nach oben

Rare Metals

Erschienen in:

03.04.2023 | Letter

Preparation and electrochemical behaviour of Ti/Mn₂O₃ coating anode

verfasst von: Fa-Ming Xie, Lin Tian, Chuan-Bin Li, Xue-Tao Yuan, Yan-Xi Yin

Erschienen in: Rare Metals | Ausgabe 7/2023

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Owing to the excellent electrocatalytic activity, corrosion resistance and high cell potential of the dimensionally stable anodes (DSA), DSAs have great application potential in metallurgical electrolysis industry. In this research, the Ti/Mn₂O₃ DSA anode was prepared by the thermal decomposition method. The results showed that the composition of the coating is Mn₂O₃, and the surface of the Ti/Mn₂O₃ coating anode is uniform and compact. But there are tiny cracks in the local area of the dense Mn₂O₃ coating surface, which significantly improves the electrocatalytic activity. The catalytic activity of the Ti/Mn₂O₃ anode is greater than that of the Pb-Ag (0.8 wt%) anode in the sulfuric acid solution. The rate-determining step of both anodes is the rearrangement of intermediates. The accelerated life of Ti/Mn₂O₃ anode can reach 34 h, which has great application potential in metallurgical electrochemistry.

Graphical abstract

Vorheriger Artikel Corrosion resistance of Cr2O3 coating formed by in-situ oxidation on 2205 duplex stainless steel in different pH solutions

Nächster Artikel Flexible impedance sensor based on Ti3C2Tx MXene and graphitic carbon nitride nanohybrid for humidity-sensing application with ultrahigh response

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Nur mit Berechtigung zugänglich

[1]

Yuan XT, Lu XD, Hua ZQ, Wang L, Li T. Corrosion behavior of Pb-Ca-Sn electrodes for copper electrowinning. Adv Mater Res. 2011;402:349. https://doi.org/10.4028/www.scientific.net/AMR.402.349.CrossRef

[2]

Karlsson RKB, Cornell A. Selectivity between oxygen and chlorine evolution in the chlor-alkali and chlorate processes. Chem Rev. 2016;116(5):2982. https://doi.org/10.1021/acs.chemrev.5b00389.CrossRef

[3]

Rheinlander PJ, Durst J. Transformation of the OER-active IrO_x species under transient operation conditions in PEM water electrolysis. Electrochem Soc. 2021;168(2):1. https://doi.org/10.1149/1945-7111/abe0d4.CrossRef

[4]

Galizzioli D, Tantardini F, Trasatti S. Ruthenium dioxide: a new electrode material. I. Behaviour in acid solutions of inert electrolytes. J Appl Electrochem. 1974;4(1):57. https://doi.org/10.1007/BF00615906.CrossRef

[5]

Wu T, Sun MZ, Huang BL. Non-noble metal-based bifunctional electrocatalysts for hydrogen production. Rare Met. 2022;41(7):2169. https://doi.org/10.1007/s12598-021-01914-x.CrossRef

[6]

Li HH, Yuan TC, Li RD. Electrochemical properties of powder-pressed Pb-Ag–PbO₂ anodes. Trans Nonferrous Met Soc China. 2019;29(11):2422. https://doi.org/10.1016/S1003-6326(19)65148-4.CrossRef

[7]

Chen BM, Liu JH, Wang SC, Huang H, He YP, Guo ZC. Preparation and electrochemical properties of a novel porous Ti/Sn-Sb-RuO_x/beta-PbO₂/MnO₂ anode for zinc electrowinning. RSC Adv. 2021;11(31):19136. https://doi.org/10.1039/d1ra02815d.CrossRef

[8]

Liu SB, Li AL, Yang CG, Ouyang P, Zhou JF, Liu XL. MnO₂/Mn₂O₃ with self-triggered oxygen-defects for superior pseudocapacitive energy storage. Appl Surf Sci. 2021;571:151306. https://doi.org/10.1016/j.apsusc.2021.151306.CrossRef

[9]

Mao LQ, Zhang D, Sotomura T, Nakatsu K, Koshiba N, Ohsa T. Mechanistic study of the reduction of oxygen in air electrode with manganese oxides as electrocatalysts. Electrochim Acta. 2003;48(8):1015. https://doi.org/10.1016/j.apsusc.2021.151306.CrossRef

