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01.10.2023 | Research paper

Preparation of silver nanoparticles on free-standing polyaniline/cellulose acetate blend film for surface-enhanced Raman scattering application

verfasst von: Bismark Nogueira da Silva, Victor dos Santos Azevedo Leite, Frederico Garcia Pinto, Jairo Tronto, Celly Mieko Shinohara Izumi

Erschienen in: Journal of Nanoparticle Research | Ausgabe 10/2023

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Abstract

Polyaniline (PANI) has been used as a precursor for the preparation of surface-enhanced Raman scattering (SERS) substrates because of its ability to act as a reducing agent and binding site of plasmonic metal nanoparticles (NPs). However, the processability of PANI is limited due to its poor mechanical properties. In this work, a simple preparation of a free-standing polymeric blend film by mixing hydrochloric acid–doped polyaniline nanofibers (PANI) and cellulose acetate (CA) is demonstrated. This PANI/CA was used as a reducing agent for synthesizing Ag nanoparticles (AgNPs). The formation of globular NPs and cubic microstructures on the surface of the film was observed, as well as the formation of AgCl due to the presence of chloride ions in the PANI structure. The film was then treated with hydrazine to reduce AgCl to AgNPs resulting in isolated and clustered AgNPs. Rhodamine 6G dye was used as a probe molecule for SERS measurements. This new composite film PANI/CA@Ag treated with hydrazine was successfully applied as a SERS substrate. This substrate enhancement of Rhodamine 6G dye Raman bands was estimated, and the Rhodamine 6G dye could be detected even at a concentration of 10⁻⁷ mol L⁻¹.

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Vorheriger Artikel Estimation of the structure of binary Ag–Cu nanoparticles during their crystallization by computer simulation

Nächster Artikel Enhanced magnetoresistance and evolution of Griffiths-like phase in La1−xCaxMnO3 (x = 0.4, 0.5) nanoparticles

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Mohamad Ahad IZ, Wadi Harun S, Gan SN, Phang SW (2018) Polyaniline (PAni) optical sensor in chloroform detection. Sensors Actuators B Chem 261:97–105. https://doi.org/10.1016/j.snb.2018.01.082CrossRef

Yuan S, Tang Q, He B, Yang P (2014) Efficient quasi-solid-state dye-sensitized solar cells employing polyaniline and polypyrrole incorporated microporous conducting gel electrolytes. J Power Sources 254:98–105. https://doi.org/10.1016/j.jpowsour.2013.12.112CrossRef

Bandeira RM, van Drunen J, Garcia AC, Tremiliosi-Filho G (2017) Influence of the thickness and roughness of polyaniline coatings on corrosion protection of AA7075 aluminum alloy. Electrochim Acta 240:215–224. https://doi.org/10.1016/j.electacta.2017.04.083CrossRef

Wu X, Zhang W, Wang Q, Wang Y, Yan H, Chen W (2016) Hydrogen bonding of graphene/polyaniline composites film for solid electrochromic devices. Synth Met 212:1–11. https://doi.org/10.1016/j.synthmet.2015.12.001CrossRef

Xu P, Han X, Zhang B, Wang H (2014) Multifunctional polymer – metal nanocomposites via direct chemical. Chem Soc Rev 43:1349–1360. https://doi.org/10.1039/c3cs60380fCrossRef

Huang JX (2006) Syntheses and applications of conducting polymer polyaniline nanofibers. Pure Appl Chem 78:15–27. https://doi.org/10.1351/pac200678010015CrossRef

Li D, Huang J, Kaner RB (2009) Polyaniline nanofibers: a unique polymer nanostructure for versatile applications. Acc Chem Res 42:135–145. https://doi.org/10.1021/ar800080nCrossRef

Li D, Kaner RB (2005) Processable stabilizer-free polyaniline nanofiber aqueous colloids. Chem Commun:3286–3288. https://doi.org/10.1039/b504020e

Huang W-S, Humphrey BD, MacDiarmid AG (1986) Polyaniline, a novel conducting polymer. Morphology and chemistry of its oxidation and reduction in aqueous electrolytes. J Chem Soc Faraday Trans 82:2385–2400. https://doi.org/10.1039/F19868202385CrossRef

10.

MacDiarmid AG, Epstein AJ (1989) Polyanilines: a novel class of conducting polymers. Faraday Discuss Chem Soc 88:317–332. https://doi.org/10.1039/DC9898800317CrossRef

11.

Li W, Jia QX, Wang H-L (2006) Facile synthesis of metal nanoparticles using conducting polymer colloids. Polymer (Guildf) 47:23–26. https://doi.org/10.1016/j.polymer.2005.11.032CrossRef

12.

