Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Bücher
Zeitschriften
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
MTZ-Fachkongress

Antriebe und Energiesysteme von morgen


Austausch von Automobil- und Energiewirtschaft

Am 14./15. Mai geht es in Chemnitz um die Mobilitätswende durch Elektro- und Wasserstofffahrzeuge.
Erweiterte Suche
Anmelden
nach oben
Polymer Bulletin
Erschienen in: Polymer Bulletin 7/2024

13.10.2023 | ORIGINAL PAPER

Preparation and properties of rapidly plasticized poly (butylene succinate)/mechanically activated cassava starch biocomposite

verfasst von: Yinhong Li, Zhengxin Li, Shuai Sheng, Yan Li, Jin-Rong Zhong, Jinlin Tan, Yue-Fei Zhang

Erschienen in: Polymer Bulletin | Ausgabe 7/2024

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Overcoming limitations of poly (butylene succinate) (PBS) and enabling non-toxic, rapid production could lay the foundation for expanding applications in various fields. In this work, mechanically activated cassava starch (ACS) was used to augment the toughness of PBS and reduce the plasticization time of starch. The composite was prepared by melt blending PBS with two types of activated cassava starch particles (native starch and ACS) and acetyl tributyl citrate (ATBC) as a non-toxic plasticizer. X-ray diffractometer (XRD), Fourier transform infrared spectrometer (FTIR), scanning electronic microscope (SEM), and differential scanning calorimetry (DSC) were used to investigate the structural changes, compatibility, and dispersibility of ACS particles in PBS. The results showed that under high-speed shear and grinding, the hydrogen bonds within ACS molecules were severely disrupted and the amorphous regions increased, leading to improved compatibility with PBS. Under the plasticization of ATBC, the cross-section of ACS composites was smoother. DSC results showed that addition of ACS significantly reduced crystallinity of PBS/ACS composites. Mechanical properties results showed that impact strength and elongation at break of PBS/ACS-12A were, respectively, increased by 125% and over 5 times compared with that of PBS. Water absorption test and contact angle test demonstrate a significant improvement in the water resistance of PBS/ACS. This study provides a simple and feasible method for preparing low-cost PBS biocomposites, and their extensions are expected to further replace general-purpose plastics in daily application.
Vorheriger Artikel Strength and ductility of reinforced concrete using basalt fibre-reinforced polymers
Nächster Artikel Efficient single-crystal 4-N,N-dimethylamino-4-N-methyl-stilbazolium tosylate (DAST) on the optical, piezoelectric coefficient and structure of P(VDF-HFP) copolymer for energy conversion systems

