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Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 11/2014

01.11.2014 | Original Contribution

Preparation and characterization of composite membranes with Brønsted acidic ionic liquid

verfasst von: Yi Yang, Hejun Gao, Fei Lu, Liqiang Zheng

Erschienen in: Colloid and Polymer Science | Ausgabe 11/2014

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Abstract

Poly-(vinyl alcohol) (PVA) proton-conducting composite membranes were prepared using succinic acid (SA) as a cross-linking agent and Brønsted acidic ionic liquid (BAIL) as a proton source. The incorporated BAILs resulted in a relatively high proton conductivity compared with PVA/SA membrane without BAILs. The proton conductivities of PVA/SA/BAIL composite membranes increased versus the BAIL content. In addition, the optimal resultant proton conductivity of PVA/SA/BAIL composite membrane under dry condition could reach 0.4 mS/cm at 140 °C, which was higher than that of PVA/sulfosuccinic acid (SSA) composite membrane (0.032 mS/cm), PVA/SSA/5-aminotetrazole membrane (0.022 mS/cm at 130 °C), and PVA/chlorosulfonic acid/glutaraldehyde membrane (0.0585 mS/cm at 90 °C) measured at the same condition. It was notable that the PVA/SA/BAIL composite membranes could reach high thermal stability up to 150 °C, which was higher than that of traditional PVA membranes (below 80 °C).
Vorheriger Artikel Micellization of anionic gemini surfactants and their interaction with polyacrylamide
Nächster Artikel Impact of PS/SiO2 morphologies on the SERS activity of PS/SiO2/Ag nanocomposite particles

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Metadaten
Titel
Preparation and characterization of composite membranes with Brønsted acidic ionic liquid
verfasst von
Yi Yang
Hejun Gao
Fei Lu
Liqiang Zheng
Publikationsdatum
01.11.2014
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 11/2014
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-014-3324-7

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