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Journal of Materials Science
Erschienen in: Journal of Materials Science 20/2014

01.10.2014

Preparation and performance of silica/polypropylene composite separator for lithium-ion batteries

verfasst von: Hongyu Liu, Jun Xu, Baohua Guo, Xiangming He

Erschienen in: Journal of Materials Science | Ausgabe 20/2014

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Abstract

In an effort to improve thermal stability and mechanical properties of porous polypropylene (PP) separators for lithium-ion battery, SiO2/PP/SiO2 composite separators were prepared by introducing SiO2 layer on both sides of PP separator through a dip-coating process, with polyvinylidene fluoride–hexafluoropropylene (PVDF–HFP) as binder. SiO2 nanoparticles are evenly distributed and closely packed in the coated layer, which features a porous honeycomb structure. This unique porous structure was quantitatively analyzed by Gurley value, and it can retain liquid electrolyte, leading to higher electrolyte uptake and ionic conductivity of the composite separator. The introduction of SiO2-coated layers can not only suppress thermal shrinkage but also improve mechanical properties of the composite separator. C-rate capability and cycle performance of composite separator were also investigated, and compared to those of pristine PP separator.
Vorheriger Artikel Nanoscale Bi2FeO6−x precipitates in BiFeO3 thin films: a metastable Aurivillius phase
Nächster Artikel Behavior of indium oxide in zinc phosphate and borophosphate glasses