Wang H-L, Li W, Jia QX, Akhadov E (2007) Tailoring conducting polymer chemistry for the chemical deposition of metal particles and clusters. Chem Mater 19:520–525. https://doi.org/10.1021/cm0619508CrossRef

13.

Stejskal J, Trchová M, Brožová L, Prokeš J (2009) Reduction of silver nitrate by polyaniline nanotubes to produce silver-polyaniline composites. Chem Pap 63:77–83. https://doi.org/10.2478/s11696-008-0086-zCrossRef

14.

Stejskal J, Trchová M, Kovářová J, Prokeš J, Omastová M (2008) Polyaniline-coated cellulose fibers decorated with silver nanoparticles. Chem Pap 62:181–186. https://doi.org/10.2478/s11696-008-0009-zCrossRef

15.

Mack NH, Bailey JA, Doorn SK, Chen C-A, Gau H-M, Xu P, Williams DJ, Akhadov EA, Wang H-L (2011) Mechanistic study of silver nanoparticle formation on conducting polymer surfaces. Langmuir 27:4979–4985. https://doi.org/10.1021/la103644jCrossRef

16.

He Y, Han X, Chen D, Kang L, Jin W, Qiang R, Xu P, Du Y (2014) Chemical deposition of Ag nanostructures on polypyrrole films as active SERS substrates. RSC Adv 4:7202–7206. https://doi.org/10.1039/C3RA42577KCrossRef

17.

Li S, Xiong L, Liu S, Xu P (2014) Fast fabrication of homogeneous Ag nanostructures on dual-acid doped polyaniline for SERS applications. RSC Adv 4:16121–16126. https://doi.org/10.1039/C4RA02004ACrossRef

18.

Yan J, Han X, He J, Kang L, Zhang B, Du Y, Zhao H, Dong C, Wang H-L, Xu P (2012) Highly sensitive surface-enhanced Raman spectroscopy (SERS) platforms based on silver nanostructures fabricated on polyaniline membrane surfaces. ACS Appl Mater Interfaces 4:2752–2756. https://doi.org/10.1021/am300381vCrossRef

19.

Benahmed WN, Bekri-Abbes I, Srasra E (2018) Spectroscopic study of polyaniline/AgCl@Ag nanocomposites prepared by a one-step method. J Spectrosc 2018:7320654. https://doi.org/10.1155/2018/7320654CrossRef

20.

da Silva BN, Vieira MF, Izumi CMS (2022) In situ preparation of silver nanoparticles on polyaniline nanofibers for SERS applications. Synth Met 291. https://doi.org/10.1016/j.synthmet.2022.117171

21.

Rao GPC, Yang J (2010) Chemical reduction method for preparation of silver nanoparticles on a silver chloride substrate for application in surface-enhanced infrared optical sensors. Appl Spectrosc 64:1094–1099 https://opg.optica.org/as/abstract.cfm?URI=as-64-10-1094CrossRef

22.

Proń A, Zagorska M, Nicolau Y, Genoud F, Nechtschein M (1997) Highly conductive composites of polyaniline with plasticized cellulose acetate. Synth Met 84:89–90. https://doi.org/10.1016/S0379-6779(96)03850-7CrossRef

23.

Cerqueira DA, Valente AJM, Filho GR, Burrows HD (2009) Synthesis and properties of polyaniline–cellulose acetate blends: the use of sugarcane bagasse waste and the effect of the substitution degree. Carbohydr Polym 78:402–408. https://doi.org/10.1016/j.carbpol.2009.04.016CrossRef

24.

Marques AP, Brett CMA, Burrows HD, Monkman AP, Retimal B (2002) Spectral and electrochemical studies on blends of polyaniline and cellulose esters. J Appl Polym Sci 86:2182–2188. https://doi.org/10.1002/app.11169CrossRef

25.

Al-Ahmed A, Mohammad F, Zaki Ab M (2004) Rahman, Composites of polyaniline and cellulose acetate: preparation, characterization, thermo-oxidative degradation and stability in terms of DC electrical conductivity retention. Synth Met 144:29–49. https://doi.org/10.1016/j.synthmet.2004.01.007CrossRef

26.

Wang Y, Shi Y-F, Chen Y-B, Wu L-M (2012) Hydrazine reduction of metal ions to porous submicro-structures of Ag, Pd, Cu, Ni, and Bi. J Solid State Chem 191:19–26. https://doi.org/10.1016/j.jssc.2012.02.059CrossRef

27.

Gurusamy V, Krishnamoorthy R, Gopal B, Veeraravagan V, Neelamegam P (2017) Systematic investigation on hydrazine hydrate assisted reduction of silver nanoparticles and its antibacterial properties. Inorg Nano-Met Chem 47:761–767. https://doi.org/10.1080/15533174.2015.1137074CrossRef

28.