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Liu G-C, Zhang W-Q, Wang X-L, Wang Y-Z (2017) Synthesis and performances of poly (butylene-succinate) with enhanced viscosity and crystallization rate via introducing a small amount of diacetylene groups. Chin Chem Lett 28(2):354–357
2.
Luyt AS, Malik SS (2019) Can biodegradable plastics solve plastic solid waste accumulation? Plastics to energy. Elsevier, Norwich, pp 403–423
3.
Zhang S, He Y, Yin Y, Jiang G (2019) Fabrication of innovative thermoplastic starch bio-elastomer to achieve high toughness poly (butylene succinate) composites. Carbohydr Polym 206:827–836PubMed
4.
Zhu C, Zhang Z, Liu Q, Wang Z, Jin J (2003) Synthesis and biodegradation of aliphatic polyesters from dicarboxylic acids and diols. J Appl Polym Sci 90(4):982–990
5.
Jacquel N, Freyermouth F, Fenouillot F, Rousseau A, Pascault JP, Fuertes P, Saint-Loup R (2011) Synthesis and properties of poly (butylene succinate): efficiency of different transesterification catalysts. J Polym Sci Part A Polym Chem 49(24):5301–5312
6.
Zakharova E, Lavilla C, Alla A, de Ilarduya AM, Muñoz-Guerra S (2014) Modification of properties of poly (butylene succinate) by copolymerization with tartaric acid-based monomers. Eur Polym J 61:263–273
7.
Jin HJ, Kim DS, Kim MN, Lee IM, Lee HS, Yoon JS (2001) Synthesis and properties of poly (butylene succinate) with N-hexenyl side branches. J Appl Polym Sci 81(9):2219–2226
8.
Shi K, Bai Z, Su T, Wang Z (2019) Selective enzymatic degradation and porous morphology of poly (butylene succinate)/poly (lactic acid) blends. Int J Biol Macromol 126:436–442PubMed
9.
Jiang L, Zhang J (2017) Biodegradable and biobased polymers. Applied plastics engineering handbook. Elsevier, Norwich, pp 127–143
10.
Abushammala H, Mao J (2020) Impact of the surface properties of cellulose nanocrystals on the crystallization kinetics of poly (butylene succinate). Crystals 10(3):196
11.
Savitha K, Paghadar BR, Kumar MS, Jagadish R (2022) Polybutylene succinate, a potential bio-degradable polymer: synthesis, copolymerization and bio-degradation. Polym Chem 13(24):3562–3612
12.
Aliotta L, Seggiani M, Lazzeri A, Gigante V, Cinelli P (2022) A brief review of poly (butylene succinate)(PBS) and its main copolymers: synthesis, blends, composites, biodegradability, and applications. Polymers 14(4):844PubMedPubMedCentral
13.
Freitas PA, González-Martínez C, Chiralt A (2023) Using rice straw fractions to develop reinforced, active PLA-starch bilayers for meat preservation. Food Chem 405:134990PubMed
14.
Akay O, Altinkok C, Acik G, Yuce H, Ege GK (2021) A bio-based and non-toxic polyurethane film derived from luffa cylindrica cellulose and ʟ-Lysine diisocyanate ethyl ester. Eur Polym J 161:110856
15.
Hararak B, Wanmolee W, Wijaranakul P, Prakymoramas N, Winotapun C, Kraithong W, Nakason K (2023) Physicochemical properties of lignin nanoparticles from softwood and their potential application in sustainable pre-harvest bagging as transparent UV-shielding films. Int J Biol Macromol 229:575–588PubMed
16.
Park H, Oh J, Park Y, Kim S, Kim J (2022) Environmentally sustainable particulate filter fabricated via induced phase separation of bioderived fungal chitin and poly (lactic acid). Acs appl polym mater 5(1):452–462
17.
Zeeman SC, Kossmann J, Smith AM (2010) Starch: its metabolism, evolution, and biotechnological modification in plants. Annu Rev Plant Biol 61:209–234PubMed
18.
Sankri A, Arhaliass A, Dez I, Gaumont AC, Grohens Y, Lourdin D, Pillin I, Rolland-Sabaté A, Leroy E (2010) Thermoplastic starch plasticized by an ionic liquid. Carbohydr Polym 82(2):256–263
19.
Qiao X, Tang Z, Sun K (2011) Plasticization of corn starch by polyol mixtures. Carbohydr Polym 83(2):659–664
20.
Schmitt H, Guidez A, Prashantha K, Soulestin J, Lacrampe M, Krawczak P (2015) Studies on the effect of storage time and plasticizers on the structural variations in thermoplastic starch. Carbohydr Polym 115:364–372PubMed
