Skip to main content
Erschienen in: Journal of Materials Science 7/2019

14.12.2018 | Polymers

Sandwich-type porous polyimide film with improved dielectric, water resistance and mechanical properties

Erschienen in: Journal of Materials Science | Ausgabe 7/2019

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

The simultaneous improvement of dielectric, mechanical and water resistance properties of dielectric materials is extremely important for their practical use, but rarely been realized. Here, the comprehensive properties of polyimide (PI) film were enhanced through the construction of sandwich-type porous film using the microemulsion method. Due to the introduction of porous structure on both sides of PI film, apparent decreases were observed in dielectric constant (16.50%) and water absorption (82.7%), accompanied by increases in tensile strength (5.14%) and tensile modulus (41.17%), compared to flat PI film. Furthermore, excellent durability of low dielectric constant of the sandwich-type porous film under moist environment was demonstrated since 1.76% of increase was found upon exposing to 75% R.H. for 32 h. This provides a novel method to optimize the comprehensive properties of dielectric materials and also displays underlying insight for the development of functional materials in electronic and electric areas.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Grill A, Gates SM, Ryan TE, Nguyen SV, Priyadarshini D (2014) Progress in the development and understanding of advanced low k and ultralow k dielectrics for very large-scale integrated interconnects-state of the art. Appl Phys Rev 1(1):011306. https://doi.org/10.1063/1.4861876 CrossRef Grill A, Gates SM, Ryan TE, Nguyen SV, Priyadarshini D (2014) Progress in the development and understanding of advanced low k and ultralow k dielectrics for very large-scale integrated interconnects-state of the art. Appl Phys Rev 1(1):011306. https://​doi.​org/​10.​1063/​1.​4861876 CrossRef
2.
Zurück zum Zitat Mativenga M, Geng D, Kim B, Jang J (2015) Fully transparent and rollable electronics. ACS Appl Mater Interfaces 7(3):1578–1585CrossRef Mativenga M, Geng D, Kim B, Jang J (2015) Fully transparent and rollable electronics. ACS Appl Mater Interfaces 7(3):1578–1585CrossRef
3.
Zurück zum Zitat Spechler JA, Koh TW, Herb JT, Rand BP, Arnold CB (2015) A transparent, smooth, thermally robust, conductive polyimide for flexible electronics. Adv Funct Mater 25(48):7428–7434CrossRef Spechler JA, Koh TW, Herb JT, Rand BP, Arnold CB (2015) A transparent, smooth, thermally robust, conductive polyimide for flexible electronics. Adv Funct Mater 25(48):7428–7434CrossRef
4.
Zurück zum Zitat Grigoras K, Keskinen J, Grοnberg L, Yli-Rantala E, Laakso S, Valimaki H, Kauranen P, Ahopelto J, Prunnila M (2016) Conformal titanium nitride in a porous silicon matrix: a nanomaterial for in-chip supercapacitors. Nano Energy 26:340–345CrossRef Grigoras K, Keskinen J, Grοnberg L, Yli-Rantala E, Laakso S, Valimaki H, Kauranen P, Ahopelto J, Prunnila M (2016) Conformal titanium nitride in a porous silicon matrix: a nanomaterial for in-chip supercapacitors. Nano Energy 26:340–345CrossRef
5.
Zurück zum Zitat Li L, Zhang JB, Peng ZW, Li YL, Gao CT, Ji YS, Ye RQ, Kim ND, Zhong QF, Yang Y, Fei HL, Ruan JD, Tour JM (2016) High-performance pseudocapacitive microsupercapacitors from laser-induced graphene. Adv Mater 28(5):838–845CrossRef Li L, Zhang JB, Peng ZW, Li YL, Gao CT, Ji YS, Ye RQ, Kim ND, Zhong QF, Yang Y, Fei HL, Ruan JD, Tour JM (2016) High-performance pseudocapacitive microsupercapacitors from laser-induced graphene. Adv Mater 28(5):838–845CrossRef
6.
