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Polymer Bulletin
Erschienen in: Polymer Bulletin 4/2012

01.03.2012 | Original Paper

Preparation and characterization of sodium alginate/poly(N-isopropylacrylamide)/clay semi-IPN magnetic hydrogels

verfasst von: Zhiqiang Li, Jianfeng Shen, Hongwei Ma, Xin Lu, Min Shi, Na Li, Mingxin Ye

Erschienen in: Polymer Bulletin | Ausgabe 4/2012

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Abstract

pH- and temperature-responsive semi-interpenetrating magnetic nanocomposite hydrogels (NC hydrogels) were prepared by using linear sodium alginate (SA), poly(N-isopropylacrylamide) (PNIPAM) and Fe3O4 nanoparticles with inorganic clay as an effective multifunctional cross-linker. The effects of cross-linker and SA contents on various physical properties were investigated. The NC hydrogels exhibited a volume phase transition temperature (VPTT) around 32 °C with no significant deviation from the conventional chemically cross-linked PNIPAM hydrogels (OR hydrogels). The swelling ratios of NC hydrogels were much larger than those of OR hydrogels. Moreover, the swelling ratios of NC hydrogels gradually decreased with increasing the contents of clay and increased with increasing the contents of SA. The pH sensitivity of NC hydrogels was evident below their VPTT. The NC hydrogels had a much better mechanical property than the OR hydrogels. The results showed that the incorporation of clay did not affect the saturation magnetization of the hydrogels.
Vorheriger Artikel Thermal and phase-separation behavior of injection-molded poly(l-lactic acid)/poly(d-lactic acid) blends with moderate optical purity
Nächster Artikel Short-term effects of fully bioabsorbable PLLA coronary stents in a porcine model

