Skip to main content
Erschienen in: Journal of Materials Science: Materials in Electronics 11/2024

01.04.2024

Rational design of yolk-shell CoFe2O4 nanospheres towards enhanced lithium storage performance

verfasst von: Xiaoman Meng, Shiqi Chen, Jinkai Wang, Shuoyu Wang, Zhi Liu, Zhengdong Wang

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 11/2024

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Co–Fe bimetal oxides have attracted increasing attention owing to their high theoretical capacity and multiple electrochemically active sites for lithium-ion battery which widely applied in electric/hybrid electric vehicles and renewable energy storage. However, Co–Fe bimetal oxides still suffer from the inherently poor conductivity and severe volume change upon lithiation/delithiation process, thus resulting in poor cycle stability. Herein, the yolk-shell CoFe2O4 nanospheres were prepared by a solvothermal method and subsequent calcination strategy. The phase and morphology can affect the electrochemical storage performance by adjusting the annealing temperature. Benefiting from the unique structure, the yolk-shell CoFe2O4 electrode displayed improved lithium storage performance and excellent rate capability, delivering a reversible capacity of ~ 912.7 mAh g−1 at 200 mA g−1 and 694.3 mAh g−1 at even a high current density of 1000 mA g−1. More importantly, this novel strategy can be commonly used to design various other bimetal oxides with novel nanostructures, which is promising for developing advanced electrodes for high-performance energy storage devices.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Anhänge
Nur mit Berechtigung zugänglich
Literatur
12.
Zurück zum Zitat J.G. Kim, Y. Noh, Y. Kim, S. Lee, W.B. Kim, Fabrication of three-dimensional ordered macroporous spinel CoFe2O4 as efficient bifunctional catalysts for the positive electrode of lithium–oxygen batteries. J. Nanoscale Commun. 916, 5119–5128 (2017). https://doi.org/10.1039/c7nr00052aCrossRef J.G. Kim, Y. Noh, Y. Kim, S. Lee, W.B. Kim, Fabrication of three-dimensional ordered macroporous spinel CoFe2O4 as efficient bifunctional catalysts for the positive electrode of lithium–oxygen batteries. J. Nanoscale Commun. 916, 5119–5128 (2017). https://​doi.​org/​10.​1039/​c7nr00052aCrossRef
13.
Zurück zum Zitat Z.-J. Jiang, S. Cheng, H. Rong, Z. Jiang, J. Huang, General synthesis of MFe2O4/carbon (M = zn, Mn, Co, Ni) spindles from mixed metal organic frameworks as high performance anodes for lithium ion batteries. J. Mater. Chem. Commun. 545, 23641–23650 (2017). https://doi.org/10.1039/c7ta07097gCrossRef Z.-J. Jiang, S. Cheng, H. Rong, Z. Jiang, J. Huang, General synthesis of MFe2O4/carbon (M = zn, Mn, Co, Ni) spindles from mixed metal organic frameworks as high performance anodes for lithium ion batteries. J. Mater. Chem. Commun. 545, 23641–23650 (2017). https://​doi.​org/​10.​1039/​c7ta07097gCrossRef
18.
19.
36.
Zurück zum Zitat B. Wang, S. Li, X. Wu, B. Li, J. Liu, M. Yu, Nanocrystal-constructed mesoporous CoFe2O4 nanowire arrays aligned on flexible carbon fabric as integrated anodes with enhanced lithium storage properties. J. Phys. Chem. Chem. Phys. Commun. 1733, 21476–21484 (2015). https://doi.org/10.1039/c5cp03042kCrossRef B. Wang, S. Li, X. Wu, B. Li, J. Liu, M. Yu, Nanocrystal-constructed mesoporous CoFe2O4 nanowire arrays aligned on flexible carbon fabric as integrated anodes with enhanced lithium storage properties. J. Phys. Chem. Chem. Phys. Commun. 1733, 21476–21484 (2015). https://​doi.​org/​10.​1039/​c5cp03042kCrossRef
37.