Zurück zum Zitat Jia MC, Zhou MT, Li YJ, Lu GL, Huang XY (2018) Construction of semi-fluorinated polyimides with perfluorocyclobutyl aryl ether-based side chains. Polym Chem 9(7):920–930CrossRef Jia MC, Zhou MT, Li YJ, Lu GL, Huang XY (2018) Construction of semi-fluorinated polyimides with perfluorocyclobutyl aryl ether-based side chains. Polym Chem 9(7):920–930CrossRef
7.
Zurück zum Zitat Ko YG, Kwon W, Yen HJ, Chang CW, Kim DM, Kim K, Hahm SG, Lee TJ, Liou GS, Ree M (2012) Various digital memory behaviors of functional aromatic polyimides based on electron donor and acceptor substituted triphenylamines. Macromolecules 45(9):3749–3758CrossRef Ko YG, Kwon W, Yen HJ, Chang CW, Kim DM, Kim K, Hahm SG, Lee TJ, Liou GS, Ree M (2012) Various digital memory behaviors of functional aromatic polyimides based on electron donor and acceptor substituted triphenylamines. Macromolecules 45(9):3749–3758CrossRef
8.
Zurück zum Zitat Murotani E, Lee JK, Chatzichristidi M, Zakhidov AA, Taylor PG, Schwartz EL, Malliaras GG, Ober CK (2009) Cross-linkable molecular glasses: low dielectric constant materials patternable in hydrofluoroethers. ACS Appl Mater Interfaces 1(10):2363–2370CrossRef Murotani E, Lee JK, Chatzichristidi M, Zakhidov AA, Taylor PG, Schwartz EL, Malliaras GG, Ober CK (2009) Cross-linkable molecular glasses: low dielectric constant materials patternable in hydrofluoroethers. ACS Appl Mater Interfaces 1(10):2363–2370CrossRef
9.
Zurück zum Zitat Lifson ML, Kim MW, Greer JR, Kim BJ (2017) Enabling simultaneous extreme ultra low-k in stiff, resilient, and thermally stable nano-architected materials. Nano Lett 17(12):7737–7743CrossRef Lifson ML, Kim MW, Greer JR, Kim BJ (2017) Enabling simultaneous extreme ultra low-k in stiff, resilient, and thermally stable nano-architected materials. Nano Lett 17(12):7737–7743CrossRef
10.
Zurück zum Zitat Bei RX, Qian C, Zhang Y, Chi ZG, Liu SW, Chen XD, Xu JR, Aldred MP (2017) Intrinsic low dielectric constant polyimides: relationship between molecular structure and dielectric properties. J Mater Chem C 5(48):12807–12815CrossRef Bei RX, Qian C, Zhang Y, Chi ZG, Liu SW, Chen XD, Xu JR, Aldred MP (2017) Intrinsic low dielectric constant polyimides: relationship between molecular structure and dielectric properties. J Mater Chem C 5(48):12807–12815CrossRef
11.
Zurück zum Zitat Volksen W, Miller RD, Dubois G (2010) Low dielectric constant materials. Chem Rev 110(1):56–110CrossRef Volksen W, Miller RD, Dubois G (2010) Low dielectric constant materials. Chem Rev 110(1):56–110CrossRef
12.
Zurück zum Zitat Ishizaka T, Ishigaki A, Chatterjee M, Suzuki A, Suzuki TM, Kawanami H (2010) Continuous process for fabrication of size controlled polyimide nanoparticles using microfluidic system. Chem Commun 46(38):7214–7216CrossRef Ishizaka T, Ishigaki A, Chatterjee M, Suzuki A, Suzuki TM, Kawanami H (2010) Continuous process for fabrication of size controlled polyimide nanoparticles using microfluidic system. Chem Commun 46(38):7214–7216CrossRef
13.
Zurück zum Zitat Yuan C, Jin KK, Li K, Diao S, Tong JW, Fang Q (2013) Non-porous low-k dielectric films based on a new structural amorphous fluoropolymer. Adv Mater 25(35):4875–4878CrossRef Yuan C, Jin KK, Li K, Diao S, Tong JW, Fang Q (2013) Non-porous low-k dielectric films based on a new structural amorphous fluoropolymer. Adv Mater 25(35):4875–4878CrossRef
14.
