Skip to main content
Erschienen in: Metallography, Microstructure, and Analysis 6/2012

01.12.2012 | Technical Article

Preparation and Characterization of Ti-10Mo Alloy by Mechanical Alloying

verfasst von: Zhifang Gao, Honglin Luo, Qunying Li, Yizao Wan

Erschienen in: Metallography, Microstructure, and Analysis | Ausgabe 6/2012

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

In the present study, Ti-10Mo alloy was fabricated by mechanical alloying and subsequently consolidated by powder metallurgy techniques. The structural evolution of the powder blends with various milling durations, and the sintered alloys with different holding times, were characterized by x-ray diffraction, scanning electron microscopy, and light microscopy. The results revealed that the size of powder particles decreased with increasing milling time. In addition, only the sintered alloy using powders milled for 5 h exhibited both α-phase and β-phase. When the milling time increased to greater than 40 h, TiN phase gradually formed, which suppressed the α-phase to β-phase transformation. Furthermore, the effects of the sinter holding time on the Vickers hardness and the corrosion behavior of Ti-10Mo alloys was also investigated. The results showed that the Vickers hardness increased with increasing sinter holding time; after sintering the alloy for 5 h, the samples exhibited acceptable corrosion resistance.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat M. Niinomi, Biologically and mechanically biocompatible titanium alloys. Mater. Trans. 49(10), 2170–2178 (2008)CrossRef M. Niinomi, Biologically and mechanically biocompatible titanium alloys. Mater. Trans. 49(10), 2170–2178 (2008)CrossRef
2.
Zurück zum Zitat J.J. Oak, D.V. Louzguine-Luzgin, A. Inoue, Fabrication of Ni-free Ti-based bulk-metallic glassy alloy having potential for application as biomaterial, and investigation of its mechanical properties, corrosion, and crystallization behavior. J. Mater. Res. 22(5), 1346–1353 (2007)CrossRef J.J. Oak, D.V. Louzguine-Luzgin, A. Inoue, Fabrication of Ni-free Ti-based bulk-metallic glassy alloy having potential for application as biomaterial, and investigation of its mechanical properties, corrosion, and crystallization behavior. J. Mater. Res. 22(5), 1346–1353 (2007)CrossRef
3.
Zurück zum Zitat M. Niinomi, Metallic biomaterials. J. Artif. Organs 11(3), 105–110 (2008)CrossRef M. Niinomi, Metallic biomaterials. J. Artif. Organs 11(3), 105–110 (2008)CrossRef
4.
Zurück zum Zitat J.C. Wataha, Biocompatibility of dental casting alloys. J. Prosthet. Dent. 83(2), 223–234 (2000)CrossRef J.C. Wataha, Biocompatibility of dental casting alloys. J. Prosthet. Dent. 83(2), 223–234 (2000)CrossRef
5.
Zurück zum Zitat S. Lugowski, D. Smith, A. McHugh, V. Loon, Release of metal ions from dental implant materials in vivo: determination of Al, Co., Cr, Mo, Ni, V and Ti in organ tissue. J. Biomed. Mater. Res. 25(12), 1443–1458 (1991)CrossRef S. Lugowski, D. Smith, A. McHugh, V. Loon, Release of metal ions from dental implant materials in vivo: determination of Al, Co., Cr, Mo, Ni, V and Ti in organ tissue. J. Biomed. Mater. Res. 25(12), 1443–1458 (1991)CrossRef
6.
Zurück zum Zitat H.Y. Kim, J.I. Kim, T. Inamura, H. Hosoda, S. Miyazaki, Effect of thermo-mechanical treatment on mechanical properties and shape memory behavior of Ti-(26–28) at.% Nb alloys. Mater. Sci. Eng. A 438–440(35), 839–843 (2006) H.Y. Kim, J.I. Kim, T. Inamura, H. Hosoda, S. Miyazaki, Effect of thermo-mechanical treatment on mechanical properties and shape memory behavior of Ti-(26–28) at.% Nb alloys. Mater. Sci. Eng. A 438–440(35), 839–843 (2006)
