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18.11.2021 | Original Research

Scalable synthesis of γ-Fe₂O₃–based composite films as freestanding negative electrodes with ultra-high areal capacitances for high-performance asymmetric supercapacitors

verfasst von: Jincy Parayangattil Jyothibasu, Ruei-Hong Wang, Kenneth Ong, Juping Hillary Lin Ong, Rong-Ho Lee

Erschienen in: Cellulose | Ausgabe 1/2022

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Abstract

This paper reports a simple, cost-effective, and environmentally friendly procedure for the synthesis of cellulose/functionalized carbon nanotube (f-CNT)/Fe₂O₃ (CCF) composite films and their performance as freestanding negative electrodes in supercapacitors. A facile chemical precipitation process was performed at room temperature within a short reaction time without requiring any of the special processing conditions used in the conventional hydrothermal synthesis, making it the most cost-efficient method for the bulk-scale production of sustainable supercapacitors. The binder-free negative electrode with ultra-high active material loading exhibited outstanding areal (9107.1 mF cm^–2) and volumetric (314 F cm^–3) capacitances, which were much greater than the values reported previously in the literature for negative electrodes. Moreover, an asymmetric supercapacitor cell featuring cellulose/f-CNT/MnO₂ (CCM) and CCF as its positive and negative electrodes, respectively, achieved superior electrochemical performances. Therefore, on account of the economic and environmental superiority of this method and its bulk scalability, this paper provides a simple, eco-friendly, and cost-effective approach for the development of sustainable supercapacitors for practical use.

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Vorheriger Artikel Selective catalytic transformation of cellulose into bio-based cresol with CuCr2O4@MCM-41 catalyst

Nächster Artikel A self-healing water-dissolvable and stretchable cellulose-hydrogel for strain sensor

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Augustyn V, Simon P, Dunn B (2014) Pseudocapacitive oxide materials for high-rate electrochemical energy storage Energy. Environ Sci 7:1597–1614. https://doi.org/10.1039/C3EE44164DCrossRef

Azhar A et al (2019) Nanoarchitectonics: a new materials horizon for prussian blue and its analogues. Bull Chem Soc Jpn 92:875–904. https://doi.org/10.1246/bcsj.20180368

Barzegar F, Momodu DY, Fashedemi OO, Bello A, Dangbegnon JK, Manyala N (2015) Investigation of different aqueous electrolytes on the electrochemical performance of activated carbon-based supercapacitors. RSC Adv 5:107482–107487. https://doi.org/10.1039/C5RA21962KCrossRef

Bing L et al (2019) Synthesis of FeP nanotube arrays as negative electrode for solid-state asymmetric supercapacitor. Nanotechnology 30:295401CrossRef

Chang J et al (2013) Asymmetric supercapacitors based on graphene/MnO₂ nanospheres and graphene/MoO₃ nanosheets with high energy density. Adv Funct Mater 23:5074–5083. https://doi.org/10.1002/adfm201301851

Chen Z et al (2009) Design and synthesis of hierarchical nanowire composites for electrochemical energy storage. Adv Funct Mater 19:3420–3426. https://doi.org/10.1002/adfm.200900971CrossRef

Chen PC, Shen G, Shi Y, Chen H, Zhou C (2010) Preparation and characterization of flexible asymmetric supercapacitors based on transition-metal-oxide nanowire/single-walled carbon nanotube hybrid thin-film electrodes. ACS Nano 4:4403–4411. https://doi.org/10.1021/nn100856yCrossRefPubMed

Chen D, Zhou S, Quan H, Zou R, Gao W, Luo X, Guo L (2018) Tetsubo-like α-Fe₂O₃/C nanoarrays on carbon cloth as negative electrode for high-performance asymmetric supercapacitors. Chem Eng J 341:102–111. https://doi.org/10.1016/j.cej.2018.02.021

Choi H, Yoon H (2015) Nanostructured electrode materials for electrochemical capacitor applications. Nanomaterials (Basel) 5:906–936. https://doi.org/10.3390/nano5020906CrossRef

Choudhary N, Li C, Moore J, Nagaiah N, Zhai L, Jung Y, Thomas J (2017) Asymmetric supercapacitor electrodes and devices. Adv Mater 29:1605336. https://doi.org/10.1002/adma.201605336CrossRef

Dong Y, Xing L, Hu F, Umar A, Wu X (2018) α-Fe₂O₃/rGO nanospindles as electrode materials for supercapacitors with long cycle life. Mater Res Bull 107:391–396. https://doi.org/10.1016/j.materresbull.2018.07.038