Zurück zum Zitat Lim J, Yeo H, Goh M, Ku BC, Kim SG, Lee HS, Park B, You NH (2015) Grafting of polyimide onto chemically-functionalized graphene nanosheets for mechanically-strong barrier membranes. Chem Mater 27(6):2040–2047CrossRef Lim J, Yeo H, Goh M, Ku BC, Kim SG, Lee HS, Park B, You NH (2015) Grafting of polyimide onto chemically-functionalized graphene nanosheets for mechanically-strong barrier membranes. Chem Mater 27(6):2040–2047CrossRef
15.
Zurück zum Zitat Ghanem BS, Swaidan R, Litwiller E, Pinnau I (2014) Ultra-microporous triptycene-based polyimide membranes for high-performance gas separation. Adv Mater 26(22):3688–3692CrossRef Ghanem BS, Swaidan R, Litwiller E, Pinnau I (2014) Ultra-microporous triptycene-based polyimide membranes for high-performance gas separation. Adv Mater 26(22):3688–3692CrossRef
16.
Zurück zum Zitat Qian ZC, Wang Z, Chen Y, Tong SR, Ge MF, Zhao N, Xu J (2018) Superelastic and ultralight polyimide aerogels as thermal insulators and particulate air filters. J Mater Chem A 6(3):828–832CrossRef Qian ZC, Wang Z, Chen Y, Tong SR, Ge MF, Zhao N, Xu J (2018) Superelastic and ultralight polyimide aerogels as thermal insulators and particulate air filters. J Mater Chem A 6(3):828–832CrossRef
18.
Zurück zum Zitat Jia MC, Li YJ, He CQ, Huang XY (2016) Soluble perfluorocyclobutyl aryl ether-based polyimide for high-performance dielectric material. ACS Appl Mater Interfaces 8(39):26352–26358CrossRef Jia MC, Li YJ, He CQ, Huang XY (2016) Soluble perfluorocyclobutyl aryl ether-based polyimide for high-performance dielectric material. ACS Appl Mater Interfaces 8(39):26352–26358CrossRef
19.
Zurück zum Zitat Liaw DJ, Wang KL, Huang YC, Lee KR, Lai JY, Ha CS (2012) Advanced polyimide materials: syntheses, physical properties and applications. Prog Polym Sci 37(7):907–974CrossRef Liaw DJ, Wang KL, Huang YC, Lee KR, Lai JY, Ha CS (2012) Advanced polyimide materials: syntheses, physical properties and applications. Prog Polym Sci 37(7):907–974CrossRef
20.
Zurück zum Zitat Liu YW, Qian C, Qu LJ, Wu YN, Zhang Y, Wu XH, Zou B, Chen WX, Chen ZQ, Chi ZG, Liu SW, Chen XD, Xu JR (2015) A bulk dielectric polymer film with intrinsic ultralow dielectric constant and outstanding comprehensive properties. Chem Mater 27(19):6543–6549CrossRef Liu YW, Qian C, Qu LJ, Wu YN, Zhang Y, Wu XH, Zou B, Chen WX, Chen ZQ, Chi ZG, Liu SW, Chen XD, Xu JR (2015) A bulk dielectric polymer film with intrinsic ultralow dielectric constant and outstanding comprehensive properties. Chem Mater 27(19):6543–6549CrossRef
21.
Zurück zum Zitat Wang X, Dai YY, Wang WM, Ren MM, Li BY, Fan C, Liu XY (2014) Fluorographene with high fluorine/carbon ratio: a nano-filler for preparing low-κ polyimide hybrid films. ACS Appl Mater Interfaces 6(18):16182–16188CrossRef Wang X, Dai YY, Wang WM, Ren MM, Li BY, Fan C, Liu XY (2014) Fluorographene with high fluorine/carbon ratio: a nano-filler for preparing low-κ polyimide hybrid films. ACS Appl Mater Interfaces 6(18):16182–16188CrossRef
23.