7.
Zurück zum Zitat S. Miyazaki, H.Y. Kim, H. Hosoda, Development and characterization of Ni-free Ti-base shape memory and superelastic alloys. Mater. Sci. Eng. A 438, 18–24 (2006)CrossRef S. Miyazaki, H.Y. Kim, H. Hosoda, Development and characterization of Ni-free Ti-base shape memory and superelastic alloys. Mater. Sci. Eng. A 438, 18–24 (2006)CrossRef
8.
Zurück zum Zitat A. Cremasco, W.R. Osório, C.e.M.A. Freire, A. Garcia, R. Caram, Electrochemical corrosion behavior of a Ti-35Nb alloy for medical prostheses. Electrochim. Acta 53(14), 4867–4874 (2008)CrossRef A. Cremasco, W.R. Osório, C.e.M.A. Freire, A. Garcia, R. Caram, Electrochemical corrosion behavior of a Ti-35Nb alloy for medical prostheses. Electrochim. Acta 53(14), 4867–4874 (2008)CrossRef
9.
Zurück zum Zitat J. Xiong, Y. Li, X. Wang, P. Hodgson, C.e. Wen, Mechanical properties and bioactive surface modification via alkali-heat treatment of a porous Ti-18Nb-4Sn alloy for biomedical applications. Acta Biomater. 4(6), 1963–1968 (2008)CrossRef J. Xiong, Y. Li, X. Wang, P. Hodgson, C.e. Wen, Mechanical properties and bioactive surface modification via alkali-heat treatment of a porous Ti-18Nb-4Sn alloy for biomedical applications. Acta Biomater. 4(6), 1963–1968 (2008)CrossRef
10.
Zurück zum Zitat X.J. Wang, Y.C. Li, J.Y. Xiong, P.D. Hodgson, C.E. Wen, Porous TiNbZr alloy scaffolds for biomedical applications. Acta Biomater. 5(9), 3616–3624 (2009)CrossRef X.J. Wang, Y.C. Li, J.Y. Xiong, P.D. Hodgson, C.E. Wen, Porous TiNbZr alloy scaffolds for biomedical applications. Acta Biomater. 5(9), 3616–3624 (2009)CrossRef
11.
Zurück zum Zitat Y.-L. Zhou, M. Niinomi, T. Akahori, Changes in mechanical properties of Ti alloys in relation to alloying additions of Ta and Hf. Mater. Sci. Eng. A 483–484, 153–156 (2008) Y.-L. Zhou, M. Niinomi, T. Akahori, Changes in mechanical properties of Ti alloys in relation to alloying additions of Ta and Hf. Mater. Sci. Eng. A 483–484, 153–156 (2008)
12.
Zurück zum Zitat D. Mareci, R. Chelariu, D.-M. Gordin, G. Ungureanu, T. Gloriant, Comparative corrosion study of Ti-Ta alloys for dental applications. Acta Biomater. 5(9), 3625–3639 (2009)CrossRef D. Mareci, R. Chelariu, D.-M. Gordin, G. Ungureanu, T. Gloriant, Comparative corrosion study of Ti-Ta alloys for dental applications. Acta Biomater. 5(9), 3625–3639 (2009)CrossRef
13.
Zurück zum Zitat L.J. Xu, Y.Y. Chen, Z.G. Liu, F.T. Kong, The microstructure and properties of Ti-Mo-Nb alloys for biomedical application. J. Alloys Compd. 453(1–2), 320–324 (2008)CrossRef L.J. Xu, Y.Y. Chen, Z.G. Liu, F.T. Kong, The microstructure and properties of Ti-Mo-Nb alloys for biomedical application. J. Alloys Compd. 453(1–2), 320–324 (2008)CrossRef
14.
Zurück zum Zitat Y. Sasikumar, M. Karthega, N. Rajendran, In vitro bioactivity of surface-modified beta-Ti alloy for biomedical applications. J. Mater. Eng. Perform. 20(7), 1271–1277 (2011)CrossRef Y. Sasikumar, M. Karthega, N. Rajendran, In vitro bioactivity of surface-modified beta-Ti alloy for biomedical applications. J. Mater. Eng. Perform. 20(7), 1271–1277 (2011)CrossRef
15.
Zurück zum Zitat J. Song, X. Zhang, X. Sun, H. Jiang, Z. Fan, C. Xie, M.H. Wu, Effect of aging on superelastic behaviors of a metastable beta Ti-Mo-based alloy. J. Mater. Eng. Perform. 21(3), 366–372 (2012)CrossRef J. Song, X. Zhang, X. Sun, H. Jiang, Z. Fan, C. Xie, M.H. Wu, Effect of aging on superelastic behaviors of a metastable beta Ti-Mo-based alloy. J. Mater. Eng. Perform. 21(3), 366–372 (2012)CrossRef