Feng JX, Ye SH, Lu XF, Tong YX, Li GR (2015) Asymmetric paper supercapacitor based on amorphous porous Mn₃O₄ negative electrode and Ni(OH)₂ positive electrode: a novel and high-performance flexible electrochemical energy storage device. ACS Appl Mater Interfaces 7:11444–11451. https://doi.org/10.1021/acsami.5b02157

French AD (2014) Idealized powder diffraction patterns for cellulose polymorphs. Cellulose 21:885–896. https://doi.org/10.1007/s10570-013-0030-4CrossRef

Guan C et al (2015) Iron oxide-decorated carbon for supercapacitor anodes with ultrahigh energy density and outstanding cycling stability. ACS Nano 9:5198–5207. https://doi.org/10.1021/acsnano.5b00582CrossRefPubMed

Guo W, Yu C, Li S, Qiu J (2021) Toward commercial-level mass-loading electrodes for supercapacitors: opportunities, challenges and perspectives. Energy Environ Sci 14:576–601. https://doi.org/10.1039/D0EE02649B

Gür TM (2018) Review of electrical energy storage technologies, materials and systems: challenges and prospects for large-scale grid storage. Energy Environ Sci 11:2696–2767. https://doi.org/10.1039/C8EE01419A

Hu Y, Guan C, Ke Q, Yow ZF, Cheng C, Wang J (2016) Hybrid Fe₂O₃ nanoparticle clusters/rGO paper as an effective negative electrode for flexible supercapacitors. Chem Mater 28:7296–7303. https://doi.org/10.1021/acs.chemmater.6b02585

Hui BH, Salimi MN (2020) Production of iron oxide nanoparticles by co-precipitation method with optimization studies of processing temperature, pH and stirring rate. IOP Conf Ser Mater Sci Eng 743:012036. https://doi.org/10.1088/1757-899x/743/1/012036

Jeong JM et al (2021) Alternative-ultrathin assembling of exfoliated manganese dioxide and nitrogen-doped carbon layers for high-mass-loading supercapacitors with outstanding capacitance and impressive rate capability. Adv Funct Mater 31:2009632. https://doi.org/10.1002/adfm.202009632CrossRef

Jiang K, Sun B, Yao M, Wang N, Hu W, Komarneni S (2018) In situ hydrothermal preparation of mesoporous Fe₃O₄ film for high-performance negative electrodes of supercapacitors. Micropor Mesopor Mater 265:189–194. https://doi.org/10.1016/j.micromeso.2018.02.015

Jincy PJ, Anita Das R, Sarma US (2015) Ecofriendly organosolv process for pulping of tender coconut fibre. Cord 31:11. https://doi.org/10.37833/cord.v31i1.64

Jyothibasu JP et al (2021a) V₂O₅/carbon nanotube/polypyrrole based freestanding negative electrodes for high-performance supercapacitors. Catalysts 11:980

Jyothibasu JP, Lee RH (2018) Facile, scalable, eco-friendly fabrication of high-performance flexible all-solid-state supercapacitors. Polymers 10:1247

Jyothibasu JP, Lee RH (2020) Green synthesis of polypyrrole tubes using curcumin template for excellent electrochemical performance in supercapacitors. J Mater Chem A 8:3186–3202. https://doi.org/10.1039/C9TA11934ECrossRef

Jyothibasu JP, Kuo DW, Lee RH (2019) Flexible and freestanding electrodes based on polypyrrole/carbon nanotube/cellulose composites for supercapacitor application. Cellulose 26:4495–4513. https://doi.org/10.1007/s10570-019-02376-2CrossRef

Jyothibasu JP, Wang R-H, Ong K, Ong JHL, Lee RH (2021b) Cellulose/carbon nanotube/MnO₂ composite electrodes with high mass loadings for symmetric supercapacitors. Cellulose 28:3549-3567. https://doi.org/10.1007/s10570-021-03757-2CrossRef

Kalantari K, Bin Ahmad M, Shameli K, Khandanlou R (2013) Synthesis of talc/Fe₃O₄ magnetic nanocomposites using chemical co-precipitation method. Int J Nanomedicine 8:1817–1823. https://doi.org/10.2147/IJN.S43693

Keppeler M, Shen N, Nageswaran S, Srinivasan M (2016) Synthesis of α-Fe₂O₃/carbon nanocomposites as high capacity electrodes for next generation lithium ion batteries: a review. J Mater Chem A 4:18223–18239. https://doi.org/10.1039/C6TA08456G

