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Polymer Bulletin

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06.10.2023 | ORIGINAL PAPER

Self-healing carboxylic acid-cured epoxy networks driven by the cyclodextrin–cyclohexane host–guest interaction

verfasst von: Risa Kurihara, Yamato Ogawa, Kaito Sugane, Mitsuhiro Shibata

Erschienen in: Polymer Bulletin | Ausgabe 7/2024

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Abstract

The reaction of β-cyclodextrin (β-CD) and bromoacetic acid in the presence of potassium hydroxide produced a carboxymethylated β-CD (CMβCD) with a substitution degree of 3.0. Thermal curing reactions of sorbitol polyglycidyl ether with CMβCD, cyclohexanecarboxylic acid, and poly(ethylene glycol) bis(carboxymethyl) ether (PEGBC) at 1/1 epoxy/carboxylic acid molar ratios produced carboxylic acid-cured epoxy networks (SCCPB) incorporating the cyclodextrin-cyclohexane host–guest moieties. The FT–IR and gel fraction measurements for the cured products revealed that polymer networks were formed by the reaction between epoxy and carboxy groups. With increasing PEGBC content, the glass transition temperature (T_g), tensile strength, and tensile modulus of SCCPB films decreased. SCCPB films with relatively high PEGBC contents demonstrated self-healing properties after being treated at room temperature for 30 s, whereas SCCPB films with relatively low PEGBC contents did not. The SCCPB film with the highest PEGBC content exhibited an excellent healing efficiency (98%) based on the recovery rate of the tensile strength, when healed at 60 °C for 24 h.

Vorheriger Artikel Determination of gentamicin by using square wave anodic stripping voltammetry with poly (β-cyclodextrin-p-toluene sulfonic acid) modified glassy carbon electrode

Nächster Artikel Effects of monomer purity on AA-BB polycondensation: a Monte Carlo study

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Titel: Self-healing carboxylic acid-cured epoxy networks driven by the cyclodextrin–cyclohexane host–guest interaction
verfasst von: Risa Kurihara
Yamato Ogawa
Kaito Sugane
Mitsuhiro Shibata
Publikationsdatum: 06.10.2023
Verlag: Springer Berlin Heidelberg
Erschienen in: Polymer Bulletin / Ausgabe 7/2024
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-023-05017-8

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