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Literatur
1.
Kiler J, Scranton AB, Peppas NA (1990) Self-associating networks of poly(methacrylic acid-g-ethylene glycol). Macromolecules 23(23):4944–4949CrossRef
2.
Chiu HC, Lin YF, Hung SH (2002) Equilibrium swelling of copolymerized acrylic acid-methacrylated dextran networks: effects of pH and neutral salt. Macromolecules 35(13):5235–5242CrossRef
3.
Kokufata E, Zhang YQ, Tanaka T (1991) Saccharide-sensitive phase transition of a lectin-loaded gel. Nature 351:302–304CrossRef
4.
Dhara D, Chatterji PR (2000) Swelling and deswelling pathways in nonionic poly(N-isopropylacrylamide) hydrogels in presence of additives. Polymer 41(16):6133–6143CrossRef
5.
Suzuki A, Tanaka T (1990) Phase transition in polymer gels induced by visible light. Nature 346:345–347CrossRef
6.
Xulu PM, Filipcsei G, Zrinyi M (2000) Preparation and responsive properties of magnetically soft poly(N-isopropylacrylamide) gels. Macromolecules 33(5):1716–1719CrossRef
7.
Serizawa T, Wakita K, Akashi M (2002) Rapid deswelling of porous poly(N-isopropylacrylamide) hydrogels prepared by incorporation of silica particles. Macromolecules 35(1):10–12CrossRef
8.
Kim JH, Lee SB, Kim SJ, Lee YM (2002) Rapid temperature/pH response of porous alginate-g-poly(N-isopropylacrylamide) hydrogels. Polymer 43(26):7549–7558CrossRef
9.
Tanaka Y, Kagami Y, Matsuda A, Osada Y (1995) Thermoreversible transition of tensile modulus of hydrogel with ordered aggregates. Macromolecules 28(7):2574–2576CrossRef
10.
Zhang J, Peppas NA (2002) Morphology of poly(methacrylic acid)/poly(N-isopropylacrylamide) interpenetrating polymeric networks. J Biomater Sci Polym Ed 13(5):511–525CrossRef
11.
Tang YF, Zhao YY, Li Y, Du YM (2010) A thermosensitive chitosan/poly(vinyl alcohol) hydrogel containing nanoparticles for drug delivery. Polym Bull 64(8):791–804CrossRef
12.
Hoffman AS (2002) Hydrogels for biomedical applications. Adv Drug Rev 54(1):3–12CrossRef
13.
Kawaguchi H, Fujimoto K (1998) Smart latexes for bioseparation. Bioseparation 7(4/5):253–258CrossRef
14.
Zhang QS, Li XW, Zhao YP, Chen L (2009) Preparation and performance of nanocomposite hydrogels based on different clay. Appl Clay Sci 46(4):346–350CrossRef
15.
Liu F, Tao GL, Zhuo RX (1993) Synthesis of thermal phase separating reactive polymers and their applications in immobilized enzymes. Polym J 25(6):561–567CrossRef
16.
Shiino D, Murata Y, Kataoka K, Koyama Y, Yokoyama M, Okano T, Sakurai Y (1994) Preparation and characterization of a glucose-responsive insulin-releasing polymer device. Biomaterials 15(2):121–128CrossRef
17.
Miyazaki S, Nakayama A, Oda M, Takada M, Attwood D (1995) Drug release from oral mucosal adhesive tablets of chitosan and sodium alginate. Int J Pharm 118(2):257–263CrossRef
18.
Wang CY, Liu HX, Gao QX, Liu XX, Tong Z (2008) Alginate-calcium carbonate porous microparticle hybrid hydrogels with versatile drug loading capabilities and variable mechanical strengths. Carbohydr Polym 71:476–480CrossRef
19.
Zhang GQ, Zha LS, Zhou MH, Ma JH, Liang BR (2005) Preparation and characterization of pH- and temperature-responsive semi-interpenetrating polymer network hydrogels based on linear sodium alginate and crosslinked poly(N-isopropylacrylamide). J Appl Polym Sci 97(5):1931–1940CrossRef
20.
Guo BL, Gao QY (2007) Preparation and properties of a pH/temperature-responsive carboxymethyl chitosan/poly(N-isopropylacrylamide) semi-IPN hydrogel for oral delivery of drugs. Carbohydr Res 342(16):2416–2422CrossRef
21.
Zhao SP, Li YL, Cao MJ, Xu WL (2011) pH- and thermo-sensitive semi-IPN hydrogels composed of chitosan, N-isopropylacrylamide, and poly(ethylene glycol)-co-poly(ε-caprolactone) macromer for drug delivery. Polym Bull 66(8):1075–1087CrossRef
22.
Zhang GQ, Zha LS, Zhou MH, Ma JH, Liang BR (2005) Rapid deswelling of sodium alginate/poly(N-isopropylacrylamide) semi-interpenetrating polymer network hydrogels in response to temperature and pH changes. Colloid Polym Sci 283(4):431–438CrossRef
23.
Bajpai AK, Bajpai J, Shukla S, Kulkarni RA (2004) Modulation in sorption dynamics of a pH-sensitive interpenetrating polymer network (IPN). J Marcromol Sci A 41(2):211–230CrossRef
24.
Lee WF, Chen YJ (2001) Studies on Preparation and swelling properties of the N-isopropylacrylamide/chitosan semi-IPN and IPN hydrogels. J Appl Polym Sci 82(10):2487–2496CrossRef
25.
Zhang JT, Cheng SX, Zhuo RX (2003) Poly(vinyl alcohol)/poly(N-isopropylacrylamide) semi-interpenetrating polymer network hydrogels with rapid response to temperature changes. Colloid Polym Sci 281(6):580–583CrossRef