[10]

Xiong YJ, Liu X, Zhang TC, Yuan SJ. MnO₂/TiO₂ nanotube array-coated titanium substrates as anodes for electrocatalytic oxidation of As(III) in aqueous solution. ACS Appl Nano Mater. 2021;4(7):7404. https://doi.org/10.1021/acsanm.1c01376.CrossRef

[11]

Ye ZG, Meng HM, Sun DB. New degradation mechanism of Ti/IrO₂+MnO₂ anode for oxygen evolution in 0.5 M H₂SO₄ solution. Electrochim Acta. 2008;53(18):5639. https://doi.org/10.1016/j.electacta.2008.03.025.CrossRef

[12]

Ao X, Zhao CP, Han YP, Tang GQ, Ren HJ. N-doped δ-MnO₂ synthesized by the hydrothermal method and its electrochemical performance as anode materials. Ceram Int. 2021;47(10):13722. https://doi.org/10.1016/j.ceramint.2021.01.233.CrossRef

[13]

Lai YQ, Li Y, Jiang LX, Lv XJ, Li J, Liu YX. Electrochemical performance of a Pb/Pb-MnO₂ composite anode in sulfuric acid solution containing Mn²⁺. Hydrometallurgy. 2012;115:64. https://doi.org/10.1016/j.hydromet.2011.12.013.CrossRef

[14]

Huang AX, Zhou WJ, Wang AR, Chen MF, Tian QH, Chen JZ. Molten salt synthesis of α-MnO₂/Mn₂O₃ nanocomposite as a high-performance cathode material for aqueous zinc-ion batteries. J Energy Chem. 2021;54:475. https://doi.org/10.1016/j.jech-em.2020.06.041.CrossRef

[15]

Li SM, Li B, Zhong YT, Pan ZH, Xu MQ, Qiu YC, Huang QM, Li WS. Mn₂O₃@C yolk-shell nanocubes as lithium-storage anode with suppressed surface electrolyte decomposition. Mater Chem Phys. 2019;222:256. https://doi.org/10.1016/j.matchem-phys.2018.10.015.CrossRef

[16]

Choudhary D, Tavar D, Singh P, Raizada P, Ashiq M, Srivastava AK, Singh A. Nanoalumina-supported Mn₂O₃ as efficient adsorbent for removal of fluoride and arsenic from water: a study from lab to field. J Mater Sci. 2022;57(28):13326. https://doi.org/10.1007/s10853-022-07466-4.CrossRef

[17]

Saputra E, Zhang HY, Liu QR, Sun HQ, Wang SB. Egg-shaped core/shell α-Mn₂O₃@α-MnO₂ as heterogeneous catalysts for decomposition of phenolics in aqueous solutions. Chemosphere. 2016;159:351. https://doi.org/10.1016/j.chemosphere.2016.06.021.CrossRef

[18]

Manigandan R, Suresh R, Giribabu K, Vijayalakshmi A, Stephen NV. Synthesis, characterization, optical and sensing property of manganese oxide nanoparticles. AIP Conf Proc. 2014;1576:125.CrossRef

[19]

Moritz K, Sebastian F, Roel VDK, Bogdanoff P. Evaluation of electrodeposited alpha-Mn₂O₃ as a catalyst for the oxygen evolution reaction. Catal Today. 2017;290:2. https://doi.org/10.1016/j.cattod.2017.03.030.CrossRef

[20]

Stellmach D. Evaluation of MnO_x, Mn₂O₃, and Mn₃O₄ electrodeposited films for the oxygen evolution reaction of water. J Phys Chem C. 2015;118(26):14073. https://doi.org/10.1021/jp500939d.CrossRef

[21]

Javed Q, Wang FP, Rafique MY, Mohammadtoufiq A, Zubair I. Canted antiferromagnetic and optical properties of nanostructures of Mn₂O₃ prepared by hydrothermal synthesis. Chin Phys B. 2012;21(11):117311. https://doi.org/10.1088/1674-1056/21/11/117311.CrossRef

[22]