Zurück zum Zitat C. Wang, H. Su, Y. Ma, D. Yang, Y. Dong, D. Li, L. Wang, Y. Liu, J. Zhang, Coordination polymers-derived three-dimensional hierarchical CoFe2O4 hollow spheres as high-performance lithium ion storage. ACS Appl. Mater. Interfaces Commun. 1034, 28679–28685 (2018). https://doi.org/10.1021/acsami.8b09459CrossRef C. Wang, H. Su, Y. Ma, D. Yang, Y. Dong, D. Li, L. Wang, Y. Liu, J. Zhang, Coordination polymers-derived three-dimensional hierarchical CoFe2O4 hollow spheres as high-performance lithium ion storage. ACS Appl. Mater. Interfaces Commun. 1034, 28679–28685 (2018). https://​doi.​org/​10.​1021/​acsami.​8b09459CrossRef
38.
Zurück zum Zitat F. Xue, Y. Li, C. Liu, Z. Zhang, J. Lin, J. Hao, Q. Li, Engineering flexible carbon nanofiber concatenated MOF-derived hollow octahedral CoFe2O4 as an anode material for enhanced lithium storage. J. Inorg. Chem. Front. Commun. 813, 3363–3370 (2021). https://doi.org/10.1039/d1qi00414jCrossRef F. Xue, Y. Li, C. Liu, Z. Zhang, J. Lin, J. Hao, Q. Li, Engineering flexible carbon nanofiber concatenated MOF-derived hollow octahedral CoFe2O4 as an anode material for enhanced lithium storage. J. Inorg. Chem. Front. Commun. 813, 3363–3370 (2021). https://​doi.​org/​10.​1039/​d1qi00414jCrossRef
39.
Zurück zum Zitat Z. Zhang, C. Yang, C. Fang, W. Yang, X. Zhang, Z. Rong, X. Li, Y. Jung, J. Lu, X. Dong, Laser ablation of pristine Fe foil for constructing a layer-by-layer SiO2/Fe2O3/Fe integrated anode for high cycling-stability lithium-ion batteries. J. Phys. Chem. Chem. Phys. Commun. 2317, 10365–10376 (2021). https://doi.org/10.1039/d1cp00153aCrossRef Z. Zhang, C. Yang, C. Fang, W. Yang, X. Zhang, Z. Rong, X. Li, Y. Jung, J. Lu, X. Dong, Laser ablation of pristine Fe foil for constructing a layer-by-layer SiO2/Fe2O3/Fe integrated anode for high cycling-stability lithium-ion batteries. J. Phys. Chem. Chem. Phys. Commun. 2317, 10365–10376 (2021). https://​doi.​org/​10.​1039/​d1cp00153aCrossRef
42.
Zurück zum Zitat D. Narsimulu, O. Padmaraj, E. Srinadhu, N. Satyanarayana, Synthesis, characterization and electrical properties of mesoporous nanocrystalline CoFe2O4 as a negative electrode material for lithium battery applications. J. Mater. Science: Mater. Electron. Commun. 28, 17208–17214 (2017). https://doi.org/10.1007/s10854-017-7650-7CrossRef D. Narsimulu, O. Padmaraj, E. Srinadhu, N. Satyanarayana, Synthesis, characterization and electrical properties of mesoporous nanocrystalline CoFe2O4 as a negative electrode material for lithium battery applications. J. Mater. Science: Mater. Electron. Commun. 28, 17208–17214 (2017). https://​doi.​org/​10.​1007/​s10854-017-7650-7CrossRef
43.
Zurück zum Zitat Y. Xiang, H. Wu, K.H. Zhang, M. Coto, T. Zhao, S. Chen, B. Dong, S. Lu, A. Abdelkader, Y. Guo, Quick one-pot synthesis of amorphous carbon-coated cobalt–ferrite twin elliptical frustums for enhanced lithium storage capability. J. Mater. Chem. Commun. 517, 8062–8069 (2017). https://doi.org/10.1039/c7ta02136dCrossRef Y. Xiang, H. Wu, K.H. Zhang, M. Coto, T. Zhao, S. Chen, B. Dong, S. Lu, A. Abdelkader, Y. Guo, Quick one-pot synthesis of amorphous carbon-coated cobalt–ferrite twin elliptical frustums for enhanced lithium storage capability. J. Mater. Chem. Commun. 517, 8062–8069 (2017). https://​doi.​org/​10.​1039/​c7ta02136dCrossRef
Metadaten
Titel
Rational design of yolk-shell CoFe2O4 nanospheres towards enhanced lithium storage performance
verfasst von
Xiaoman Meng
Shiqi Chen
Jinkai Wang
Shuoyu Wang
Zhi Liu
Zhengdong Wang
Publikationsdatum
01.04.2024
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 11/2024
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-024-12560-1

Weitere Artikel der Ausgabe 11/2024

Journal of Materials Science: Materials in Electronics 11/2024 Zur Ausgabe

Neuer Inhalt