16.
Zurück zum Zitat Y. Cui, Y. Li, K. Luo, H. Xu, Microstructure and shape memory effect of Ti-20Zr-10Nb alloy. Mater. Sci. Eng. A 527(3), 652–656 (2010)CrossRef Y. Cui, Y. Li, K. Luo, H. Xu, Microstructure and shape memory effect of Ti-20Zr-10Nb alloy. Mater. Sci. Eng. A 527(3), 652–656 (2010)CrossRef
17.
Zurück zum Zitat N.T.C. Oliveira, G. Aleixo, R. Caram, A.C. Guastaldi, Development of Ti-Mo alloys for biomedical applications: Microstructure and electrochemical characterization. Mater. Sci. Eng. A 452, 727–731 (2007)CrossRef N.T.C. Oliveira, G. Aleixo, R. Caram, A.C. Guastaldi, Development of Ti-Mo alloys for biomedical applications: Microstructure and electrochemical characterization. Mater. Sci. Eng. A 452, 727–731 (2007)CrossRef
18.
Zurück zum Zitat G. Rondelli, B. Vicentini, Effect of copper on the localized corrosion resistance of Ni-Ti shape memory alloy. Biomaterials 23(3), 639–644 (2002)CrossRef G. Rondelli, B. Vicentini, Effect of copper on the localized corrosion resistance of Ni-Ti shape memory alloy. Biomaterials 23(3), 639–644 (2002)CrossRef
19.
Zurück zum Zitat W.S. Lee, T.H. Chen, C.F. Lin, N.W. Lee, High strain rate shear deformation and fracture behaviour of biomedical titanium alloy. Mater. Sci. Technol. Ser. 26(9), 1079–1087 (2010)CrossRef W.S. Lee, T.H. Chen, C.F. Lin, N.W. Lee, High strain rate shear deformation and fracture behaviour of biomedical titanium alloy. Mater. Sci. Technol. Ser. 26(9), 1079–1087 (2010)CrossRef
20.
Zurück zum Zitat H. Guo, M. Enomoto, Surface relief effects of [alpha] precipitates in a Ti-Mo alloy. Acta Mater. 50(5), 929–941 (2002)CrossRef H. Guo, M. Enomoto, Surface relief effects of [alpha] precipitates in a Ti-Mo alloy. Acta Mater. 50(5), 929–941 (2002)CrossRef
21.
Zurück zum Zitat F.G. Cuevas, J.M. Montes, J. Cintas, J.M. Gallardo, Production of Al-Al3Ti powders by mechanical alloying and annealing. Powder Metall. 48(4), 365–370 (2005)CrossRef F.G. Cuevas, J.M. Montes, J. Cintas, J.M. Gallardo, Production of Al-Al3Ti powders by mechanical alloying and annealing. Powder Metall. 48(4), 365–370 (2005)CrossRef
22.
Zurück zum Zitat S.R. Bakhshi, M. Salehi, H. Edris, G.H. Borhani, Preparation of Mo-Si-B nanocomposite powders by mechanical alloying and heat treating. Powder Metall. 54(2), 108–112 (2011) S.R. Bakhshi, M. Salehi, H. Edris, G.H. Borhani, Preparation of Mo-Si-B nanocomposite powders by mechanical alloying and heat treating. Powder Metall. 54(2), 108–112 (2011)
23.
Zurück zum Zitat S. Dymek, A. Lorent, M. Wrel, A. Dollar, Mechanical alloying and microstructure of a Nb-20% V-15% Al alloy. Mater. Charact. 47(5), 375–381 (2001)CrossRef S. Dymek, A. Lorent, M. Wrel, A. Dollar, Mechanical alloying and microstructure of a Nb-20% V-15% Al alloy. Mater. Charact. 47(5), 375–381 (2001)CrossRef
24.
Zurück zum Zitat H. Yang, P.G. McCormick, Synthesis of titanium oxynitride by mechanical milling. J. Mater. Sci. 28(20), 5663–5667 (1993)CrossRef H. Yang, P.G. McCormick, Synthesis of titanium oxynitride by mechanical milling. J. Mater. Sci. 28(20), 5663–5667 (1993)CrossRef
25.
Zurück zum Zitat H. Zhangy, E.H. Kisiy, S. Myhra, A solid solution pumping mechanism for the nitrogenation of titanium during mechanical deformation in air. J. Phys. D 29(5), 1367–1372 (1996)CrossRef H. Zhangy, E.H. Kisiy, S. Myhra, A solid solution pumping mechanism for the nitrogenation of titanium during mechanical deformation in air. J. Phys. D 29(5), 1367–1372 (1996)CrossRef