21.
Copeland L, Blazek J, Salman H, Tang MC (2009) Form and functionality of starch. Food Hydrocoll 23(6):1527–1534
22.
Lourdin D, Putaux J-L, Potocki-Véronèse G, Chevigny C, Rolland-Sabaté A, and Buléon A (2015) Crystalline structure in starch. Starch: Metabolism and Structure: 61-90.
23.
Vamadevan V, Bertoft E (2015) Structure-function relationships of starch components. Starch Stärke 67(1–2):55–68
24.
Zeng J-B, Jiao L, Li Y-D, Srinivasan M, Li T, Wang Y-Z (2011) Bio-based blends of starch and poly (butylene succinate) with improved miscibility, mechanical properties, and reduced water absorption. Carbohydr Polym 83(2):762–768
25.
Li J, Luo X, Lin X, Zhou Y (2013) Comparative study on the blends of PBS/thermoplastic starch prepared from waxy and normal corn starches. Starch Stärke 65(9–10):831–839
26.
Wang W, Zhang G, Zhang W, Guo W, Wang J (2013) Processing and thermal behaviors of poly (butylene succinate) blends with highly-filled starch and glycerol. J Polym Environ 21:46–53
27.
Abbott AP, Abolibda TZ, Davis SJ, Emmerling F, Lourdin D, Leroy E, Wise WR (2014) Glycol based plasticisers for salt modified starch. RSC Adv 4(76):40421–40427
28.
Zhang Y, and Rempel C (2012) Retrogradation and antiplasticization of thermoplastic starch. Thermoplastic Elastomers. 118119
29.
Mohammadi Nafchi A, Moradpour M, Saeidi M, Alias AK (2013) Thermoplastic starches: properties, challenges, and prospects. Starch Stärke 65(1–2):61–72
30.
Alonso-González M, Felix M, Guerrero A, Romero A (2021) Rice bran-based bioplastics: effects of the mixing temperature on starch plastification and final properties. Int J Biol Macromol 188:932–940PubMed
31.
Suchao-in K, Koombhongse P, Chirachanchai S (2014) Starch grafted poly (butylene succinate) via conjugating reaction and its role on enhancing the compatibility. Carbohydr Polym 102:95–102
32.
Suttiruengwong S, Sotho K, Seadan M (2014) Effect of glycerol and reactive compatibilizers on poly (butylene succinate)/starch blends. J Renew Mater 2(1):85–92
33.
Liu D, Qi Z, Zhang Y, Xu J, Guo B (2015) Poly (butylene succinate)(PBS)/ionic liquid plasticized starch blends: preparation, characterization, and properties. Starch Stärke 67(9–10):802–809
34.
Xu J, Chen Y, Tian Y, Yang Z, Zhao Z, Du W, Zhang X (2021) Effect of ionic liquid 1-buyl-3-methylimidazolium halide on the structure and tensile property of PBS/corn starch blends. Int J Biol Macromol 172:170–177PubMed
35.
Fang K, He W, Jiang Y, Li K, Li J (2020) Preparation, characterization and physicochemical properties of cassava starch-ferulic acid complexes by mechanical activation. Int J Biol Macromol 160:482–488PubMed
36.
Acik G (2019) Soybean oil modified bio-based poly (vinyl alcohol) s via ring-opening polymerization. J Polym Environ 27(11):2618–2623
37.
Wang M, Song X, Jiang J, Xia J, Ding H, Li M (2018) Plasticization and thermal behavior of hydroxyl and nitrogen rich group-containing tung-oil-based ester plasticizers for PVC. New J Chem 42(4):2422–2431
38.
Halloran MW, Danielczak L, Nicell JA, Leask RL, Marić M (2022) Highly flexible polylactide food packaging plasticized with nontoxic, biosourced glycerol plasticizers. Acs Appl Polym Mater 4(5):3608–3617
39.
Ouajai S, Shanks RA (2009) Biocomposites of cellulose acetate butyrate with modified hemp cellulose fibres. Macromol Mater Eng 294(3):213–221
40.
Pang C, Shanks RA, Daver F (2015) Characterization of kenaf fiber composites prepared with tributyl citrate plasticized cellulose acetate. Compos Part A Appl S 70:52–58
41.
Aliotta L, Canesi I, Lazzeri A (2021) Study on the preferential distribution of acetyl tributyl citrate in poly (lactic) acid-poly (butylene adipate-co-terephthalate) blends. Polym Test 98:107163
42.
