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Erschienen in: Journal of Materials Science: Materials in Electronics 9/2017

25.01.2017

Pre-wetted treatment for optimized multicrystalline Si wafer texturing and its solar cell efficiency improvement

verfasst von: Qiqi Hua, Chenfan Yang, Yajie Wang, Tiezheng Lv

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 9/2017

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Abstract

We report a simple way to optimize texturing of multi-crystalline Si (mc-Si) wafer by pre-wetted surface in the wet etching. In the range of 300–1200 nm, a better texturing surface was achieved with average reflectivity <20%. We could explain the low reflectivity from surface morphology difference of SEM pictures. Further, standard solar cells have been finished. Obvious improvement in short circuit current (>40 mA) and efficiency (0.1% absolute) has been achieved compared with control cell without deterioration of other performance parameters (such as open circuit voltage and fill factor). Internal quantum efficiency measurement also proves the lower front surface recombination velocity of pre-wetted based solar cell. We believe that the improved wetting surface property of multi-crystalline Si prior to etching is important for optimizing texturing process, and pre-wetted treatment is easy integrated for industrial mass production.

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Literatur
1.
Zurück zum Zitat C. Breyer, A. Gerlach, Global overview on grid-parity. Prog. Photovolt. Res. Appl. 21(1), 121–136 (2013)CrossRef C. Breyer, A. Gerlach, Global overview on grid-parity. Prog. Photovolt. Res. Appl. 21(1), 121–136 (2013)CrossRef
2.
Zurück zum Zitat A. Goetzberger, C. Hebling, H.-W. Schock, Photovoltaic materials history status and outlook. Mater. Sci. Eng. Res. 40, 1–46 (2003)CrossRef A. Goetzberger, C. Hebling, H.-W. Schock, Photovoltaic materials history status and outlook. Mater. Sci. Eng. Res. 40, 1–46 (2003)CrossRef
3.
Zurück zum Zitat A.W. Weeber, A.R. Burgers, M.J.A.A. Goris, M. Koppes, E.J. Kossen, H.C. Rieffe, W.J. Soppe, C.J.J. Tool, J.H. Bultman, 16% mc-Si cell efficiencies using industrial in-line processing, in Proceedings of 19th EPVSEC, Paris (2004), pp. 532–555 A.W. Weeber, A.R. Burgers, M.J.A.A. Goris, M. Koppes, E.J. Kossen, H.C. Rieffe, W.J. Soppe, C.J.J. Tool, J.H. Bultman, 16% mc-Si cell efficiencies using industrial in-line processing, in Proceedings of 19th EPVSEC, Paris (2004), pp. 532–555
4.
Zurück zum Zitat U. Gangopadhyay, S.K. Dhungel, P.K. Basu, S.K. Dutta, H. Saha, J. Yi, Comparative study of different approaches of multicrystalline silicon texturing for solar cell fabrication. Sol. Energy Mater. Sol. Cells 91, 285–289 (2007)CrossRef U. Gangopadhyay, S.K. Dhungel, P.K. Basu, S.K. Dutta, H. Saha, J. Yi, Comparative study of different approaches of multicrystalline silicon texturing for solar cell fabrication. Sol. Energy Mater. Sol. Cells 91, 285–289 (2007)CrossRef
5.
Zurück zum Zitat W.A. Nositschka, C. Beneking, O. Voigt, H. Kurz, Texturisation of multicyrstalline silicon wafers for solar cells by reactive ion etching through colloidal masks. Sol. Energy Mater. Sol. Cells 76, 155–166 (2003)CrossRef W.A. Nositschka, C. Beneking, O. Voigt, H. Kurz, Texturisation of multicyrstalline silicon wafers for solar cells by reactive ion etching through colloidal masks. Sol. Energy Mater. Sol. Cells 76, 155–166 (2003)CrossRef
6.
Zurück zum Zitat Y. Nishimoto, T. Ishihara, K. Namba, Investigation of acidic texturization for multicrystalline silicon solar cells. J. Electrochem. Soc 146, 457–461 (1999)CrossRef Y. Nishimoto, T. Ishihara, K. Namba, Investigation of acidic texturization for multicrystalline silicon solar cells. J. Electrochem. Soc 146, 457–461 (1999)CrossRef
7.
Zurück zum Zitat M. Steinert, J. Acker, A. Henge, K. Wetzig, Experimental studies on the mechanism of wet chemical etching of silicon in HF/ HNO3 mixtures. J. Electrochem. Soc 152(12), C843–C850 (2005)CrossRef M. Steinert, J. Acker, A. Henge, K. Wetzig, Experimental studies on the mechanism of wet chemical etching of silicon in HF/ HNO3 mixtures. J. Electrochem. Soc 152(12), C843–C850 (2005)CrossRef
8.
