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Colloid and Polymer Science

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06.02.2019 | Original Contribution

Polymer-particulate composites with differential interfaces: synthesis, characterization, and mathematical modeling to evaluate interface-yield strength correlations

verfasst von: Adeel Afzal, Humaira M. Siddiqi, Shahzad Sarwar, Zakya Rubab, Adnan Mujahid

Erschienen in: Colloid and Polymer Science | Ausgabe 4/2019

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Abstract

Polymer particulate composites (PPC) are extensively used in numerous mechanical and aviation applications, which take advantage of their synergistic properties such as superior yield strength. This work combines experimental and theoretical approaches to evaluate yield strength of thermosetting PPC made of pristine p-TiO₂ or surface-grafted g-TiO₂ nanoparticles and an epoxy thermoset. Accordingly, p-PPC and g-PPC sheets containing different volume fraction (ϕ_f = 0.0234–0.0936) of p-TiO₂ or g-TiO₂ nanoparticles exhibit variable yield strength. A mathematical model is used to evaluate the effects of nanoparticles aggregation on the relative yield strength of PPC. The interfacial parameters “B” and “B_agg” give a quantitative measure of the ability of stress dispersion by the agglomerated nanoparticles. The higher “B” and “B_agg” values for g-PPC reveal its greater interfacial strength. The experimental data show good correlation with the theoretical predictions. However, these models truly predict PPC’s yield strength only at low volume fraction (ϕ_f ≤ 0.09) of filler nanoparticles.

Vorheriger Artikel A re-formulation of the Mori–Tanaka method for predicting material properties of fiber-reinforced polymers/composites

Nächster Artikel Characterization of PMMA-b-PDMAEMA aggregates in aqueous solutions

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Titel: Polymer-particulate composites with differential interfaces: synthesis, characterization, and mathematical modeling to evaluate interface-yield strength correlations
verfasst von: Adeel Afzal
Humaira M. Siddiqi
Shahzad Sarwar
Zakya Rubab
Adnan Mujahid
Publikationsdatum: 06.02.2019
Verlag: Springer Berlin Heidelberg
Erschienen in: Colloid and Polymer Science / Ausgabe 4/2019
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI: https://doi.org/10.1007/s00396-019-04477-7

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