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Rheologica Acta

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01.02.2004 | Original Contribution

Rheology of transient networks containing hydrophobically modified cellulose, anionic surfactant and colloidal silica: role of selective adsorption

verfasst von: K. Derek Berglund, My T. Truong, Todd M. Przybycien, Robert D. Tilton, Lynn M. Walker

Erschienen in: Rheologica Acta | Ausgabe 1/2004

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Abstract

Rheology and adsorption studies are performed on a model multicomponent system of hydrophobically modified cellulose (hmHEC), anionic surfactant (SDS), and negatively charged silica. Optical reflectometry measurements on silica quantify the total adsorbed mass from polymer-surfactant mixtures and indicate that the adsorption is irreversible. Linear and nonlinear rheological measurements show that the addition of colloidal silica to polymer-surfactant mixtures leads to complex and unexpected changes in behavior that cannot be explained simply as depletion of the bulk solution via adsorption to the colloidal surface. Instead, the combination of rheology and adsorption measurements indicates that the colloidal silica becomes an integral part of the transient network shifting the dynamics of the system.

Vorheriger Artikel Viscoelastic properties of magnetorheological fluids

Nächster Artikel A phenomenological model of electrorheological fluids

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Titel: Rheology of transient networks containing hydrophobically modified cellulose, anionic surfactant and colloidal silica: role of selective adsorption
verfasst von: K. Derek Berglund
My T. Truong
Todd M. Przybycien
Robert D. Tilton
Lynn M. Walker
Publikationsdatum: 01.02.2004
Verlag: Springer-Verlag
Erschienen in: Rheologica Acta / Ausgabe 1/2004
Print ISSN: 0035-4511
Elektronische ISSN: 1435-1528
DOI: https://doi.org/10.1007/s00397-003-0319-6

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