Lu HT, Zhang Y, Liu PF. Mn₂O₃ microcubes with three-dimensional porous network structure as electrochemical sensing material for nitrite. J Appl Electrochem. 2016;46:1059. https://doi.org/10.1007/s10800-016-0985-6.CrossRef

[23]

Ginsburg A, Keller DA, Barad HN, Rietwyk K, Bouhadana Y. One-step synthesis of crystalline Mn₂O₃ thin film by ultrasonic spray pyrolysis. Thin Solid Films. 2016;615:261. https://doi.org/10.1016/j.tsf.2016.06.050.CrossRef

[24]

Kong FD, Sheng S, Yin GP, Liu J, Xu ZQ. IrO₂-graphene hybrid as an active oxygen evolution catalyst for water electrolysis. Int J Hydrog Energy. 2013;38(22):9217. https://doi.org/10.1016/j.ijhydene.2013.05.023.CrossRef

[25]

Jm HU, Zhang JQ, Cao CN. Oxygen evolution reaction on IrO₂-based DSA type electrodes: kinetics analysis of Tafel lines and EIS. Int J Hydrog Energy. 2004;29(8):791. https://doi.org/10.1016/j.ijhydene.2003.09.007.CrossRef

[26]

Xu RD, Huang LP, Zhou JF, Zhan P, Guan YY, Kong Y. Effects of tungsten carbide on electrochemical properties and microstructural features of Al/Pb-PANI-WC composite inert anodes used in zinc electrowinning. Hydrometallurgy. 2012;125:8. https://doi.org/10.1016/j.hydromet.2012.04.012.CrossRef

[27]

Yang HT, Chen BM, Liu HN, Liu HN, Guo ZR, Zhang YC, Li XL, Xu RD. Effects of manganese nitrate concentration on the performance of an aluminum substrate β-PbO₂-MnO₂-WC-ZrO₂ composite electrode material. Int J Hydrogen Energy. 2014;39(7):3087. https://doi.org/10.1016/j.ijhydene.2013.12.091.CrossRef

[28]

Lai YQ, Li Y, Jiang LX, Xu W, Lv XJ, Li J, Liu YX. Electrochemical behaviors of co-deposited Pb/Pb-MnO₂ composite anode in sulfuric acid solution-Tafel and EIS investigations. J Electroanal Chem. 2012;671(1):16. https://doi.org/10.1016/j.jele-chem.2012.02.011.CrossRef

[29]

Zhang JJ, Hu JM, Zhang JQ, Cao CN. IrO₂-SiO₂ binary oxide films: geometric or kinetic interpretation of the improved electrocatalytic activity for the oxygen evolution reaction. Int J Hydrogen Energy. 2011;36(9):5218. https://doi.org/10.1016/j.ijhy-dene.2011.01.131.CrossRef

[30]

Silva LM, Faria LAD, Boodts JFC. Electrochemical ozone production: influence of the supporting electrolyte on kinetics and current efficiency. Electrochim Acta. 2003;48(6):699. https://doi.org/10.1016/S0013-4686(02)00739-9.CrossRef

[31]

Zhou F, Zhou Y, Liu GG, Chen TW, Jun W. Recent advances in nanostructured electrocatalysts for hydrogen evolution reaction. Rare Met. 2021;40:3375. https://doi.org/10.1007/s12598-021-01735-y.CrossRef

[32]

Ye WQ, Xu FY, Jiang LH, Duan N, Li JH, Zhang FL, Zhang G, Chen FL. A novel functional lead-based anode for efficient lead dissolution inhibition and slime generation reduction in zinc electrowinning. J Cleaner Prod. 2020. https://doi.org/10.1016/j.jclepro.2020.124767.CrossRef

[33]

Matsumoto Y, Sato E. Electrocatalytic properties of transition metal oxides for oxygen evolution reaction. Mater Chem Phys. 1986;14(5):397. https://doi.org/10.1016/0254-0584(86)90045-3.CrossRef

[34]

Michaela SB, Lisa JE, Adam SB, Zou SH, Shannon WB. Oxygen evolution reaction electrocatalysis on transition metal oxides and (oxy)hydroxides: activity trends and design principles. Chem Mater. 2015;27:7549. https://doi.org/10.1021/acs.chemmater.5b03148.CrossRef

