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Journal of Materials Science
Erschienen in: Journal of Materials Science 18/2016

21.06.2016 | Original Paper

Reinforced polyaniline/polyvinyl alcohol conducting hydrogel from a freezing–thawing method as self-supported electrode for supercapacitors

verfasst von: Huabo Huang, Junlong Yao, Liang Li, Fen Zhu, Zhitian Liu, Xiaoping Zeng, Xianghua Yu, Zhiliang Huang

Erschienen in: Journal of Materials Science | Ausgabe 18/2016

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Abstract

In the present work, by using the in situ polymerization of aniline in acidic aqueous solution of PVA and freezing–thawing method, the reinforced conducting polymer hydrogel of polyaniline/polyvinyl alcohol (PANI/PVA) was prepared and directly used as the self-supported electrode for supercapacitor. The chemical structure of PANI/PVA hydrogel was characterized by UV–Vis, and the three-dimensional (3D) interconnected hierarchical nanoporous structure was observed by scanning electron microscopy. The measurement of compressive strength demonstrated the high mechanical strength of the hydrogel. The electrochemical properties of PANI/PVA hydrogel electrodes were evaluated by using cyclic voltammetry, electrochemical impedance spectroscopy and galvanostatic charge/discharge, which indicated their good responsiveness and rate capability, low resistance, high specific capacitance (240 F/g at current density of 1 A/g) and excellent cycling stability. The easily fabricated PANI/PVA hydrogel combined hierarchical nanoporous microstructure, self-supported feature and favorable capacitive behavior and provided a new strategy for constructing high-performance electrode for supercapacitors.
Vorheriger Artikel Bioinspired durable superhydrophobic materials with antiwear property fabricated from quartz sands and organosilane
Nächster Artikel Thermal radiative and thermodynamic properties of solid and liquid uranium and plutonium carbides in the visible–near-infrared range

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Metadaten
Titel
Reinforced polyaniline/polyvinyl alcohol conducting hydrogel from a freezing–thawing method as self-supported electrode for supercapacitors
verfasst von
Huabo Huang
Junlong Yao
Liang Li
Fen Zhu
Zhitian Liu
Xiaoping Zeng
Xianghua Yu
Zhiliang Huang
Publikationsdatum
21.06.2016
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 18/2016
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-016-0137-8

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