium by triphenylphosphine, triphenylphosphine oxide or triphenylphosphine sulphide in benzene. J Phys Sci 24(2):35–47

23.

Wu SP (2013) Extraction of palladium(II) from hydrochloride solutions with 2-n-octyl-4-isothiazolin-3-one as novel extractant. Rare Met 32(4):425–430. https://doi.org/10.1007/s12598-013-0070-9 CrossRef

24.

Cieszynska A, Wisniewski M (2012) Extractive recovery of palladium(II) from hydrochloric acid solutions with Cyphos IL 104. Hydromet 113–114:79–85. https://doi.org/10.1016/j.hydromet.2011.12.006 CrossRef

25.

Cieszynska A, Wisniewski M (2010) Extraction of palladium(II) from chloride solutions with Cyphos IL 101/toluene mixtures as novel extractant. Sep Purif Technol 73:202–207. https://doi.org/10.1016/j.seppur.2010.04.001 CrossRef

26.

Othman N, Noah NFM, Sulaiman RNR, Bachok SK (2014) Liquid–liquid extraction of palladium from simulated liquid waste using phosphinic acid as a carrier. J Teknologi 68(5):41–45

27.

Gupta B, Singh I (2013) Extraction and separation of platinum, palladium and rhodium using Cyanex 923 and their recovery from real samples. Hydromet 134–135:11–18. https://doi.org/10.1016/j.hydromet.2013.01.001 CrossRef

28.

Ortet O, Paiva AP (2015) Development of tertiary thioamide derivatives to recover palladium(II) from simulated complex chloride solutions. Hydromet 151:33–41. https://doi.org/10.1016/j.hydromet.2014.11.001 CrossRef

29.

Paiva AP, Martins ME, Ortet O (2015) Palladium(II) recovery from hydrochloric acid solutions by N,N′-dimethyl-N,N′-dibutylthiodiglycolamide. Metals 5:2303–2315. https://doi.org/10.3390/met5042303 CrossRef

30.

Pan L, Zhang Z (2009) Solvent extraction and separation of palladium(II) and platinum(IV) from hydrochloric acid medium with dibutyl sulfoxide. Miner Eng 22:1271–1276. https://doi.org/10.1016/j.mineng.2009.07.006 CrossRef

31.

UNEP (2013) Metal recycling—opportunities, limits, infrastructures. http://www.unep.org/resourcepanel/Portals/24102/PDFs/Metal_Recycling_Full_Report.pdf

32.

Brunori C, Cafiero L, De Carolis R, Fontana D, Guzzinati R, Pietrantonio M, Pucciarmati S, Torelli GN, Trinca E, Tuffi R (2015) Innovative technologies for metals recovery and plastic valorisation from electric and electronic waste: an integrated approach. Environ Eng Manag J 14(7):1553–1562

33.

Brunori C, Fontana D, De Carolis R, Pietrantonio M, Pucciarmati S, Guzzinati R, Torelli GN (2014) Hydrometallurgical process to recover valuable materials from printed circuit boards. Patent application n PCTIB2014065131

34.

Kim YW, Kim MJ, Chung BY, Bang du Y, Lim SK, Choi SM, Lim DS, Cho MC, Yoon K, Kim HS, Kim KB, Kim YS, Kwack SJ, Lee BM (2013) Safety evaluation and risk assessment of d-Limonene. J Toxicol Environ Health B Crit Rev 16(1):17–38. https://doi.org/10.1080/10937404.2013.769418 CrossRef

35.

Hagelüken C (2012) Recycling the platinum group metals: a European perspective. Platin Met Rev 56(1):29–35. https://doi.org/10.1595/147106712X611733 CrossRef

36.

Levitin G, Schmuckler G (2003) Solvent extraction of rhodium chloride from aqueous solutions and its separation from palladium and platinum. React Funct Polym 54:149–154. https://doi.org/10.1016/S1381-5148(02)00190-6 CrossRef

37.

Kumar ASK, Sharma S, Reddy RS, Barathi M, Rajesh N (2015) Comprehending the interaction between chitosan and ionic liquid for the adsorption of palladium. Inter J Biolog Macrom 72:633–639. https://doi.org/10.1016/j.ijbiomac.2014.09.002 CrossRef

38.

Ruiz M, Sastre AM, Guibal E (2000) Palladium sorption on glutaraldehyde-crosslinked chitosan. React Funct Polym 45:155–173. https://doi.org/10.1016/S1381-5148(00)00019-5 CrossRef

Titel: Palladium recovery from monolithic ceramic capacitors by leaching, solvent extraction and reduction
verfasst von: Danilo Fontana
Massimiliana Pietrantonio
Stefano Pucciarmati
Giorgia Nadia Torelli
Chiara Bonomi
Federica Masi
Publikationsdatum: 24.11.2017
Verlag: Springer Japan
Erschienen in: Journal of Material Cycles and Waste Management / Ausgabe 2/2018
Print ISSN: 1438-4957
Elektronische ISSN: 1611-8227
DOI: https://doi.org/10.1007/s10163-017-0684-3

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