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Literatur
1.
Johnson BA, White RE (1998) Characterization of commercially available lithium-ion batteries. J Power Sources 70:48–54CrossRef
2.
Whittingham MS (2004) Lithium batteries and cathode materials. Chem Rev 104:4271–4301CrossRef
3.
Huang XS (2012) A lithium-ion battery separator prepared using a phase inversion process. J Power Sources 216:216–221CrossRef
4.
Song KW, Kim CK (2010) Coating with macroporous polyarylate via a nonsolvent induced phase separation process for enhancement of polyethylene separator thermal stability. J Membr Sci 352:239–246CrossRef
5.
Jeong HS, Hong SC, Lee SY (2010) Effect of microporous structure on thermal shrinkage and electrochemical performance of Al2O3/poly(vinylidene fluoride-hexafluoropropylene) composite separators for lithium-ion batteries. J Membr Sci 364:177–182CrossRef
6.
Jeong HS, Kim DW, Jeong YU, Lee SY (2010) Effect of phase inversion on microporous structure development of Al2O3/poly(vinylidene fluoride-hexafluoropropylene)-based ceramic composite separators for lithium-ion batteries. J Power Sources 195:6116–6121CrossRef
7.
Sohn JY, Im JS, Shin J, Nho YC (2012) PVDF–HFP/PMMA-coated PE separator for lithium ion battery. J Solid State Electrochem 16:551–556CrossRef
8.
Ryou MH, Lee YM, Park JK, Choi JW (2011) Mussel-inspired polydopamine-treated polyethylene separators for high-power Li-ion batteries. Adv Mater 23:3066–3070CrossRef
9.
Arora P, Zhang ZM (2004) Battery separators. Chem Rev 104:4419–4462CrossRef
10.
Zhang SS (2007) A review on the separators of liquid electrolyte Li-ion batteries. J Power Sources 164:351–364CrossRef
11.
Park JH, Cho JH, Park W, Ryoo D, Yoon SJ, Kim JH, Jeong YU, Lee SY (2010) Close-packed SiO2/poly(methyl methacrylate) binary nanoparticles-coated polyethylene separators for lithium-ion batteries. J Power Sources 195:8306–8310CrossRef
12.
Kim M, Han GY, Yoon KJ, Park JH (2010) Preparation of a trilayer separator and its application to lithium-ion batteries. J Power Sources 195:8302–8305CrossRef
13.
Fu D, Luan B, Argue S, Bureau MN, Davidson IJ (2012) Nano SiO2 particle formation and deposition on polypropylene separators for lithium-ion batteries. J Power Sources 206:325–333CrossRef
14.
Huang XS, Hitt J (2013) Lithium ion battery separators: development and performance characterization of a composite membrane. J Membr Sci 425–426:163–168CrossRef
15.
Zhang SS, Xu K, Jow TR (2003) Alkaline composite film as a separator for rechargeable lithium batteries. J Solid State Electrochem 7:492–496CrossRef
16.
Jeong HS, Kim JH, Lee SY (2010) A novel poly(vinylidene fluoride-hexafluoropropylene)/poly(ethylene terephthalate) composite nonwoven separator with phase inversion-controlled microporous structure for a lithium-ion battery. J Mater Chem 20:9180–9186CrossRef
17.
Lee YM, Kim JW, Choi NS, Lee JA, Seol WH, Park JK (2005) Novel porous separator based on PVdF and PE non-woven matrix for rechargeable lithium batteries. J Power Sources 139:235–241CrossRef
18.
Kim KJ, Kim JH, Park MS, Kwon HK, Kim H, Kim YJ (2012) Enhancement of electrochemical and thermal properties of polyethylene separators coated with polyvinylidene fluoride–hexafluoropropylene co-polymer for Li-ion batteries. J Power Sources 198:298–302CrossRef
19.
Choi JA, Kim SH, Kim DW (2010) Enhancement of thermal stability and cycling performance in lithium-ion cells through the use of ceramic-coated separators. J Power Sources 195:6192–6196CrossRef
20.
Wachtler M, Ostrovskii D, Jacobsson P, Scrosati B (2004) A study on PVdF-based SiO2-containing composite gel-type polymer electrolytes for lithium batteries. Electrochim Acta 50:357–361CrossRef
21.
Kim KM, Park NG, Ryu KS, Chang SH (2006) Characteristics of PVdF–HFP/TiO2 composite membrane electrolytes prepared by phase inversion and conventional casting methods. Electrochim Acta 51:5636–5644CrossRef
22.
Li ZH, Su GY, Gao DS, Wang XY, Li XP (2004) Effect of Al2O3 nanoparticles on the electrochemical characteristics of P(VDF-HFP)-based polymer electrolyte. Electrochim Acta 49:4633–4639CrossRef
23.
Takemura D, Aihara S, Hamano K, Kise M, Nishimura T, Urushibata H, Yoshiyasu H (2005) A powder particle size effect on ceramic powder based separator for lithium rechargeable battery. J Power Sources 146:779–783CrossRef
24.
Zhang SS, Xu K, Jow TR (2005) An inorganic composite membrane as the separator of Li-ion batteries. J Power Sources 140:361–364CrossRef
25.
Huang XS (2011) Separator technologies for lithium-ion batteries. J Solid State Electrochem 15:649–662CrossRef
26.
Zhang YQ, Zhang GD, Du TD, Zhang LZ (2010) Study on performance of composite polymer films doped with modified molecular sieve for lithium-ion batteries. Electrochim Acta 55:5793–5797CrossRef
27.
Jeong HS, Lee SY (2011) Closely packed SiO2 nanoparticles/poly(vinylidene fluoride-hexafluoropropylene) layers-coated polyethylene separators for lithium-ion batteries. J Power Sources 196:6716–6722CrossRef
28.
Sharmin K, Abdalla MA, Aglan HA (2014) Effect of fumed silica nanoparticles on the proton conductivity of polyimide–phosphoric anhydride membranes. J Elastom Plast 46:43–56CrossRef
29.
Osińska M, Walkowiak M, Zalewska A, Jesionowski T (2009) Study of the role of ceramic filler in composite gel electrolytes based on microporous polymer membranes. J Membr Sci 326:582–588CrossRef
30.
Liu XJ, Kusawake H, Kuwajima S (2001) Preparation of a PVdF–HFP/polyethylene composite gel electrolyte with shutdown function for lithium-ion secondary battery. J Power Sources 97–98:661–663CrossRef
31.
Cao J, Wang L, Fang M, He XM, Li JJ, Gao J, Deng LF, Wang JL, Chen H (2014) Structure and electrochemical properties of composite polymer electrolyte based on poly vinylidene fluoride-hexafluoropropylene/titania-poly(methyl methacrylate) for lithium-ion batteries. J Power Sources 246:499–504CrossRef
32.
Kim DW, Oh B, Park JH, Sun YK (2000) Gel-coated membranes for lithium-ion polymer batteries. Solid State Ion 138:41–49CrossRef
33.
Lee KS, Sun YK, Noh J, Song KS, Kim DW (2009) Improvement of high voltage cycling performance and thermal stability of lithium-ion cells by use of a thiophene additive. Electrochem Commun 11:1900–1903CrossRef
34.
Sun YK, Han JM, Myung ST, Lee SW, Amine K (2006) Significant improvement of high voltage cycling behavior AlF3-coated LiCoO2 cathode. Electrochem Commun 8:821–826CrossRef
35.
Sun YK, Cho SW, Myung ST, Amine K, Prakash J (2007) Effect of AlF3 coating amount on high voltage cycling performance of LiCoO2. Electrochim Acta 53:1013–1019CrossRef
36.
Chang W, Choi JW, Im JC, Lee JK (2010) Effects of ZnO coating on electrochemical performance and thermal stability of LiCoO2 as cathode material for lithium-ion batteries. J Power Sources 195:320–326CrossRef
37.
Oh SW, Myung ST, Oh SM, Yoon CS, Amine K, Sun YK (2010) Polyvinylpyrrolidone-assisted synthesis of microscale C-LiFePO4 with high tap density as positive electrode materials for lithium batteries. Electrochim Acta 55:1193–1199CrossRef
Metadaten
Titel
Preparation and performance of silica/polypropylene composite separator for lithium-ion batteries
verfasst von
Hongyu Liu
Jun Xu
Baohua Guo
Xiangming He
Publikationsdatum
01.10.2014
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 20/2014
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-014-8401-2

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