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International Journal of Plastics Technology

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01.12.2014 | Research Article

Rheology of multiphase polymer blends with and without reactive compatibiliser: evaluation of interfacial tension using theoretical predictions

verfasst von: Seno Jose, Sabu Thomas, Indose Aravind, J. Karger-Kocsis

Erschienen in: International Journal of Plastics Technology | Ausgabe 2/2014

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Abstract

The phase morphology and rheology of polyamide 12/polypropylene (PA12/PP) blends have been studied. Effects of blend ratio and reactive compatibilisation on the rheological properties of compatibilised and uncompatibilised blends were analysed. The viscosity ratio between the polymers was found to be sensitive to frequency. The complex viscosity and dynamic modulus increased with increase in the amount of compatibiliser, up to critical micelle concentration. The interfacial tension between the polymers was calculated from the storage modulus of the blends using Palierne and Choi-Schowalter models. It was found that the rheological properties of both compatibilised and uncompatibilised blends are intimately related to their phase morphology.

Vorheriger Artikel Influence of interface interaction on thermal, mechanical and conducting properties of segmented poly (azo-urethane)/carbon nanotube composites

Nächster Artikel An annular rotating-die technique in extrusion process: effect of mandrel rotating speed on entrance pressure drop and flow properties of molten HDPE

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Oldroyd JG (1953) Elastic and viscous properties of emulsions and suspensions. Proc Roy Soc London A218:122–132. doi:10.1098/rspa.1953.0092 CrossRef

Choi SJ, Schowalter WR (1975) Rheological properties of nondilute suspensions of deformable particles. Phys Fluids 18:420–427. doi:10.1063/1.861167 CrossRef

Graebling D, Froelich D, Muller R (1989) Viscoelastic properties of polydimethylsiloxane-polyoxyethylene blends in the melt. Emulsion model. J Rheol 33:1283–1291. doi:10.1122/1.550051 CrossRef

Palierne JF (1990) Linear rheology of viscoelastic emulsions with interfacial tension. Rheol Acta 29:204–214. doi:10.1007/BF01331356 CrossRef

Gramespacher H, Meissner J (1992) Interfacial tension between polymer melts measured by shear oscillations of their blends. J Rheol 36:1127–1141. doi:10.1122/1.550304 CrossRef

Bousmina M, Bataille P, Sapieha S, Schreiber HP (1995) Comparing the effect of corona treatment and block copolymer addition on rheological properties of polystyrene/polyethylene blends. J Rheol 39:499–517. doi:10.1122/1.550709 CrossRef

Lacroix C, Aressy M, Carreau PJ (1997) Linear viscoelastic behavior of molten polymer blends: a comparative study of the Palierne and Lee and Park models. Rheol Acta 36:416–428CrossRef

Gallego R, García-López D, López-Quintana S, Gobernado-Mitre I, Merino JC, Pastor JM (2008) Toughening of PA6/mEPDM blends by two methods of compounding, extruder and internal mixer: rheological, morphological and mechanical characterization. Polym Bull 60:665–675. doi:10.1007/s00289-008-0902-1 CrossRef

Ares A, Silva J, Maia JM, Barral L, Abad MJ (2009) Rheomechanical and morphological study of compatibilized PP/EVOH blends. Rheol Acta 48:993–1004. doi:10.1007/s00397-009-0381-9 CrossRef

10.

Aravind I, Jose S, Ahn KH, Thomas S (2010) Rheology and morphology of polytrimethylene terephthalate/ethylene propylene diene monomer blends in the presence and absence of a reactive compatibilizer. Polym Eng Sci 50:1945–1955. doi:10.1002/pen.21723 CrossRef

11.

Maani A, Heuzey M-C, Carreau PJ (2011) Coalescence in thermoplastic olefin (TPO) blends under shear flow. Rheol Acta 50:881–895. doi:10.1007/s00397-010-0501-6 CrossRef

12.

Graebling D, Muller R, Palierne JF (1993) Linear viscoelastic behavior of some incompatible polymer blends in the melt. Interpretation of data with a model of emulsion of viscoelastic liquids. Macromolecules 26:320–329. doi:10.1021/ma00054a011 CrossRef

13.

Riemann R-E, Cantow H-J, Chr F (1997) Interpretation of a new interface-governed relaxation process in compatibilised polymer blends. Macromolecules 30:5476–5484. doi:10.1021/ma961814w CrossRef

14.

Asthana H, Jayaraman K (1999) Rheology of reactively compatibilised polymer blends with varying extent of interfacial reaction. Macromolecules 32:3412–3419. doi:10.1021/ma980181d CrossRef

15.

Jafari SH, Yavari A, Asadinezhad A, Khonakdar HA, Bohme F (2005) Correlation of morphology and rheological response of interfacially modified PTT/m-LLDPE blends with varying extent of modification. Polymer 46:5082–5093. doi:10.1016/j.polymer.2005.04.045 CrossRef

16.

Silva J, Machado AV, Maia J (2007) Rheological behavior of compatibilized and non-compatibilized PA6/EPM blends. Rheol Acta 46:1091–1097. doi:10.1007/s00397-007-0201-z CrossRef

17.

Lee HG, Sung Y-T, Lee YK, Kim WN, Yoon HG, Lee HS (2009) Effects of PP-g-MAH on the mechanical, morphological and rheological properties of polypropylene and poly(acrylonitrile-butadiene-styrene) blends. Macromol Res 17:417–423. doi:10.1007/BF03218883 CrossRef

18.