Zurück zum Zitat D.H. Macdonald, A. Cuevas, M.J. Kerr, C. Samundsett, D. Ruby, S. Winderbaum, A. Leo, Texturing industrial multicrystalline silicon solar cells. Sol. Energy 76, 277–283 (2004)CrossRef D.H. Macdonald, A. Cuevas, M.J. Kerr, C. Samundsett, D. Ruby, S. Winderbaum, A. Leo, Texturing industrial multicrystalline silicon solar cells. Sol. Energy 76, 277–283 (2004)CrossRef
9.
Zurück zum Zitat H.C. Yuan, V.E. Yost, M.R. Page et al., Efficient black silicon solar cell with a density-graded nanoporous surface: optical properties, performance limitations, and design rules. Appl. Phys. Lett. 95, 123501 (2009)CrossRef H.C. Yuan, V.E. Yost, M.R. Page et al., Efficient black silicon solar cell with a density-graded nanoporous surface: optical properties, performance limitations, and design rules. Appl. Phys. Lett. 95, 123501 (2009)CrossRef
10.
Zurück zum Zitat R. Torres, V. Vervisch, M. Halbwax et al., Femtosecond laser texturization for improvement of photo voltaic cells: black silicon. J. Optoelectron. Adv. Mater 12, 621–625 (2010) R. Torres, V. Vervisch, M. Halbwax et al., Femtosecond laser texturization for improvement of photo voltaic cells: black silicon. J. Optoelectron. Adv. Mater 12, 621–625 (2010)
11.
Zurück zum Zitat M.A. Gosalvez, B. Tang, P. Pal, K. Sato, Y. Kimura, K. Ishibashi, Orientation and concentration dependent surfactant adsorption on silicon in aqueous alkaline solutions: explaining the changes in the etch rate, roughness and undercutting for MEMS applications. J. Micromech. Microeng. 19, 125011 (2009)CrossRef M.A. Gosalvez, B. Tang, P. Pal, K. Sato, Y. Kimura, K. Ishibashi, Orientation and concentration dependent surfactant adsorption on silicon in aqueous alkaline solutions: explaining the changes in the etch rate, roughness and undercutting for MEMS applications. J. Micromech. Microeng. 19, 125011 (2009)CrossRef
12.
Zurück zum Zitat H.M. Branz, V.E. Yost, S. Ward, K.M. Jones, B. To, P. Stradins, Nanostructured black silicon and the optical reflectance of grade-density surfaces. Appl. Phys. Lett. 94, 231121(1)–231121(3) (2009)CrossRef H.M. Branz, V.E. Yost, S. Ward, K.M. Jones, B. To, P. Stradins, Nanostructured black silicon and the optical reflectance of grade-density surfaces. Appl. Phys. Lett. 94, 231121(1)–231121(3) (2009)CrossRef
13.
Zurück zum Zitat S.W. Park, D.S. Kim, S.H. Lee, New approach to isotropic texturing techniques on multicrystalline silicon wafers. J. Mater. Sci. Mater. Electron. 12, 619–622 (2001)CrossRef S.W. Park, D.S. Kim, S.H. Lee, New approach to isotropic texturing techniques on multicrystalline silicon wafers. J. Mater. Sci. Mater. Electron. 12, 619–622 (2001)CrossRef
14.
Zurück zum Zitat M. Grundner, H. Jacob, Investigations on hydrophilic and hydrophobic silicon (100) wafer surfaces by X-ray photoelectron and high-resolution electron energy loss-spectroscopy. Appl. Phys. A 39, 73–82 (1986)CrossRef M. Grundner, H. Jacob, Investigations on hydrophilic and hydrophobic silicon (100) wafer surfaces by X-ray photoelectron and high-resolution electron energy loss-spectroscopy. Appl. Phys. A 39, 73–82 (1986)CrossRef
15.
Zurück zum Zitat M.A. Green, Silicon Solar Cells—Advanced Principles & Practice, vol. 2 (University of New South Wales, New South Wales, 1995) M.A. Green, Silicon Solar Cells—Advanced Principles & Practice, vol. 2 (University of New South Wales, New South Wales, 1995)
17.
Zurück zum Zitat D. Kumar, S.K. Srivastava, P.K. Singh, K.N. Sood, V.N. Singh, N. Dilawar, M. Husain, Room temperature growth of wafer-scale silicon nanowire arrays and their Raman characteristics. J. Nanopart. Res 12, 2267–2276 (2010)CrossRef D. Kumar, S.K. Srivastava, P.K. Singh, K.N. Sood, V.N. Singh, N. Dilawar, M. Husain, Room temperature growth of wafer-scale silicon nanowire arrays and their Raman characteristics. J. Nanopart. Res 12, 2267–2276 (2010)CrossRef
Metadaten
Titel
Pre-wetted treatment for optimized multicrystalline Si wafer texturing and its solar cell efficiency improvement
verfasst von
Qiqi Hua
Chenfan Yang
Yajie Wang
Tiezheng Lv
Publikationsdatum
25.01.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 9/2017
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-017-6380-1

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