Lee KK et al. (2012) α-Fe2O3 nanotubes-reduced graphene oxide composites as synergistic electrochemical capacitor materials. Nanoscale 4:2958–2961. https://doi.org/10.1039/C2NR11902A

Li Z et al (2014) Colossal pseudocapacitance in a high functionality—high surface area carbon anode doubles the energy of an asymmetric supercapacitor. Energy Environ Sci 7:1708–1718. https://doi.org/10.1039/C3EE43979H

Li C et al. (2018) Fabricating an aqueous symmetric supercapacitor with a stable high working voltage of 2 V by using an alkaline-acidic electrolyte. Adv Sci (Weinh) 6:1801665–1801665. https://doi.org/10.1002/advs.201801665

Li J et al. (2019) Porous Fe₂O₃ nanospheres anchored on activated carbon cloth for high-performance symmetric supercapacitors. Nano Energy 57:379–387. https://doi.org/10.1016/j.nanoen.2018.12.061

Li Y et al (2020) Fabrication of flexible microsupercapacitors with binder-free ZIF-8 derived carbon films via electrophoretic deposition. Bull Chem Soc Jpn 93:176–181. https://doi.org/10.1246/bcsj.20190298

Li GR, Wang ZL, Zheng FL, Ou YN, Tong YX (2011) ZnO@MoO₃ core/shell nanocables: facile electrochemical synthesis and enhanced supercapacitor performances. J Mater Chem 21:4217–4221. https://doi.org/10.1039/C0JM03500A

Lindman B, Medronho B, Alves L, Costa C, Edlund H, Norgren M (2017) The relevance of structural features of cellulose and its interactions to dissolution, regeneration, gelation and plasticization phenomena. Phys Chem Chem Phys 19:23704–23718 https://doi.org/10.1039/C7CP02409F

Liu T et al. (2015) Investigation of hematite nanorod–nanoflake morphological transformation and the application of ultrathin nanoflakes for electrochemical devices. Nano Energy 12:169–177. https://doi.org/10.1016/j.nanoen.2014.12.023

Liu S, Yao K, Fu LH, Ma MG (2016) Selective synthesis of Fe₃O₄, γ-Fe₂O₃, and α-Fe₂O₃ using cellulose-based composites as precursors. RSC Adv 6:2135–2140 https://doi.org/10.1039/C5RA22985E

Liu Z et al (2019) Three-dimensional ordered porous electrode materials for electrochemical energy storage. NPG Asia Mater 11:12. https://doi.org/10.1038/s41427-019-0112-3CrossRef

Lu X et al (2013) H-TiO2@MnO2//H-TiO2@C core–shell nanowires for high performance and flexible asymmetric supercapacitors. Adv Mater 25:267–272. https://doi.org/10.1002/adma.201203410

Lu X et al (2014) Oxygen-deficient hematite nanorods as high-performance and novel negative electrodes for flexible asymmetric supercapacitors. Adv Mater 26:3148–3155. https://doi.org/10.1002/adma.201305851CrossRefPubMed

Lu XF, Chen XY, Zhou W, Tong YX, Li GR (2015) α-Fe₂O₃@PANI Core–shell nanowire arrays as negative electrodes for asymmetric supercapacitors. ACS Appl Mater Interfaces 7:14843–14850. https://doi.org/10.1021/acsami.5b03126

Lv H, Zhao H, Cao T, Qian L, Wang Y, Zhao G (2015) Efficient degradation of high concentration azo-dye wastewater by heterogeneous fenton process with iron-based metal-organic framework. J Mol Catal A Chem 400:81–89. https://doi.org/10.1016/j.molcata.2015.02.007CrossRef

Ma J, Guo X, Yan Y, Xue H, Pang H (2018) FeOx-based materials for electrochemical energy storage. Adv Sci (weinh) 5:1700986. https://doi.org/10.1002/advs.201700986CrossRefPubMedCentral

Mahmood Q, Yun HJ, Kim WS, Park HS (2013) Highly uniform deposition of MoO₃ nanodots on multiwalled carbon nanotubes for improved performance of supercapacitors. J Power Sources 235:187–192. https://doi.org/10.1016/j.jpowsour.2013.01.165

Ng KC, Zhang S, Peng C, Chen GZ (2009) Individual and bipolarly stacked asymmetrical aqueous supercapacitors of CNTs/SnO₂ and CNTs/MnO₂ nanocomposites. J Electrochem Soc 156:A846–A853 https://doi.org/10.1149/1.3205482