Taheri M, Morshedian J, Khonakdar HA (2011) Effect of compatibilizer on interfacial tension of SAN/EPDM blend as measured via relaxation spectrums calculated from Palierne and Choi–Schowalter models. Polym Bull 66:363–376. doi:10.1007/s00289-010-0336-4 CrossRef

19.

Al-Mulla A, Alfadhel K, Qambar G, Shaban H (2013) Rheological study of recycled polypropylene–starch blends. Polym Bull 70:2599–2618. doi:10.1007/s00289-013-0977-1 CrossRef

20.

Favis BD (2000) In: Paul DR, Bucknall CB (eds) Polymer blends, vol 1. New York, Wiley Interscience

21.

Everaert V, Aerts L, Groeninckx G (1999) Phase morphology development in immiscible PP/(PS/PPE) blends: Influence of melt viscosity ratio and blend composition. Polymer 40:6627–6644. doi:10.1016/S0032-3861(99)00048-8 CrossRef

22.

Kim WN, Denn MM (1992) Properties of a thermotropic liquid crystalline polymer with a flexible polymer (Vectra/PET). J Rheol 36:1477–1498. doi:10.1122/1.550269 CrossRef

23.

Sung YT, Han MS, Hyun JC, Kim WN, Lee SS (2003) Rheological properties and interfacial tension of polypropylene poly(styrene-co-acrylonitrile) blend containing compatibiliser. Polymer 44:1681–1687. doi:10.1016/S0032-3861(02)00920-5 CrossRef

24.

Macaubas PHP, Demarquette NR (2001) Morphologies and interfacial tensions of immiscible polypropylene/polystyrene blends modified with triblock copolymers. Polymer 42:2543–2554. doi:10.1016/S0032-3861(00)00655-8 CrossRef

25.

Tschoegle NW (1989) The phenomenological theory of linear viscoelastic behaviour. Springer, Berlin. doi:10.1007/978-3-642-73602-5 CrossRef

26.

Taylor GT (1932) The viscosity of a fluid containing small drops of another. Proc Roy Soc London A138:41–48. doi:10.1098/rspa.1932.0169 CrossRef

27.

Wu S (1987) Formation of dispersed phase in incompatible blends: interfacial and rheological effects. Polym Eng Sci 27:335–343. doi:10.1002/pen.760270506 CrossRef

28.

Lepers JC, Favis BD, Tabar RJ (1997) The relative role of coalescence and interfacial tension in controlling dispersed phase size reduction during the compatibilization of polyethylene terephthalate/polypropylene blends. J Polym Sci B Polym Phys 35:2271–2280. doi:10.1002/(SICI)1099-0488(199710)35:14<2271::AID-POLB7>3.0.CO;2-Z CrossRef

29.

Liang H, Favis BD, Yu YS, Eisenberg A (1999) Correlation between the interfacial tension and dispersed phase morphology in interfacially modified blends of LLDPE and PVC. Macromolecules 32:1637–1642. doi:10.1021/ma9805553 CrossRef

30.

Tokita N (1977) Analysis of morphology formation in elastomer blends. Rubber Chem Technol 50:292–300. doi:10.5254/1.3535144 CrossRef

31.

Retsos H, Margiolaki I, Messaritaki A, Anastasiadis SH (2001) Interfacial tension in binary polymer blends in the presence of block copolymers: effects of additive MW. Macromolecules 34:5295–5305. doi:10.1021/ma002105s CrossRef

32.

Anastasiadis SH (2011) Interfacial tension in binary polymer blends and the effects of copolymers as emulsifying agents. Adv Polym Sci 238:179–269. doi:10.1007/12_2010_81 CrossRef

33.

Cerclé C, Favis BD (2012) Generalizing interfacial modification in polymer blends. Polymer 53:4338–4343. doi:10.1016/j.polymer.2012.07.027 CrossRef

34.

Thomas S, Groeninckx G (1999) Reactive compatibilization of heterogeneous ethylene propylene rubber (EPM)/nylon 6 blends by the addition of compatibiliser precursor EPM-g-MA. Polymer 40:5799–5819. doi:10.1016/S0032-3861(98)00813-1 CrossRef

35.

Van Puyvelde P, Oommen Z, Koets P, Groeninckx G, Moldenaers P (2003) Effect of reactive compatibilization on the interfacial slip in nylon-6/EPR blends. Polym Eng Sci 43:71–77. doi:10.1002/pen.10006 CrossRef

36.

Kim JK, Kim S, Park CE (1997) Compatibilization mechanism of polymer blends with an in-situ compatibilizer. Polymer 38:2155–2164. doi:10.1016/S0032-3861(96)00750-1 CrossRef

Titel: Rheology of multiphase polymer blends with and without reactive compatibiliser: evaluation of interfacial tension using theoretical predictions
verfasst von: Seno Jose
Sabu Thomas
Indose Aravind
J. Karger-Kocsis
Publikationsdatum: 01.12.2014
Verlag: Springer India
Erschienen in: International Journal of Plastics Technology / Ausgabe 2/2014
Print ISSN: 0972-656X
Elektronische ISSN: 0975-072X
DOI: https://doi.org/10.1007/s12588-014-9075-y

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