Tatarchuk VV, Sergievskaya AP, Korda TM, Druzhinina IA, Zaikovsky VI (2013) Kinetic factors in the synthesis of silver nanoparticles by reduction of Ag+ with hydrazine in reverse micelles of Triton N-42. Chem Mater 25:3570–3579. https://doi.org/10.1021/cm304115jCrossRef

29.

Nourafkan E, Alamdari A (2014) Study of effective parameters in silver nanoparticle synthesis through method of reverse microemulsion. J Ind Eng Chem 20:3639–3645. https://doi.org/10.1016/j.jiec.2013.12.059CrossRef

30.

Szczepanowicz K, Stefanska J, Socha RP, Warszynski P (2010) Preparation of silver nanoparticles via chemical reduction and their antimicrobial activity. Physicochem Probl Miner Proces 45:85–98

31.

Dugandžić V, Hidi IJ, Weber K, Cialla-May D, Popp J (2016) In situ hydrazine reduced silver colloid synthesis – enhancing SERS reproducibility. Anal Chim Acta 946:73–79. https://doi.org/10.1016/j.aca.2016.10.018CrossRef

32.

Zielińska A, Skwarek E, Zaleska A, Gazda M, Hupka J (2009) Preparation of silver nanoparticles with controlled particle size. Procedia Chem 1:1560–1566. https://doi.org/10.1016/j.proche.2009.11.004CrossRef

33.

Huang J, Kaner RB (2004) Nanofiber formation in the chemical polymerization of aniline: A mechanistic study. Angew Chem Int Ed 43:5817–5821. https://doi.org/10.1002/anie.200460616CrossRef

34.

Pouget JP, Jozefowicz ME, Epstein AJ, Tang X, MacDiarmid AG (1991) X-ray structure of polyaniline. Macromolecules 24:779–789. https://doi.org/10.1021/ma00003a022CrossRef

35.

Tiwari JP, Rao CRK (2008) Template synthesized high conducting silver chloride nanoplates. Solid State Ionics 179:299–304. https://doi.org/10.1016/j.ssi.2008.01.097CrossRef

36.

Medina-Ramirez I, Bashir S, Luo Z, Liu JL (2009) Green synthesis and characterization of polymer-stabilized silver nanoparticles. Colloids Surf B: Biointerfaces 73:185–191. https://doi.org/10.1016/j.colsurfb.2009.05.015CrossRef

37.

Ghaly HA, El-Kalliny AS, Gad-Allah TA, Abd El-Sattar NEA, Souaya ER (2017) Stable plasmonic Ag/AgCl–polyaniline photoactive composite for degradation of organic contaminants under solar light. RSC Adv 7:12726–12736. https://doi.org/10.1039/C6RA27957KCrossRef

38.

Ćirić-Marjanović G, Trchová M, Stejskal J (2008) The chemical oxidative polymerization of aniline in water: Raman spectroscopy. J Raman Spectrosc 39:1375–1387. https://doi.org/10.1002/jrs.2007CrossRef

39.

Trchová M, Morávková Z, Bláha M, Stejskal J (2014) Raman spectroscopy of polyaniline and oligoaniline thin films. Electrochim Acta 122:28–38. https://doi.org/10.1016/J.ELECTACTA.2013.10.133CrossRef

40.

Boyer MI, Quillard S, Rebourt E, Louarn G, Buisson JP, Monkman A, Lefrant S (1998) Vibrational analysis of polyaniline: a model compound approach. J Phys Chem B 102:7382–7392. https://doi.org/10.1021/jp972652oCrossRef

41.

do Nascimento GM, Constantino VRL, Landers R, Temperini MLA (2004) Aniline polymerization into montmorillonite clay: a spectroscopic investigation of the intercalated conducting polymer. Macromolecules 37:9373–9385. https://doi.org/10.1021/ma049054+CrossRef

42.

do Nascimento GM, Silva CHB, Izumi CMS, Temperini MLA (2008) The role of cross-linking structures to the formation of one-dimensional nano-organized polyaniline and their Raman fingerprint. Spectrochim Acta A Mol Biomol Spectrosc 71:869–875. https://doi.org/10.1016/j.saa.2008.02.009CrossRef

43.

Vos KD, Burris FO Jr, Riley RL (1966) Kinetic study of the hydrolysis of cellulose acetate in the pH range of 2–10. J Appl Polym Sci 10:825–832. https://doi.org/10.1002/app.1966.070100515CrossRef

44.

Yamashita Y, Endo T (2004) Deterioration behavior of cellulose acetate films in acidic or basic aqueous solutions. J Appl Polym Sci 91:3354–3361. https://doi.org/10.1002/app.13547CrossRef

45.

Sun Y, MacDiarmid AG, Epstein AJ (1990) Polyaniline: synthesis and characterization of pernigraniline base. J Chem Soc Chem Commun:529–531. https://doi.org/10.1039/C39900000529

46.