26.
Sayil C, Okay O (2000) The effect of preparation temperature on the swelling behavior of poly(N-isopropylacrylamide) gels. Polym Bull 45(2):175–182CrossRef
27.
Sayil C, Okay O (2002) Macroporous poly(N-isopropylacrylamide) networks. Polym Bull 48(6):499–506CrossRef
28.
Shibayama M, Morimoto M, Nomura S (1994) Phase separation induced mechanical transition of poly(N-isopropylacrylamide)/water isochore gels. Macromolecules 27(16):5060–5066CrossRef
29.
Haraguchi K, Takehisa T (2002) Nanocomposite hydrogels: a unique organic- inorganic network structure with extraordinary mechanical, optical, and swelling/deswelling properties. Adv Mater 14(16):1120–1124CrossRef
30.
Haraguchi K, Takehisa T, Fan S (2002) Effects of clay content on the properties of nanocomposite hydrogels composed of poly(N-isopropylacrylamide) and clay. Macromolecules 35(27):10162–10171CrossRef
31.
Shibayama M, Suda J, Karino T, Okabe S, Takehisa T, Haraguchi K (2004) Structure and dynamics of poly(N-isopropylacrylamide)-clay nanocomposite gels. Macromolecules 37(25):9606–9612CrossRef
32.
Haraguchi K, Li HJ, Matsuda K, Takehisa T, Elliott E (2005) Mechanism of forming organic/inorganic network structures during in situ free-radical polymerization in PNIPA-clay nanocomposite hydrogels. Macromolecules 38(8):3482–3490CrossRef
33.
Haraguchi K, Takada T (2005) Characteristic sliding frictional behavior on the surface of nanocomposite hydrogels consisting of organic-inorganic network structure. Macromol Chem Phys 206(15):1530–1540CrossRef
34.
Hu XB, Wang T, Xiong LJ, Wang CY, Liu XX, Tong Z (2010) Preferential adsorption of poly(ethylene glycol) on hectorite clay and effects on poly(N-isopropylacrylamide)/hectorite nanocomposite hydrogels. Langmuir 26(6):4233–4238CrossRef
35.
Wang T, Liu D, Lian CX, Zheng SD, Liu XX, Wang CY, Tong Z (2011) Rapid cell sheet detachment from alginate semi-interpenetrating nanocomposite hydrogels of PNIPAm and hectorite clay. React Funct Polym 71:447–454CrossRef
36.
Xiong LJ, Zhu MN, Hu XB, Liu XX, Tong Z (2009) Ultrahigh deformability and transparence of hectorite clay nanocomposite hydrogels with nimble pH response. Macromolecules 42:3811–3817CrossRef
37.
Mayer CR, Cabuil V, Lalot T, Thouvenot R (1999) Incorporation of magnetic nanoparticles in new hybrid networks based on heteropolyanions and polyacrylamide. Angew Chem Int Ed 38(24):3672–3675CrossRef
38.
Paulino AT, Guilherme MR, de Almeida EAMS, Pereira AGB, Muniz EC, Tambourgi EB (2009) One-pot synthesis of a chitosan-based hydrogel as a potential device for magnetic biomaterial. J Magn Magn Mater 321(17):2636–2642CrossRef
39.
Sun SH, Zeng H, Robinson DB, Raoux S, Rice PM, Wang SX, Li GX (2004) Monodisperse MFe2O4 (M = Fe, Co, Mn) nanoparticles. J Am Chem Soc 126(1):273–279CrossRef
40.
Li P, Zhu AM, Liu QL, Zhang QG (2008) Fe3O4/poly(N-isopropylacrylamide)/chitosan composite microspheres with multiresponsive properties. Ind Eng Chem Res 47(20):7700–7706CrossRef
41.
Otake K, Inomata H, Konno M, Saito S (1990) Thermal analysis of the volume phase transition with N-isopropylacrylamide gels. Macromolecules 23(1):283–289CrossRef
42.
Ma JH, Xu YJ, Zhang QS, Zha LS, Liang BR (2007) Preparation and characterization of pH- and temperature-responsive semi-IPN hydrogels of carboxymethyl chitosan with poly(N-isopropylacrylamide) crosslinked by clay. Colloid Polym Sci 285(4):479–484CrossRef
43.
Ma JH, Xu YJ, Fan B, Liang BR (2007) Preparation and characterization of sodium carboxymethylcellulose/poly(N-isopropylacrylamide)/clay semi-IPN nanocomposite hydrogels. Eur Polym J 43(6):2221–2228CrossRef
44.
Liang YY, Zhang LM, Li W, Chen RF (2007) Polysaccharide-modified iron oxide nanoparticles as an effective magnetic affinity adsorbent for bovine serum albumin. Colloid Polym Sci 285(11):1193–1199CrossRef
45.
Ma ZY, Guan YP, Liu HZ (2005) Synthesis and characterization of micron-sized monodisperse superparamagnetic polymer particles with amino groups. J Polym Sci A 43(15):3433–3439CrossRef
Metadaten
Titel
Preparation and characterization of sodium alginate/poly(N-isopropylacrylamide)/clay semi-IPN magnetic hydrogels
verfasst von
Zhiqiang Li
Jianfeng Shen
Hongwei Ma
Xin Lu
Min Shi
Na Li
Mingxin Ye
Publikationsdatum
01.03.2012
Verlag
Springer-Verlag
Erschienen in
Polymer Bulletin / Ausgabe 4/2012
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-011-0671-0

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