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16.10.2020 | Original Research

Preparation and application of dialdehyde nanocellulose reinforced jatropha oil based polymer emulsions as leather fatliquors

verfasst von: Jianzhong Ma, Tiantian Wang, Shuai Yu, Yuehong Zhang, Bin Lyu

Erschienen in: Cellulose | Ausgabe 1/2021

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Abstract

Bio-based acrylated epoxidized jatropha oil (AEJO) was developed using a solvent-free synthetic method, and the structure of the resulting product was confirmed by Fourier transform infrared spectroscopy and proton nuclear magnetic resonance (¹H NMR) spectra. Subsequently, an amphiphilic polymer emulsion AEJO-AA was prepared by emulsion polymerization using acrylic acid (AA) and AEJO. Moreover, 2, 3-dialdehyde nanocellulose (DNC) was prepared and combined with AEJO-AA emulsion as a fatliquoring agent for goatskin upper leather. The fatliquored leather shows improved mechanical strength and thermal stability. When the DNC loading is 1.5 wt%, the fatliquored leather exhibits the highest tensile strength of 24.3 MPa, tear strength of 62.2 N/mm and thermal denaturation temperature (T_d) of 95.4 °C. The fogging values of the fatliquored leather satisfy the requirements of automobile seat leather. The biochemical oxygen demand (BOD₅) and chemical oxygen demand results indicate that the DNC/AEJO-AA emulsion is easily biodegradable. Overall, the developed DNC/AEJO-AA emulsion provides a new strategy in the production of bio-based and ecological polymer fatliquor of leather.

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Vorheriger Artikel Water retention value predicts biomass recalcitrance for pretreated biomass: biomass water interactions vary based on pretreatment chemistry and reflect composition

Nächster Artikel Cellulose phenylcarbamate-derived hybrid bead-type chiral packing materials for efficient chiral recognition

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Titel: Preparation and application of dialdehyde nanocellulose reinforced jatropha oil based polymer emulsions as leather fatliquors
verfasst von: Jianzhong Ma
Tiantian Wang
Shuai Yu
Yuehong Zhang
Bin Lyu
Publikationsdatum: 16.10.2020
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 1/2021
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-020-03494-y

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Abstract

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