Nomura S, Kugo Y, Erata T (2020) 13C NMR and XRD studies on the enhancement of cellulose II crystallinity with low concentration NaOH post-treatments. Cellulose 27:3553–3563 https://doi.org/10.1007/s10570-020-03036-6

Parveen N, Cho MH (2016) Self-assembled 3D flower-like nickel hydroxide nanostructures and their supercapacitor. Appl Sci Rep 6:27318. https://doi.org/10.1038/srep27318

Quan H, Cheng B, Xiao Y, Lei S (2016) One-pot synthesis of α-Fe₂O₃ nanoplates-reduced graphene oxide composites for supercapacitor application. Chem Eng J 286:165–173. https://doi.org/10.1016/j.cej.2015.10.068

Samuel E, Kim TG, Park CW, Joshi B, Swihart MT, Yoon SS (2019) Supersonically sprayed Zn₂SnO₄/SnO₂/CNT nanocomposites for high-performance supercapacitor electrodes. ACS Sustain Chem Eng 7:14031–14040 https://doi.org/10.1021/acssuschemeng.9b02549CrossRef

Su H, Ye Z, Hmidi N, Subramanian R (2017) Carbon nanosphere–iron oxide nanocomposites as high-capacity adsorbents for arsenic removal. RSC Adv 7:36138–36148 https://doi.org/10.1039/C7RA06187K

Tang J et al (2016) Bimetallic metal-organic frameworks for controlled catalytic graphitization of nanoporous carbons. Sci Rep 6:30295. https://doi.org/10.1038/srep30295CrossRefPubMedPubMedCentral

Upadhyay KK, Nguyen T, Silva TM, Carmezim MJ, Montemor MF (2017) Electrodeposited MoOx films as negative electrode materials for redox supercapacitors. Electrochim Acta 225:19–28. https://doi.org/10.1016/j.electacta.2016.12.106CrossRef

Wang L et al. (2016) Three-dimensional macroporous carbon/Fe₃O₄-doped porous carbon nanorods for high-performance supercapacitor. ACS Sustain Chem Eng 4:1531–1537. https://doi.org/10.1021/acssuschemeng.5b01474

Wang H, Xu Z, Yi H, Wei H, Guo Z, Wang X (2014) One-step preparation of single-crystalline Fe₂O₃ particles/graphene composite hydrogels as high performance anode materials for supercapacitors. Nano Energy 7:86–96. https://doi.org/10.1016/j.nanoen.2014.04.009CrossRef

Wu TH, Liang WY (2021) Reduced intercalation energy barrier by rich structural water in spinel ZnMn₂O₄ for high-rate zinc-ion batteries. ACS Appl Mater Interfaces 13:23822–23832. https://doi.org/10.1021/acsami.1c05150CrossRefPubMed

Wu MS, Lee RH, Jow JJ, Yang WD, Hsieh CY, Weng BJ (2009) Nanostructured iron oxide films prepared by electrochemical method for electrochemical capacitors. Electrochem Solid-State Lett 12:A1–A4. https://doi.org/10.1149/1.2998547CrossRef

Wu TH, Hsu CT, Hu CC, Hardwick LJ (2013) Important parameters affecting the cell voltage of aqueous electrical double-layer capacitors. J Power Sources 242:289–298. https://doi.org/10.1016/j.jpowsour.2013.05.080CrossRef

Wu Z, Li L, Yan JM, Zhang XB (2017) Materials design and system construction for conventional and new-concept supercapacitors. Adv Sci (weinh) 4:1600382–1600382. https://doi.org/10.1002/advs.201600382CrossRef

Wu X, Huang B, Wang Q, Wang Y (2019) Wide potential and high energy density for an asymmetric aqueous supercapacitor. J Mater Chem A 7:19017–19025. https://doi.org/10.1039/C9TA06428ACrossRef

Wu TH, Scivetti I, Chen JC, Wang JA, Teobaldi G, Hu CC, Hardwick LJ (2020) Quantitative resolution of complex stoichiometric changes during electrochemical cycling by density functional theory-assisted electrochemical quartz crystal microbalance. ACS Appl Energy Mater 3:3347–3357. https://doi.org/10.1021/acsaem.9b02386CrossRef

Wulan Septiani NL et al (2020) Self-assembly of nickel phosphate-based nanotubes into two-dimensional crumpled sheet-like architectures for high-performance asymmetric supercapacitors. Nano Energy 67:104270. https://doi.org/10.1016/j.nanoen.2019.104270CrossRef

