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Optical and Quantum Electronics

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01.03.2024

Preparation and exploration of optical performance of novel polythiophene-ZrO₂ composites

verfasst von: Shivani Kataria, Md. Kismat Rain, Anil Kumar, Harish Mudila

Erschienen in: Optical and Quantum Electronics | Ausgabe 3/2024

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Abstract

Studies were carried out to comprehend the synergetic effect of ZrO₂ on the optical behavior of Polythiophene (PTh). PTh was composited with the requisite amount of ZrO₂ to produce the novel composite materials (PZs), which were further investigated for their optical properties viz. optical band-gap, extinction coefficient, refractive index, dielectric constants, and consequently optical conductivity. The studies represent the composite PZ-1 (PTh: ZrO₂, 2:1 w/w%) shows a low optical band-gap (2.45 eV) as compared to PTh (3.14 eV), ZrO₂ (3.51 eV) and other PZs, owing to the overlap of the valance and conduction bands of the two components. Correspondingly the optical conductivity of PZ-1 was encountered to be 1.55 × 10¹¹ Scm⁻¹ which is much higher as compared to all the other PZs and individual components, thus, suggesting the potential application of ZrO₂-Doped PTh (PZ-1) in optoelectronic devices. The optical band gap and optical conductivity for PZs (especially PZ-1) were found to be much more promising as compared to other studies represented on PTh and its composites. Studies like FT-IR, SEM, TGA, and DSC were carried out to study the other important parameters of the PTh, ZrO₂, and PZs.

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Titel: Preparation and exploration of optical performance of novel polythiophene-ZrO2 composites
verfasst von: Shivani Kataria
Md. Kismat Rain
Anil Kumar
Harish Mudila
Publikationsdatum: 01.03.2024
Verlag: Springer US
Erschienen in: Optical and Quantum Electronics / Ausgabe 3/2024
Print ISSN: 0306-8919
Elektronische ISSN: 1572-817X
DOI: https://doi.org/10.1007/s11082-023-06046-3

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