26.
Zurück zum Zitat Y.W. Gu, L.S. Goi, A.E.W. Jarfors, D.L. Butler, C.S. Lim, Structural evolution in Ti-Si alloy synthesized by mechanical alloying. Phys. B 352(1–4), 299–304 (2004)CrossRef Y.W. Gu, L.S. Goi, A.E.W. Jarfors, D.L. Butler, C.S. Lim, Structural evolution in Ti-Si alloy synthesized by mechanical alloying. Phys. B 352(1–4), 299–304 (2004)CrossRef
27.
Zurück zum Zitat S. Bera, I. Manna, Polymorphic phase transformation in Ti50Zr50 binary alloy by mechanical alloying. Mater. Sci. Eng. A 417(1–2), 110–113 (2006) S. Bera, I. Manna, Polymorphic phase transformation in Ti50Zr50 binary alloy by mechanical alloying. Mater. Sci. Eng. A 417(1–2), 110–113 (2006)
28.
Zurück zum Zitat S. Kumaran, T. Sasikumar, R. Arockiakumar, T.S. Rao, Nanostructured titanium aluminides prepared by mechanical alloying and subsequent thermal treatment. Powder Technol. 185(2), 124–130 (2008)CrossRef S. Kumaran, T. Sasikumar, R. Arockiakumar, T.S. Rao, Nanostructured titanium aluminides prepared by mechanical alloying and subsequent thermal treatment. Powder Technol. 185(2), 124–130 (2008)CrossRef
29.
Zurück zum Zitat J. Yang, J. Wu, W. Hua, Study on mechanical alloying and subsequent heat treatment of the Ti-Si system. Phys. B 279(4), 241–245 (2000)CrossRef J. Yang, J. Wu, W. Hua, Study on mechanical alloying and subsequent heat treatment of the Ti-Si system. Phys. B 279(4), 241–245 (2000)CrossRef
30.
Zurück zum Zitat Z. Gao, Q. Li, F. He, Y. Huang, Y. Wan, Mechanical modulation and bioactive surface modification of porous Ti-10Mo alloy for bone implants. Mater. Des. 42, 13–20 (2012)CrossRef Z. Gao, Q. Li, F. He, Y. Huang, Y. Wan, Mechanical modulation and bioactive surface modification of porous Ti-10Mo alloy for bone implants. Mater. Des. 42, 13–20 (2012)CrossRef
31.
Zurück zum Zitat Y. Liu, W.F. Wei, K.C. Zhou, L.F. Chen, H.P. Tang, Microstructures and mechanical behavior of PM Ti-Mo alloy. J. Cent. S. Univ. Technol. 10(2), 81–86 (2003)CrossRef Y. Liu, W.F. Wei, K.C. Zhou, L.F. Chen, H.P. Tang, Microstructures and mechanical behavior of PM Ti-Mo alloy. J. Cent. S. Univ. Technol. 10(2), 81–86 (2003)CrossRef
32.
Zurück zum Zitat Y.W. Gu, M.S. Yong, B.Y. Tay, C.S. Lim, Synthesis and bioactivity of porous Ti alloy prepared by foaming with TiH2. Mater. Sci. Eng. C 29(5), 1515–1520 (2009)CrossRef Y.W. Gu, M.S. Yong, B.Y. Tay, C.S. Lim, Synthesis and bioactivity of porous Ti alloy prepared by foaming with TiH2. Mater. Sci. Eng. C 29(5), 1515–1520 (2009)CrossRef
33.
Zurück zum Zitat E. Delvat, D.M. Gordin, T. Gloriant, J.L. Duval, M.D. Nagel, Microstructure, mechanical properties and cytocompatibility of stable beta Ti-Mo-Ta sintered alloys. J. Mech. Behav. Mater. 1(4), 345–351 (2008)CrossRef E. Delvat, D.M. Gordin, T. Gloriant, J.L. Duval, M.D. Nagel, Microstructure, mechanical properties and cytocompatibility of stable beta Ti-Mo-Ta sintered alloys. J. Mech. Behav. Mater. 1(4), 345–351 (2008)CrossRef
Metadaten
Titel
Preparation and Characterization of Ti-10Mo Alloy by Mechanical Alloying
verfasst von
Zhifang Gao
Honglin Luo
Qunying Li
Yizao Wan
Publikationsdatum
01.12.2012
Verlag
Springer-Verlag
Erschienen in
Metallography, Microstructure, and Analysis / Ausgabe 6/2012
Print ISSN: 2192-9262
Elektronische ISSN: 2192-9270
DOI
https://doi.org/10.1007/s13632-012-0045-5

Weitere Artikel der Ausgabe 6/2012

Metallography, Microstructure, and Analysis 6/2012 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.