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28.02.2018 | Original Contribution

Preparation and morphology characterization of core-shell water-dispersible polystyrene/poly(3,4-ethylenedioxythiophene) microparticles

verfasst von: Aleksei V. Kubarkov, Svetlana A. Lipovskikh, Olga A. Pyshkina, Evgeny A. Karpushkin, Keith J. Stevenson, Vladimir G. Sergeyev

Erschienen in: Colloid and Polymer Science | Ausgabe 4/2018

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Abstract

Ultrafine electrically conductive microparticles have been prepared by in situ oxidative polymerization of 3,4-ethylenedioxythiophene in the presence of sulfonated polystyrene latex beads either in water or in an aqueous solution of poly(4-styrenesulfonic) or 4-toluenesulfonic acid. The particles consist of polystyrene core and continuous poly(3,4-ethylenedioxythiophene) shell which incorporate different counter-ions derived from the oxidant or the sulfonic acid. The presence of poly(4-styrenesulfonic acid) in the polymerization medium enhances the electrical conductivity of the resulting particles by up to two orders of magnitude. The particles prepared in the presence of poly(4-styrenesulfonic acid) exhibit smooth surface morphology and high colloidal stability, while these prepared in the presence of 4-toluenesulfonic acid or in the absence of sulfonic acid show rough sponge-like morphology and do not form stable dispersions.

Vorheriger Artikel On the fracture mechanism of a symmetric interface of glassy poly(methyl methacrylate) self-healed at a temperature well below the bulk glass transition temperature

Nächster Artikel Construction of high-strength p(HEMA-co-AA) fluorescent hydrogels based on modified carbon dots as chemically crosslinkers

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Titel: Preparation and morphology characterization of core-shell water-dispersible polystyrene/poly(3,4-ethylenedioxythiophene) microparticles
verfasst von: Aleksei V. Kubarkov
Svetlana A. Lipovskikh
Olga A. Pyshkina
Evgeny A. Karpushkin
Keith J. Stevenson
Vladimir G. Sergeyev
Publikationsdatum: 28.02.2018
Verlag: Springer Berlin Heidelberg
Erschienen in: Colloid and Polymer Science / Ausgabe 4/2018
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI: https://doi.org/10.1007/s00396-018-4294-y

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