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07.11.2022 | Original Article

PdPbBi nanoalloys anchored reduced graphene-wrapped metal–organic framework-derived catalyst for enhancing ethylene glycol electrooxidation

verfasst von: Zhi-Rui Wu, Yu-Ting Zhong, Xiao-Guang Liu, Ling Li

Erschienen in: Rare Metals | Ausgabe 2/2023

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Abstract

For future clean energy demand, it is essential to develop highly efficient and durable materials for use in renewable energy conversion devices. Herein, we report an electrocatalyst loaded with Pd-Pb-Bi nanoalloys on reduced graphene (rGO)-wrapped In₂O₃ (PdPbBi@rGO/In₂O₃) prepared by a hydrothermal method. PdPbBi@rGO/In₂O₃ exhibits higher forward current density (229.12 mA·cm⁻²), larger electrochemical active surface area (ECSA) (85.87 m²·g⁻¹_Pd), smaller impedance (12.68 Ω) and lower E_onset (−0.56 V) than commercial Pd/C. Specifically, the current density and ECSA are 8.46 and 3.38 times higher than those of commercial Pd/C (27.07 mA·cm⁻², 25.41 m²·g⁻¹_Pd), respectively. Furthermore, the oxidation mechanism of ethylene glycol and the removal of carbon monoxide [CO]_ads from the surface of Pd are also discussed in detail. The columnar support structure wrapped by rGO provides a huge active surface area for catalysis. Moreover, the electronic effect of Pd-Pb-Bi nanoalloys can accelerate the removal of CO intermediate species, obtain more Pd active sites and improve the electrocatalytic performance. Our first synthesis of this highly electrocatalyst offers promising value for commercial application in direct fuel cells.

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Vorheriger Artikel Enhanced breakdown strength and energy storage density of AgNbO3 ceramics via tape casting

Nächster Artikel Ni3FeN anchored on porous carbon as electrocatalyst for advanced Li–S batteries

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Titel: PdPbBi nanoalloys anchored reduced graphene-wrapped metal–organic framework-derived catalyst for enhancing ethylene glycol electrooxidation
verfasst von: Zhi-Rui Wu
Yu-Ting Zhong
Xiao-Guang Liu
Ling Li
Publikationsdatum: 07.11.2022
Verlag: Nonferrous Metals Society of China
Erschienen in: Rare Metals / Ausgabe 2/2023
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI: https://doi.org/10.1007/s12598-022-02180-1

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