Xu X et al (2017) Three-dimensional networked metal–organic frameworks with conductive polypyrrole tubes for flexible supercapacitors. ACS Appl Mater Interfaces 9:38737–38744. https://doi.org/10.1021/acsami.7b09944CrossRefPubMed

Yang P et al (2014) Low-cost high-performance solid-state asymmetric supercapacitors based on MnO₂ nanowires and Fe₂O₃ nanotubes. Nano Lett 14:731–736. https://doi.org/10.1021/nl404008eCrossRefPubMed

Yang Z, Qiu A, Ma J, Chen M (2018) Conducting α-Fe₂O₃ nanorod/polyaniline/CNT gel framework for high performance anodes towards supercapacitors. Compos Sci Technol 156:231–237. https://doi.org/10.1016/j.compscitech.2018.01.012CrossRef

Yu X, Tong S, Ge M, Zuo J, Cao C, Song W (2013) One-step synthesis of magnetic composites of cellulose@iron oxide nanoparticles for arsenic removal. J Mater Chem A 1:959–965. https://doi.org/10.1039/C2TA00315ECrossRef

Yu M et al (2015) Holey tungsten oxynitride nanowires: novel anodes efficiently integrate microbial chemical energy conversion and electrochemical energy storage. Adv Mater 27:3085–3091. https://doi.org/10.1002/adma.201500493CrossRefPubMed

Yu M, Wang Z, Han Y, Tong Y, Lu X, Yang S (2016) Recent progress in the development of anodes for asymmetric supercapacitors. J Mater Chem A 4:4634–4658. https://doi.org/10.1039/C5TA10542KCrossRef

Yu N, Guo K, Zhang W, Wang X, Zhu M-Q (2017) Flexible high-energy asymmetric supercapacitors based on MnO@C composite nanosheet electrodes. J Mater Chem A 5:804–813 https://doi.org/10.1039/C6TA08330G

Zhang T et al. (2016a) Design and preparation of MoO₂/MoS₂ as negative electrode materials for supercapacitors. Mater Des 112:88–96. https://doi.org/10.1016/j.matdes.2016.09.054

Zhang W et al. (2016b) Fe₂O₃-decorated millimeter-long vertically aligned carbon nanotube arrays as advanced anode materials for asymmetric supercapacitors with high energy and power densities. J Mater Chem A 4:19026–19036. https://doi.org/10.1039/C6TA07720J

Zhang F, Zhang T, Yang X, Zhang L, Leng K, Huang Y, Chen Y (2013) A high-performance supercapacitor-battery hybrid energy storage device based on graphene-enhanced electrode materials with ultrahigh energy density. Energy Environ Sci 6:1623–1632. https://doi.org/10.1039/C3EE40509ECrossRef

Zhao ZY et al. (2018) A novel capacitive negative electrode material of Fe₃N. Nano 13:1850002. https://doi.org/10.1142/s1793292018500029

Zheng X et al. (2016) Temperature-dependent electrochemical capacitive performance of the α-Fe₂O₃ hollow nanoshuttles as supercapacitor electrodes. J Colloid Interface Sci 466:291–296. https://doi.org/10.1016/j.jcis.2015.12.024CrossRefPubMed

Zhong C, Deng Y, Hu W, Qiao J, Zhang L, Zhang J (2015) A review of electrolyte materials and compositions for electrochemical supercapacitors. Chem Soc Rev 44:7484–7539. https://doi.org/10.1039/C5CS00303BCrossRefPubMed

Zhu S et al. (2019) Hydrothermal synthesis of graphene-encapsulated 2D circular nanoplates of α-Fe₂O₃ towards enhanced electrochemical performance for supercapacitor. J Alloys Compd 775:63–71. https://doi.org/10.1016/j.jallcom.2018.10.085CrossRef

Zhu M, Wang Y, Meng D, Qin X, Diao G (2012) Hydrothermal synthesis of hematite nanoparticles and their electrochemical properties. J Phys Chem C 116:16276–16285. https://doi.org/10.1021/jp304041mCrossRef

Titel: Scalable synthesis of γ-Fe2O3–based composite films as freestanding negative electrodes with ultra-high areal capacitances for high-performance asymmetric supercapacitors
verfasst von: Jincy Parayangattil Jyothibasu
Ruei-Hong Wang
Kenneth Ong
Juping Hillary Lin Ong
Rong-Ho Lee
Publikationsdatum: 18.11.2021
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 1/2022
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-021-04298-4

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