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Biomass Conversion and Biorefinery
Erschienen in: Biomass Conversion and Biorefinery 3/2019

01.07.2019 | Original Article

Selective deoxygenation of waste chicken fat over sulfided and reduced Co-Mo-La/γAl2O3 as catalysts for the sustainable production of renewable fuel

verfasst von: Samia A. Hanafi, Mamdouh S. Elmelawy, Ghada Eshaq, Ahmed E. ElMetwally

Erschienen in: Biomass Conversion and Biorefinery | Ausgabe 3/2019

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Abstract

Sulfided and reduced Co-Mo-La/γAl2O3 were prepared and examined as catalysts in the selective deoxygenation of waste chicken fat (WCF) to produce gas oil–like hydrocarbons. The effect of reaction conditions was investigated in terms of reaction temperature, reaction pressure, and liquid hourly space velocity (LHSV). The results revealed that the hydrodeoxygenation reaction is favored over the sulfided Co-Mo-La/γAl2O3, while the decarbonylation and decarboxylation reactions are favored over the reduced Co-Mo-La/γAl2O3. It was found that the use of lower LHSV and higher pressure suppresses the decarbonylation and decarboxylation reactions, and consequently the generation of CO and CO2 is minimized. The results also showed that the reduced Co-Mo-La/γAl2O3 catalyst consumes higher amounts of hydrogen, which can be attributed to the methanation reaction, and thus, the composition of the product is heavily dependent on the initial H2 pressure, temperature, and LHSV as well.
Vorheriger Artikel Catalytic conversion of a lignin model compound to value-added products using Cu/TEMPO-catalyzed aerobic oxidation
Nächster Artikel Maximization of fermentable sugar production from sweet sorghum bagasse (dry and wet bases) using response surface methodology (RSM)

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Metadaten
Titel
Selective deoxygenation of waste chicken fat over sulfided and reduced Co-Mo-La/γAl2O3 as catalysts for the sustainable production of renewable fuel
verfasst von
Samia A. Hanafi
Mamdouh S. Elmelawy
Ghada Eshaq
Ahmed E. ElMetwally
Publikationsdatum
01.07.2019
Verlag
Springer Berlin Heidelberg
Erschienen in
Biomass Conversion and Biorefinery / Ausgabe 3/2019
Print ISSN: 2190-6815
Elektronische ISSN: 2190-6823
DOI
https://doi.org/10.1007/s13399-019-00467-5

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