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Erschienen in: Polymer Bulletin 5/2010

01.09.2010 | Original Paper

PP/clay nanocomposite: optimization of mixing conditions with respect to mechanical properties

verfasst von: H. Kubišová, D. Měřínská, P. Svoboda

Erschienen in: Polymer Bulletin | Ausgabe 5/2010

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Abstract

Polypropylene/clay nanocomposites were studied with focus on optimization of mixing conditions. Two different types of commercial nanofillers Dellite® were used (Dellite® 72T and Dellite® 67G). Effect of various concentrations of fillers on morphology and mechanical properties was investigated. Conditions of preparation were varied with respect to mixing time and speed of rotation of kneaders. Results of morphology study showed that nanocomposites contained agglomerates of nanofillers. The comparison of the filler types revealed that better dispersion and distribution was found for nanocomposites containing Dellite 72T which had also better tensile strength. Optimum mixing time was 30 min. 3D graphical analysis showed that the optimum speed of rotation was 60 rpm and with increasing clay content (2–10 wt%) the tensile strength increased.

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Literatur
1.
Zurück zum Zitat Nam PH et al (2001) A hierarchal structure and properties of intercalated polypropylene/clay nanocomposites. Polymer 42:9633–9640 Nam PH et al (2001) A hierarchal structure and properties of intercalated polypropylene/clay nanocomposites. Polymer 42:9633–9640
2.
Zurück zum Zitat Svoboda P et al (2002) Morphology and mechanical properties of polypropylene/organoclay nanocomposites. J Appl Polym Sci 85:1562–1570 Svoboda P et al (2002) Morphology and mechanical properties of polypropylene/organoclay nanocomposites. J Appl Polym Sci 85:1562–1570
3.
Zurück zum Zitat Zhong Y et al (2007) Mechanical and oxygen barrier properties of organoclay-polyethylene nanocomposites films. Polym Eng Sci 47:1101–1107 Zhong Y et al (2007) Mechanical and oxygen barrier properties of organoclay-polyethylene nanocomposites films. Polym Eng Sci 47:1101–1107
4.
Zurück zum Zitat Shaofeng W et al (2003) Preparation of polyethylene-clay nanocomposites directly from Na montmorillonite by a melt intercalation method. J Appl Poly Sci 89:2583–2585 Shaofeng W et al (2003) Preparation of polyethylene-clay nanocomposites directly from Na montmorillonite by a melt intercalation method. J Appl Poly Sci 89:2583–2585
5.
Zurück zum Zitat Vlasveld DNP et al (2005) Analysis of the modulus of polyamide-6 silicate nanocomposites using moisture controlled variation of the matrix properties. Polymer 46:6102–6113 Vlasveld DNP et al (2005) Analysis of the modulus of polyamide-6 silicate nanocomposites using moisture controlled variation of the matrix properties. Polymer 46:6102–6113
6.
Zurück zum Zitat Fornes TD et al (2005) Effect of organoclay structure on nylon 6 nanocomposite morphology and properties. Polymer 46:8641–8660 Fornes TD et al (2005) Effect of organoclay structure on nylon 6 nanocomposite morphology and properties. Polymer 46:8641–8660
7.
Zurück zum Zitat Morgan AB, Chu L-L, Harris JD (2005) A flammability performance comparison between synthetic and natural clays in polystyrene nanocomposites. Fire Mater 29:213–229 Morgan AB, Chu L-L, Harris JD (2005) A flammability performance comparison between synthetic and natural clays in polystyrene nanocomposites. Fire Mater 29:213–229
8.
Zurück zum Zitat Nazarenko S et al (2005) Gas barrier of polystyrene montmorillonite clay nanocomposites: effect of mineral layer aggregation. Fire Mater 29:213–229 Nazarenko S et al (2005) Gas barrier of polystyrene montmorillonite clay nanocomposites: effect of mineral layer aggregation. Fire Mater 29:213–229
9.
Zurück zum Zitat Kato M, Usuki A, Okada A (1997) Synthesis of polypropylene oligomer-clay intercalation compounds. J Appl Polym Sci 66:1781–1785 Kato M, Usuki A, Okada A (1997) Synthesis of polypropylene oligomer-clay intercalation compounds. J Appl Polym Sci 66:1781–1785
10.
Zurück zum Zitat Tjong SC, Meng YZ (2003) Impact-modified polypropylene/vermiculite nanocomposites. J Polym Sci B 41:2332–2341 Tjong SC, Meng YZ (2003) Impact-modified polypropylene/vermiculite nanocomposites. J Polym Sci B 41:2332–2341
11.
Zurück zum Zitat Tjong SC, Meng YZ, Xu Y (2002) Preparation and properties of polyamide6/polypropylene-vermiculite nanocomposite/polyamide 6 alloys. J Appl Polym Sci 86:2330–2337 Tjong SC, Meng YZ, Xu Y (2002) Preparation and properties of polyamide6/polypropylene-vermiculite nanocomposite/polyamide 6 alloys. J Appl Polym Sci 86:2330–2337
12.
Zurück zum Zitat Ku BC, Froio D, Steeves D, Kim DW, Ahn H, Ratto JA et al (2004) Cross-linked multilayer polymer-clay nanocomposites and permeability properties. J Macromol Sci A 41:2441–2446 Ku BC, Froio D, Steeves D, Kim DW, Ahn H, Ratto JA et al (2004) Cross-linked multilayer polymer-clay nanocomposites and permeability properties. J Macromol Sci A 41:2441–2446
13.
Zurück zum Zitat Wu T-M, L Yi-H, Hsu S-F (2004) Isothermal crystallization kinetics and melting behavior of nylon/saponite and nylon/montmorillonite nanocomposites. J Appl Polym Sci 94:2196–2204 Wu T-M, L Yi-H, Hsu S-F (2004) Isothermal crystallization kinetics and melting behavior of nylon/saponite and nylon/montmorillonite nanocomposites. J Appl Polym Sci 94:2196–2204
14.
Zurück zum Zitat Nguyen QT, Baird DG (2007) An improved technique for exfoliating and dispersing nanoclay particles into polymer matrices using supercritical carbon dioxide. Polymer 48:6923–6933 Nguyen QT, Baird DG (2007) An improved technique for exfoliating and dispersing nanoclay particles into polymer matrices using supercritical carbon dioxide. Polymer 48:6923–6933
15.
Zurück zum Zitat Hasegava N, Usuki A (2004) Silicate laver exfoliation in polvolefin/clay nanocomposites based on maleic anhydride modified polyolefins and organophilic clay. J Appl Polym Sci 93:464–470 Hasegava N, Usuki A (2004) Silicate laver exfoliation in polvolefin/clay nanocomposites based on maleic anhydride modified polyolefins and organophilic clay. J Appl Polym Sci 93:464–470
16.
Zurück zum Zitat Martin D et al (2003) Polyethylene/layered silicate nanocomposites for rotational moulding. Polymer Int 52:1774–1779 Martin D et al (2003) Polyethylene/layered silicate nanocomposites for rotational moulding. Polymer Int 52:1774–1779
Metadaten
Titel
PP/clay nanocomposite: optimization of mixing conditions with respect to mechanical properties
verfasst von
H. Kubišová
D. Měřínská
P. Svoboda
Publikationsdatum
01.09.2010
Verlag
Springer-Verlag
Erschienen in
Polymer Bulletin / Ausgabe 5/2010
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-010-0269-y

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