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Journal of Nanoparticle Research

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01.07.2019 | Research Paper

Plasmon-enhanced photocatalytic activity of Pt@Au and Pt@Cu nanoparticles in quantum size regime

verfasst von: Yong-Jie Lin, Si-Jing Ding, Kai Chen, Da-Jie Yang, Ying Xie, Zhong-Hua Hao, Li Zhou, Qu-Quan Wang

Erschienen in: Journal of Nanoparticle Research | Ausgabe 7/2019

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Abstract

We have synthesized Pt@Au and Pt@Cu bimetallic nanoparticles and investigated their surface plasmon resonance (SPR) and plasmon-enhanced photocatalytic activity in the quantum size regime. The SPR wavelength of Pt@Au bimetallic nanoparticles monotonously blue-shifts as the thickness of Pt shell increases comparing with the quantum-sized Au core nanoparticles with diameter d_Au = 3.6 ± 0.4 nm. On the other hand, the SPR of Pt@Cu bimetallic nanoparticles blue-shifts at first and then red-shifts as the Pt shell thickness increases comparing to the quantum-sized Cu core nanoparticles with diameter d_Cu = 3.7 ± 0.5 nm. Then, we comparatively investigated the photocatalytic activities of the Pt@Au nanoparticles with quantum and classical sizes. The photocatalytic rate for 4-NP:NaBH₄ is enhanced 2 times by the strong plasmon resonance and the large surface area/volume ratio of quantum-sized Pt@Au nanoparticles. Additionally, the increasing photocatalytic activity of the quantum-sized Pt@Cu with the increase of Pt shell thickness is also observed. These findings reveal the significance of the quantum plasmon resonance on the enhancement of photocatalytic activity.

Vorheriger Artikel Double redox couples manganese oxide nanorods with tunable oxygen defects and their catalytic combustion properties

Nächster Artikel Comparison of biological markers in aerosol-weighed workplaces

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Titel: Plasmon-enhanced photocatalytic activity of Pt@Au and Pt@Cu nanoparticles in quantum size regime
verfasst von: Yong-Jie Lin
Si-Jing Ding
Kai Chen
Da-Jie Yang
Ying Xie
Zhong-Hua Hao
Li Zhou
Qu-Quan Wang
Publikationsdatum: 01.07.2019
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 7/2019
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-019-4581-7

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