Zurück zum Zitat Liao WH, Yang SY, Hsiao ST, Wang YS, Li SM, Ma CCM, Tien HW, Zeng SJ (2014) Effect of octa(aminophenyl) polyhedral oligomeric silsesquioxane functionalized graphene oxide on the mechanical and dielectric properties polyimide composites. ACS Appl Mater Interfaces 6(18):15802–15812CrossRef Liao WH, Yang SY, Hsiao ST, Wang YS, Li SM, Ma CCM, Tien HW, Zeng SJ (2014) Effect of octa(aminophenyl) polyhedral oligomeric silsesquioxane functionalized graphene oxide on the mechanical and dielectric properties polyimide composites. ACS Appl Mater Interfaces 6(18):15802–15812CrossRef
24.
Zurück zum Zitat Li Y, Zhao JQ, Yuan YC, Shi CQ, Liu SM, Yan SJ, Zhao Y, Zhang MQ (2015) Polyimide/crown ether composite films with necklace-like supramolecular structure and improved mechanical, dielectric, and hydrophobic properties. Macromolecules 48(7):2173–2183CrossRef Li Y, Zhao JQ, Yuan YC, Shi CQ, Liu SM, Yan SJ, Zhao Y, Zhang MQ (2015) Polyimide/crown ether composite films with necklace-like supramolecular structure and improved mechanical, dielectric, and hydrophobic properties. Macromolecules 48(7):2173–2183CrossRef
25.
Zurück zum Zitat Kawagishi K, Saito H, Furukawa H, Horie K (2007) Superior nanoporous polyimides via supercritical CO2 drying of jungle-gym-type polyimide gels. Macromol Rapid Commun 28(1):96–100CrossRef Kawagishi K, Saito H, Furukawa H, Horie K (2007) Superior nanoporous polyimides via supercritical CO2 drying of jungle-gym-type polyimide gels. Macromol Rapid Commun 28(1):96–100CrossRef
26.
Zurück zum Zitat Taki K, Hosokawa K, Takagi S, Mabuchi H, Ohshima M (2013) Rapid production of ultralow dielectric constant porous polyimide films via CO2-tert-amine zwitterion-induced phase separation and subsequent photopolymerization. Macromolecules 46(6):2275–2281CrossRef Taki K, Hosokawa K, Takagi S, Mabuchi H, Ohshima M (2013) Rapid production of ultralow dielectric constant porous polyimide films via CO2-tert-amine zwitterion-induced phase separation and subsequent photopolymerization. Macromolecules 46(6):2275–2281CrossRef
27.
Zurück zum Zitat Yang SY, Jeon G, Kim JK (2012) A high density array of free standing alumina nanotubes aligned vertically on solid substrates in a large area. J Mater Chem 22(43):23017–23021CrossRef Yang SY, Jeon G, Kim JK (2012) A high density array of free standing alumina nanotubes aligned vertically on solid substrates in a large area. J Mater Chem 22(43):23017–23021CrossRef
28.
Zurück zum Zitat Zhang YM, Ionov L (2014) Actuating porous polyimide films. ACS Appl Mater Interfaces 6(13):10072–10077CrossRef Zhang YM, Ionov L (2014) Actuating porous polyimide films. ACS Appl Mater Interfaces 6(13):10072–10077CrossRef
29.
Zurück zum Zitat Zhang H, Lin CE, Zhou MY, John AE, Zhu BK (2016) High thermal resistance polyimide separators prepared via soluble precusor and non-solvent induced phase separation process for lithium ion batteries. Electrochim Acta 187:125–133CrossRef Zhang H, Lin CE, Zhou MY, John AE, Zhu BK (2016) High thermal resistance polyimide separators prepared via soluble precusor and non-solvent induced phase separation process for lithium ion batteries. Electrochim Acta 187:125–133CrossRef
30.
Zurück zum Zitat Chen Y, Shao GF, Kong Y, Shen XD, Cui S (2017) Facile preparation of cross-linked polyimide aerogels with carboxylic functionalization for CO2 capture. Chem Eng J 322:1–9CrossRef Chen Y, Shao GF, Kong Y, Shen XD, Cui S (2017) Facile preparation of cross-linked polyimide aerogels with carboxylic functionalization for CO2 capture. Chem Eng J 322:1–9CrossRef
31.
