Skip to main content
Erschienen in: Optical and Quantum Electronics 11/2016

01.11.2016

Room-temperature DNA-catalyzed hydrogen fuel cell

verfasst von: Wen-Bing Lai, Jyun-Lin Huang, Chungpin Liao, Li-Shen Yeh

Erschienen in: Optical and Quantum Electronics | Ausgabe 11/2016

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Motivated by previous experiences in identifying active reaction zones on plant pheophytins of the so-called semi-derivative morphology, for the catalytic decomposition of hydrogen gas, this current research aimed for similarly suggestive sites within DNA base pairs which exist in all living matters. Verified by the 1st-principle quantum mechanical simulations and subsequent wet and dry hydrogen fuel cell experiments, the feasibility of room-temperature DNA-catalyzed hydrogen oxidation reaction was unambiguously established. This implies that very low-cost DNA-catalyzed fuel cells, which contain no expensive, CO-sensitive platinum on the negative electrode side, can be put to work under room condition and thus might be practically available in every household in the very near future.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Fußnoten
1
A quantum mechanical simulation code of Accelry’s Material Studio to simulate physical, chemical, and optical properties of molecules and compounds based on the density functional theory (DFT). In it, generalized gradient approximation (GGA) PW91 scheme for exchange correlation, and numerical atomic orbital DND basis set, self-consistent field (SCF) tolerance of 1 × 10−5 eV were employed. During the geometry optimization for minimum Hamiltonian calculations, the approach of Partial Structural Constraint Path Minimization (PSCPM) was adopted.
 
Literatur
Zurück zum Zitat Huang, J.L., Lai, W.B., Liao, C.P., Yeh, L.S.: A suspected derivative morphology for pheophytin and the enhanced hydrogen decomposition it caused. Opt. Quant. Electron. 48, 469 (2016)CrossRef Huang, J.L., Lai, W.B., Liao, C.P., Yeh, L.S.: A suspected derivative morphology for pheophytin and the enhanced hydrogen decomposition it caused. Opt. Quant. Electron. 48, 469 (2016)CrossRef
Zurück zum Zitat Kadish, K.M., Smith, K.M., Guilard, R.: Handbook of Porphyrin Science: With Applications to Chemistry, Physics, Materials Science, Engineering, Biology and Medicine, pp. 1–35. World Scientific Publishing Company, Danvers (2014) Kadish, K.M., Smith, K.M., Guilard, R.: Handbook of Porphyrin Science: With Applications to Chemistry, Physics, Materials Science, Engineering, Biology and Medicine, pp. 1–35. World Scientific Publishing Company, Danvers (2014)
Zurück zum Zitat Nordell, K.J., Jackelen, A.-M.L., Michael Condren, S., Lisensky, G.C., Ellis, A.B.: DNA extraction from animal and plant tissues. J. Chem. Educ. 76, 400A–400B (1999)CrossRef Nordell, K.J., Jackelen, A.-M.L., Michael Condren, S., Lisensky, G.C., Ellis, A.B.: DNA extraction from animal and plant tissues. J. Chem. Educ. 76, 400A–400B (1999)CrossRef
Zurück zum Zitat Rittman, M., Hoffmann, S.V., Gilroy, E., Hicks, M.R., Finkenstadt, B., Rodger, A.: Probing the structure of long DNA molecules in solution using synchrotron radiation linear dichroism. Phys. Chem. Chem. Phys. 14, 353–366 (2012)CrossRef Rittman, M., Hoffmann, S.V., Gilroy, E., Hicks, M.R., Finkenstadt, B., Rodger, A.: Probing the structure of long DNA molecules in solution using synchrotron radiation linear dichroism. Phys. Chem. Chem. Phys. 14, 353–366 (2012)CrossRef
Zurück zum Zitat Wieckowski, A., Norskov, J.: Fuel Cell Science: Theory, Fundamentals, and Biocatalysis, pp. 489–510. Wiley, Hoboken (2010)CrossRef Wieckowski, A., Norskov, J.: Fuel Cell Science: Theory, Fundamentals, and Biocatalysis, pp. 489–510. Wiley, Hoboken (2010)CrossRef
Metadaten
Titel
Room-temperature DNA-catalyzed hydrogen fuel cell
verfasst von
Wen-Bing Lai
Jyun-Lin Huang
Chungpin Liao
Li-Shen Yeh
Publikationsdatum
01.11.2016
Verlag
Springer US
Erschienen in
Optical and Quantum Electronics / Ausgabe 11/2016
Print ISSN: 0306-8919
Elektronische ISSN: 1572-817X
DOI
https://doi.org/10.1007/s11082-016-0749-x

Weitere Artikel der Ausgabe 11/2016

Optical and Quantum Electronics 11/2016 Zur Ausgabe

Neuer Inhalt