Green AG, Woodhead AE (1910) CCXLIII.—Aniline-black and allied compounds. Part I. J Chem Soc Trans 97:2388–2403. https://doi.org/10.1039/CT9109702388CrossRef

47.

Mondal S, Rana U, Malik S (2015) Facile decoration of polyaniline fiber with Ag nanoparticles for recyclable SERS substrate. ACS Appl Mater Interfaces 7:10457–10465. https://doi.org/10.1021/acsami.5b01806CrossRef

48.

Hildebrandt P, Stockhurger M (1984) Surface-enhanced resonance Raman spectroscopy of Rhodamine 6G adsorbed on colloidal silver. J Phys Chem 88:5935–5944. https://doi.org/10.1021/j150668a038CrossRef

49.

Majoube M, Henry M (1991) Fourier transform Raman and infrared and surface-enhanced Raman spectra for rhodamine 6G. Spectrochim Acta A 47:1459–1466. https://doi.org/10.1016/0584-8539(91)80237-DCrossRef

50.

Shim S, Stuart CM, Mathies RA (2008) Resonance Raman cross-sections and vibronic analysis of Rhodamine 6G from broadband stimulated Raman spectroscopy. ChemPhysChem 9:697–699. https://doi.org/10.1002/cphc.200700856CrossRef

51.

Jensen L, Schatz GC (2006) Resonance Raman scattering of Rhodamine 6G as calculated using time-dependent density functional theory. J Phys Chem A 110:5973–5977. https://doi.org/10.1021/jp0610867CrossRef

52.

Zhu J, Sun L, Shan Y, Zhi Y, Chen J, Dou B, Su W (2021) Green preparation of silver nanofilms as SERS-active substrates for Rhodamine 6G detection. Vacuum 187:110096. https://doi.org/10.1016/j.vacuum.2021.110096CrossRef

53.

Turley HK, Hu Z, Jensen L, Camden JP (2017) Surface-enhanced resonance hyper-Raman scattering elucidates the molecular orientation of Rhodamine 6G on silver colloids. J Phys Chem Lett 8:1819–1823. https://doi.org/10.1021/acs.jpclett.7b00498CrossRef

54.

Michaels AM, Jiang L (2000) Brus, Ag nanocrystal junctions as the site for surface-enhanced Raman scattering of single Rhodamine 6G molecules. J Phys Chem B 104:11965–11971. https://doi.org/10.1021/jp0025476CrossRef

55.

Kudelski A (2005) Raman studies of rhodamine 6G and crystal violet sub-monolayers on electrochemically roughened silver substrates: do dye molecules adsorb preferentially on highly SERS-active sites? Chem Phys Lett 414:271–275. https://doi.org/10.1016/j.cplett.2005.08.075CrossRef

56.

Ameer FS, Pittman CU Jr, Zhang D (2013) Quantification of resonance Raman enhancement factors for Rhodamine 6G (R6G) in water and on gold and silver nanoparticles: implications for single-molecule R6G SERS. J Phys Chem C 117:27096–27104. https://doi.org/10.1021/jp4105932CrossRef

57.

Le Ru EC, Blackie E, Meyer M, Etchegoin PG (2007) Surface enhanced Raman scattering enhancement factors: a comprehensive study. J Phys Chem C 111:13794–13803. https://doi.org/10.1021/jp0687908CrossRef

58.

Lu C-H, Cheng M-R, Chen S, Syu W-L, Chien M-Y, Wang K-S, Chen J-S, Lee P-H, Liu T-Y (2023) Flexible PDMS-based SERS substrates replicated from beetle wings for water pollutant detection. Polymers (Basel) 15. https://doi.org/10.3390/polym15010191

59.

Wu H-Y, Lin H-C, Liu Y-H, Chen K-L, Wang Y-H, Sun Y-S, Hsu J-C (2022) Highly sensitive, robust, and recyclable TiO2/AgNP substrate for SERS detection. Molecules 27. https://doi.org/10.3390/molecules27196755

60.

Zhang W, Xue T, Zhang L, Lu F, Liu M, Meng C, Mao D, Mei T (2019) Surface-enhanced Raman spectroscopy based on a silver-film semi-coated nanosphere array. Sensors 19. https://doi.org/10.3390/s19183966

Titel: Preparation of silver nanoparticles on free-standing polyaniline/cellulose acetate blend film for surface-enhanced Raman scattering application
verfasst von: Bismark Nogueira da Silva
Victor dos Santos Azevedo Leite
Frederico Garcia Pinto
Jairo Tronto
Celly Mieko Shinohara Izumi
Publikationsdatum: 01.10.2023
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 10/2023
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-023-05853-9

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