Zurück zum Zitat Chen YW, Wang W, Yu WH, Yuan ZL, Kang ET, Neoh KG, Krauter B, Greiner A (2004) Nanoporous low-kappa polyimide films via poly(amic acid)s with grafted poly(ethylene glycol) side chains from a reversible addition-fragmentation chain-transfer-mediated process. Adv Funct Mater 14(5):471–478CrossRef Chen YW, Wang W, Yu WH, Yuan ZL, Kang ET, Neoh KG, Krauter B, Greiner A (2004) Nanoporous low-kappa polyimide films via poly(amic acid)s with grafted poly(ethylene glycol) side chains from a reversible addition-fragmentation chain-transfer-mediated process. Adv Funct Mater 14(5):471–478CrossRef
32.
Zurück zum Zitat Chen ZG, Liu SM, Yan SJ, Shu X, Yuan YC, Huang HH, Zhao JQ (2017) Overall improvement in dielectric and mechanical properties of porous graphene fluoroxide/polyimide nanocomposite films via bubble-stretching approach. Mater Des 117:150–156CrossRef Chen ZG, Liu SM, Yan SJ, Shu X, Yuan YC, Huang HH, Zhao JQ (2017) Overall improvement in dielectric and mechanical properties of porous graphene fluoroxide/polyimide nanocomposite films via bubble-stretching approach. Mater Des 117:150–156CrossRef
33.
Zurück zum Zitat Meador MAB, McMillon E, Sandberg A, Barrios E, Wilmoth NG, Mueller CH, Miranda FA (2014) Dielectric and other properties of polyimide aerogels containing fluorinated blocks. ACS Appl Mater Interfaces 6(9):6062–6068CrossRef Meador MAB, McMillon E, Sandberg A, Barrios E, Wilmoth NG, Mueller CH, Miranda FA (2014) Dielectric and other properties of polyimide aerogels containing fluorinated blocks. ACS Appl Mater Interfaces 6(9):6062–6068CrossRef
34.
Zurück zum Zitat Ma YY, Zhou MC, Walter S, Liang J, Chen ZJ, Wu LX (2014) Selective adhesion and controlled activity of yeast cells on honeycomb-patterned polymer films via a microemulsion approach. Chem Commun 50(100):15882–15885CrossRef Ma YY, Zhou MC, Walter S, Liang J, Chen ZJ, Wu LX (2014) Selective adhesion and controlled activity of yeast cells on honeycomb-patterned polymer films via a microemulsion approach. Chem Commun 50(100):15882–15885CrossRef
35.
Zurück zum Zitat Liang J, Ma YY, Sims S, Wu LX (2015) A patterned porous polymer film for localized capture of insulin and glucose-responsive release. J Mater Chem B 3(7):1281–1288CrossRef Liang J, Ma YY, Sims S, Wu LX (2015) A patterned porous polymer film for localized capture of insulin and glucose-responsive release. J Mater Chem B 3(7):1281–1288CrossRef
36.
Zurück zum Zitat Kreuz JA (1995) Polyimidizations from acylated diamines and dianhydrides. Polymer 36(10):2089–2094CrossRef Kreuz JA (1995) Polyimidizations from acylated diamines and dianhydrides. Polymer 36(10):2089–2094CrossRef
37.
Zurück zum Zitat Sasaki S, Matsuura T, Nishi S, Ando S (1991) Property control of new fluorinated copolyimides and their applications. Mat Res Soc Symp Proc 227:49–54CrossRef Sasaki S, Matsuura T, Nishi S, Ando S (1991) Property control of new fluorinated copolyimides and their applications. Mat Res Soc Symp Proc 227:49–54CrossRef
Metadaten
Titel
Sandwich-type porous polyimide film with improved dielectric, water resistance and mechanical properties
Publikationsdatum
14.12.2018
Erschienen in
Journal of Materials Science / Ausgabe 7/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-03248-z

Weitere Artikel der Ausgabe 7/2019

Journal of Materials Science 7/2019 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.