[35]

Shi YH, Meng HM. Electrochemical behavior of IrO₂ electrodes in the anodic electrodeposition of MnO₂. Acta Phys Chim Sin. 2011;27(2):461. https://doi.org/10.3866/PKU.WHXB20110216.CrossRef

[36]

Burke LD, Murphy OJ. Cyclic voltammetry as a technique for determining the surface area of RuO₂ electrodes. J Electroanal Chem. 1979;96(1):19. https://doi.org/10.1016/S0022-0728(79)80299-5.CrossRef

[37]

Xu W, Tayal J, Basu S, Scott K. Nano-crystalline Ru_xSn₁₋_xO₂ powder catalysts for oxygen evolution reaction in proton exchange membrane water electrolysers. Int J Hydrog Energy. 2011;36(22):14796. https://doi.org/10.1016/j.ijhydene.2011.01.067.CrossRef

[38]

Xu XH, Zhang YJ, Miao XY. Synthesis and electrocatalytic performance of 3D coral-like NiCo-P. Chin J Rare Met. 2022;46(11):1449. https://doi.org/10.13373/j.cnki.cjrm.XY22080001.CrossRef

[39]

Wu LK, Zhang JT, Hu JM, Zhang JQ. Improved corrosion performance of electrophoretic coatings by silane addition. Corros Sci. 2012;56:58. https://doi.org/10.1016/j.corsci.2011.11.018.CrossRef

[40]

Brug GJ, Eeden A, Sluytersrehbach M, Stuyters JH. The analysis of electrode impedances complicated by the presence of a constant phase element. J Electroanal Chem. 1984;176(1–2):275. https://doi.org/10.1016/s0022-0728(84)80324-1.CrossRef

[41]

Jorcin JB, Orazem ME, Pebere N, Tribollet B. CPE analysis by local electrochemical impedance spectroscopy. Electrochim Acta. 2006;51(8–9):1473. https://doi.org/10.1016/j.electacta.2005.02.128.CrossRef

[42]

Alves VA, da Silva LAD, Boodts JFC. Surface characterisation of IrO₂/TiO₂/CeO₂ oxide electrodes and faradaic impedance investigation of the oxygen evolution reaction from alkaline solution. Electrochim Acta. 1998;44(8–9):1525. https://doi.org/10.1016/S0013-4686(98)00276-X.CrossRef

[43]

Hoseinieh SM, Ashrafizadeh F, Maddahi MH. A comparative investigation of the corrosion behavior of RuO₂-IrO₂-TiO₂ coated titanium anodes in chloride solutions. J Electrochem Soc. 2010;157(4):50. https://doi.org/10.1149/1.3294569.CrossRef

[44]

Song YH, Wei G, Xiong RC. Structure and properties of PbO₂-CeO₂ anodes on stainless steel. Electrochim Acta. 2007;52(24):7022. https://doi.org/10.1016/j.elect-acta.2007.05.024.CrossRef

Titel: Preparation and electrochemical behaviour of Ti/Mn2O3 coating anode
verfasst von: Fa-Ming Xie
Lin Tian
Chuan-Bin Li
Xue-Tao Yuan
Yan-Xi Yin
Publikationsdatum: 03.04.2023
Verlag: Nonferrous Metals Society of China
Erschienen in: Rare Metals / Ausgabe 7/2023
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI: https://doi.org/10.1007/s12598-023-02297-x

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Graphical abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 7/2023

Co-free/Co-poor high-Ni cathode for high energy, stable and low-cost lithium-ion batteries

High-performance martensitic stainless steel nanocomposite powder for direct energy deposition prepared by ball milling

Ultrafine Ru nanoparticles anchored on core–shell structured zeolite-carbon for efficient catalysis of hydrogen generation

3D nitrogen and boron dual-doped carbon quantum dots/reduced graphene oxide aerogel for advanced aqueous and flexible quasi-solid-state zinc-ion hybrid capacitors

Self-sensing tribological coating with phosphor particles for wear indicator

High-dielectric loss black silicon decorated with multi-nanostructure for wide-band mid-infrared absorption

Premium Partner

Marktübersichten