Umemura RT, Felisberti MI (2021) Plasticization of poly (3-hydroxybutyrate) with triethyl citrate: thermal and mechanical properties, morphology, and kinetics of crystallization. J Appl Polym Sci 138(10):49990
43.
Zhang Z, Zhao S, Xiong S (2010) Morphology and physicochemical properties of mechanically activated rice starch. Carbohydr Polym 79(2):341–348
44.
Zhang Y, Li W, Huang M, Xu X, Jiang M, Hu H, Huang Z, Liang J, Qin Y (2021) Non-digesting strategy for efficient bioconversion of cassava to bioethanol via mechanical activation and metal salts pretreatment. Renew Energy 169:95–103
45.
Huang Z-Q, Lu J-P, Li X-H, Tong Z-F (2007) Effect of mechanical activation on physico-chemical properties and structure of cassava starch. Carbohydr Polym 68(1):128–135
46.
Zdanowicz M, Jędrzejewski R, Pilawka R (2019) Deep eutectic solvents as simultaneous plasticizing and crosslinking agents for starch. Int J Biol Macromol 129:1040–1046PubMed
47.
Bangar S P, Singh A, Ashogbon A O, and Bobade H (2023) Ball-milling: A sustainable and green approach for starch modification. Int J Biol Macromol 237
48.
Lv Y, Zhang L, Li M, He X, Hao L, Dai Y (2019) Physicochemical properties and digestibility of potato starch treated by ball milling with tea polyphenols. Int J Biol Macromol 129:207–213PubMed
49.
Su Y, Du H, Huo Y, Xu Y, Wang J, Wang L, Zhao S, Xiong S (2016) Characterization of cationic starch flocculants synthesized by dry process with ball milling activating method. Int J Biol Macromol 87:34–40PubMed
50.
Yao S-F, Chen X-T, Ye H-M (2017) Investigation of structure and crystallization behavior of poly (butylene succinate) by fourier transform infrared spectroscopy. J Phys Chem B 121(40):9476–9485PubMed
51.
Meng L, Yu L, Khalid S, Liu H, Zhang S, Duan Q, Chen L (2019) Preparation, microstructure and performance of poly (lactic acid)-Poly (butylene succinate-co-butyleneadipate)-starch hybrid composites. Compos Part B Eng 177:107384
52.
Liu R, Sun W, Zhang Y, Huang Z, Hu H, Zhao M (2019) Preparation of starch dough using damaged cassava starch induced by mechanical activation to develop staple foods: application in crackers. Food Chem 271:284–290PubMed
53.
He S, Qin Y, Walid E, Li L, Cui J, Ma Y (2014) Effect of ball-milling on the physicochemical properties of maize starch. Biotechnol rep 3:54–59
54.
Iovino R, Zullo R, Rao M, Cassar L, Gianfreda L (2008) Biodegradation of poly (lactic acid)/starch/coir biocomposites under controlled composting conditions. Polym Degrad Stab 93(1):147–157
55.
Then YY, Ibrahim NA, Zainuddin N, Ariffin H, Wan Yunus WMZ (2013) Oil palm mesocarp fiber as new lignocellulosic material for fabrication of polymer/fiber biocomposites. Int J Polym Sci 2013:797452
Metadaten
Titel
Preparation and properties of rapidly plasticized poly (butylene succinate)/mechanically activated cassava starch biocomposite
verfasst von
Yinhong Li
Zhengxin Li
Shuai Sheng
Yan Li
Jin-Rong Zhong
Jinlin Tan
Yue-Fei Zhang
Publikationsdatum
13.10.2023
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 7/2024
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-023-05018-7

Weitere Artikel der Ausgabe 7/2024

Polymer Bulletin 7/2024 Zur Ausgabe

ORIGINAL PAPER

Development of ciprofloxacin-loaded polymeric nanoparticles for drug delivery

ORIGINAL PAPER

DOPO-based derivatives with different phosphorous oxidation states as highly efficient flame retardants for epoxy resins

REVIEW PAPER

Effect of melt blending processing on mechanical properties of polymer nanocomposites: a review

EDITORIAL

Topical section “Advanced Testing of Soft Polymer Materials”

REVIEW PAPER

Advancements in eco-friendly food packaging through nanocomposites: a review

ORIGINAL PAPER

A novel sustainable composite hydrogel containing nanocellulose to remove potentially toxic metals from contaminated water

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise