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Erschienen in: Colloid and Polymer Science 5-6/2011

01.04.2011 | Original Contribution

Self-oscillating polymer gel as novel biomimetic materials exhibiting spatiotemporal structure

verfasst von: Ryo Yoshida

Erschienen in: Colloid and Polymer Science | Ausgabe 5-6/2011

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Abstract

As a novel biomimetic polymer gel, we have been studying polymer gel with an autonomous self-oscillating function since it was firstly reported in 1996. For developing the polymer gels, we utilized an oscillating chemical reaction, called the Belousov–Zhabotinsky (BZ) reaction, which is recognized as a chemical model for understanding several autonomous phenomena in biological systems. The self-oscillating polymer gel is composed of a poly(N-isopropylacrylamide) network in which the metal catalyst for the BZ reaction is covalently immobilized. Under the coexistence of the reactants, the polymer undergoes spontaneous swelling–deswelling changes (in the case of gel) or cyclic soluble–insoluble changes (in the case of uncross-linked polymer) without any on–off switching of external stimuli. Several kinds of functional material systems utilizing the self-oscillating polymer and gel such as biomimetic actuators, mass transport surface, etc. are expected. Here, these recent progress on the self-oscillating polymer and gels and the design of functional material systems are summarized.

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Literatur
1.
Zurück zum Zitat Yoshida R (2005) Design of functional polymer gels and their application to biomimetic materials. Curr Org Chem 9:1617–1641CrossRef Yoshida R (2005) Design of functional polymer gels and their application to biomimetic materials. Curr Org Chem 9:1617–1641CrossRef
2.
Zurück zum Zitat Ottenbrite RM, Park K, Okano T, Peppas NA (eds) (2010) Biomedical applications of hydrogels handbook. Springer, New York Ottenbrite RM, Park K, Okano T, Peppas NA (eds) (2010) Biomedical applications of hydrogels handbook. Springer, New York
3.
Zurück zum Zitat Miyata T (2002) In: Yui N (ed) Stimuli-responsive polymer and gels: in supramolecular design for biological applications. CRC, Boca Raton, pp 191–225 Miyata T (2002) In: Yui N (ed) Stimuli-responsive polymer and gels: in supramolecular design for biological applications. CRC, Boca Raton, pp 191–225
4.
Zurück zum Zitat Osada Y, Khokhlov AR (eds) (2002) Polymer gels and networks. Marcel Dekker, New York Osada Y, Khokhlov AR (eds) (2002) Polymer gels and networks. Marcel Dekker, New York
5.
Zurück zum Zitat Field RJ, Burger M (eds) (1985) Oscillations and traveling waves in chemical systems. Wiley, New York Field RJ, Burger M (eds) (1985) Oscillations and traveling waves in chemical systems. Wiley, New York
6.
Zurück zum Zitat Epstein IR, Pojman JA (1998) An introduction to nonlinear chemical dynamics: oscillations, waves, patterns, and chaos. Oxford University Press, New York Epstein IR, Pojman JA (1998) An introduction to nonlinear chemical dynamics: oscillations, waves, patterns, and chaos. Oxford University Press, New York
7.
Zurück zum Zitat Yoshida R, Takahashi T, Yamaguchi T, Ichijo H (1996) Self-oscillating gel. J Am Chem Soc 118:5134–5135CrossRef Yoshida R, Takahashi T, Yamaguchi T, Ichijo H (1996) Self-oscillating gel. J Am Chem Soc 118:5134–5135CrossRef
8.
Zurück zum Zitat Yoshida R, Takahashi T, Yamaguchi T, Ichijo H (1997) Self-oscillating gels. Adv Mater 9:175–178CrossRef Yoshida R, Takahashi T, Yamaguchi T, Ichijo H (1997) Self-oscillating gels. Adv Mater 9:175–178CrossRef
9.
Zurück zum Zitat Yoshida R (2008) Self-oscillating polymer and gels as novel biomimetic materials. Bull Chem Soc Jpn 81:676–688CrossRef Yoshida R (2008) Self-oscillating polymer and gels as novel biomimetic materials. Bull Chem Soc Jpn 81:676–688CrossRef
10.
Zurück zum Zitat Yoshida R, Sakai T, Hara Y, Maeda S, Hashimoto S, Suzuki D, Murase Y (2009) Self-oscillating gel as novel biomimetic materials. J Control Release 140:186–193CrossRef Yoshida R, Sakai T, Hara Y, Maeda S, Hashimoto S, Suzuki D, Murase Y (2009) Self-oscillating gel as novel biomimetic materials. J Control Release 140:186–193CrossRef
11.
Zurück zum Zitat Yoshida R (2010) Self-oscillating gels driven by the Belousov–Zhabotinsky reaction as novel smart materials. Adv Mater 22:3463–3483CrossRef Yoshida R (2010) Self-oscillating gels driven by the Belousov–Zhabotinsky reaction as novel smart materials. Adv Mater 22:3463–3483CrossRef
12.
Zurück zum Zitat Yoshida R, Tanaka M, Onodera S, Yamaguchi T, Kokufuta E (2000) In-phase synchronization of chemical and mechanical oscillations in self-oscillating gels. J Phys Chem A 104:7549–7555CrossRef Yoshida R, Tanaka M, Onodera S, Yamaguchi T, Kokufuta E (2000) In-phase synchronization of chemical and mechanical oscillations in self-oscillating gels. J Phys Chem A 104:7549–7555CrossRef
13.
Zurück zum Zitat Yoshida R, Takei K, Yamaguchi T (2003) Self-beating motion of gels and modulation of oscillation rhythm synchronized with organic acid. Macromolecules 36:1759–1761CrossRef Yoshida R, Takei K, Yamaguchi T (2003) Self-beating motion of gels and modulation of oscillation rhythm synchronized with organic acid. Macromolecules 36:1759–1761CrossRef
14.
Zurück zum Zitat Ito Y, Nogawa N, Yoshida R (2003) Temperature control of the Belousov–Zhabotinsky reaction using a thermo-responsive polymer. Langmuir 19:9577–9579CrossRef Ito Y, Nogawa N, Yoshida R (2003) Temperature control of the Belousov–Zhabotinsky reaction using a thermo-responsive polymer. Langmuir 19:9577–9579CrossRef
15.
Zurück zum Zitat Yoshida R, Sakai T, Tabata O, Yamaguchi T (2002) Design of novel biomimetic polymer gels with self-oscillating function. Sci Tech Adv Mater 3:95–102CrossRef Yoshida R, Sakai T, Tabata O, Yamaguchi T (2002) Design of novel biomimetic polymer gels with self-oscillating function. Sci Tech Adv Mater 3:95–102CrossRef
16.
Zurück zum Zitat Shinohara S, Seki T, Sakai T, Yoshida R, Takeoka Y (2008) Photoregulated wormlike motion of a gel. Angew Chem Int Ed 47:9039–9043CrossRef Shinohara S, Seki T, Sakai T, Yoshida R, Takeoka Y (2008) Photoregulated wormlike motion of a gel. Angew Chem Int Ed 47:9039–9043CrossRef
17.
Zurück zum Zitat Shinohara S, Seki T, Sakai T, Yoshida R, Takeoka Y (2008) Chemical and optical control of peristaltic actuator based on self-oscillating porous gel. Chem Commun 39:4735–4737CrossRef Shinohara S, Seki T, Sakai T, Yoshida R, Takeoka Y (2008) Chemical and optical control of peristaltic actuator based on self-oscillating porous gel. Chem Commun 39:4735–4737CrossRef
18.
Zurück zum Zitat Maeda S, Hara Y, Yoshida R, Hashimoto S (2008) Peristaltic motion of polymer gels. Angew Chem Int Ed 47:6690–6693CrossRef Maeda S, Hara Y, Yoshida R, Hashimoto S (2008) Peristaltic motion of polymer gels. Angew Chem Int Ed 47:6690–6693CrossRef
19.
Zurück zum Zitat Takeoka Y, Watanabe M, Yoshida R (2003) Self-sustaining peristaltic motion on the surface of a porous gel. J Am Chem Soc 125:13320–13321CrossRef Takeoka Y, Watanabe M, Yoshida R (2003) Self-sustaining peristaltic motion on the surface of a porous gel. J Am Chem Soc 125:13320–13321CrossRef
20.
Zurück zum Zitat Sasaki S, Koga S, Yoshida R, Yamaguchi T (2003) Mechanical oscillation coupled with the Belousov–Zhabotinsky reaction in gel. Langmuir 19:5595–5600CrossRef Sasaki S, Koga S, Yoshida R, Yamaguchi T (2003) Mechanical oscillation coupled with the Belousov–Zhabotinsky reaction in gel. Langmuir 19:5595–5600CrossRef
21.
Zurück zum Zitat Aoki R, Enoki M, Yoshida R (2007) Measurement of elastic properties of self-oscillating gel. Key Eng Mater 353:2235–2238CrossRef Aoki R, Enoki M, Yoshida R (2007) Measurement of elastic properties of self-oscillating gel. Key Eng Mater 353:2235–2238CrossRef
22.
Zurück zum Zitat Tabata O, Hirasawa H, Aoki S, Yoshida R, Kokufuta E (2002) Ciliary motion actuator using self-oscillating gel. Sensors and Actuators A 95:234–238CrossRef Tabata O, Hirasawa H, Aoki S, Yoshida R, Kokufuta E (2002) Ciliary motion actuator using self-oscillating gel. Sensors and Actuators A 95:234–238CrossRef
23.
Zurück zum Zitat Tabata O, Kojima H, Kasatani T, Isono Y, Yoshida R (2003) Chemo-mechanical actuator using self-oscillating gel for artificial cilia. Proc Int Conf MEMS 2003:12–15 Tabata O, Kojima H, Kasatani T, Isono Y, Yoshida R (2003) Chemo-mechanical actuator using self-oscillating gel for artificial cilia. Proc Int Conf MEMS 2003:12–15
24.
Zurück zum Zitat Maeda S, Hara Y, Sakai T, Yoshida R, Hashimoto S (2007) Self-walking gel. Adv Mater 19:3480–3484CrossRef Maeda S, Hara Y, Sakai T, Yoshida R, Hashimoto S (2007) Self-walking gel. Adv Mater 19:3480–3484CrossRef
25.
Zurück zum Zitat Maeda S, Hara Y, Yoshida R, Hashimoto S (2008) Control of dynamic motion of a gel actuator driven by the Belousov–Zhabotinsky reaction. Macromol Rapid Commun 29:401–405CrossRef Maeda S, Hara Y, Yoshida R, Hashimoto S (2008) Control of dynamic motion of a gel actuator driven by the Belousov–Zhabotinsky reaction. Macromol Rapid Commun 29:401–405CrossRef
26.
Zurück zum Zitat Murase Y, Maeda S, Hashimoto S, Yoshida R (2009) Design of a mass transport surface utilizing peristaltic motion of a self-oscillating gel. Langmuir 25:483–489CrossRef Murase Y, Maeda S, Hashimoto S, Yoshida R (2009) Design of a mass transport surface utilizing peristaltic motion of a self-oscillating gel. Langmuir 25:483–489CrossRef
27.
Zurück zum Zitat Murase Y, Hidaka M, Yoshida R (2010) Self-driven gel conveyer: autonomous transportation by peristaltic motion of self-oscillating gel. Sensors Actuators B 149:272–283CrossRef Murase Y, Hidaka M, Yoshida R (2010) Self-driven gel conveyer: autonomous transportation by peristaltic motion of self-oscillating gel. Sensors Actuators B 149:272–283CrossRef
28.
Zurück zum Zitat Tateyama S, Shibuta Y, Yoshida R (2008) Direction control of chemical wave propagation in self-oscillating gel array. J Phys Chem B 112:1777–1782CrossRef Tateyama S, Shibuta Y, Yoshida R (2008) Direction control of chemical wave propagation in self-oscillating gel array. J Phys Chem B 112:1777–1782CrossRef
29.
Zurück zum Zitat Sakai T, Takeoka Y, Seki T, Yoshida R (2007) Organized monolayer of thermosensitive microgel beads prepared by double-templete polymerization. Langmuir 23:8651–8654CrossRef Sakai T, Takeoka Y, Seki T, Yoshida R (2007) Organized monolayer of thermosensitive microgel beads prepared by double-templete polymerization. Langmuir 23:8651–8654CrossRef
30.
Zurück zum Zitat Yoshida R, Sakai T, Ito S, Yamaguchi T (2002) Self-oscillation of polymer chains with rhythmical soluble–insoluble changes. J Am Chem Soc 124:8095–8098CrossRef Yoshida R, Sakai T, Ito S, Yamaguchi T (2002) Self-oscillation of polymer chains with rhythmical soluble–insoluble changes. J Am Chem Soc 124:8095–8098CrossRef
31.
Zurück zum Zitat Ito Y, Hara Y, Uetsuka H, Hasuda H, Onishi H, Arakawa H, Ikai A, Yoshida R (2006) AFM observation of immobilized self-oscillating polymer. J Phys Chem B 110:5170–5173CrossRef Ito Y, Hara Y, Uetsuka H, Hasuda H, Onishi H, Arakawa H, Ikai A, Yoshida R (2006) AFM observation of immobilized self-oscillating polymer. J Phys Chem B 110:5170–5173CrossRef
32.
Zurück zum Zitat Suzuki D, Sakai T, Yoshida R (2008) Self-flocculating/self-dispersing oscillation of microgels. Angew Chem Int Ed 47:917–920CrossRef Suzuki D, Sakai T, Yoshida R (2008) Self-flocculating/self-dispersing oscillation of microgels. Angew Chem Int Ed 47:917–920CrossRef
33.
Zurück zum Zitat Suzuki D, Yoshida R (2008) Temporal control of self-oscillation for microgels by cross-linking network structure. Macromolecules 41:5830–5838CrossRef Suzuki D, Yoshida R (2008) Temporal control of self-oscillation for microgels by cross-linking network structure. Macromolecules 41:5830–5838CrossRef
34.
Zurück zum Zitat Suzuki D, Yoshida R (2008) Effect of initial substrate concentration of the Belousov–Zhabotinsky reaction on self-oscillation for microgel system. J Phys Chem B 112:12618–12624CrossRef Suzuki D, Yoshida R (2008) Effect of initial substrate concentration of the Belousov–Zhabotinsky reaction on self-oscillation for microgel system. J Phys Chem B 112:12618–12624CrossRef
35.
Zurück zum Zitat Suzuki D, Yoshida R (2010) Self-oscillating core/shell microgels. Polym J 42:501–508CrossRef Suzuki D, Yoshida R (2010) Self-oscillating core/shell microgels. Polym J 42:501–508CrossRef
36.
Zurück zum Zitat Suzuki D, Taniguchi H, Yoshida R (2009) Autonomously oscillating viscosity in microgel dispersions. J Am Chem Soc 131:12058–12059CrossRef Suzuki D, Taniguchi H, Yoshida R (2009) Autonomously oscillating viscosity in microgel dispersions. J Am Chem Soc 131:12058–12059CrossRef
37.
Zurück zum Zitat Taniguchi H, Suzuki D, Yoshida R (2010) Characterization of autonomously oscillating viscosity induced by swelling/deswelling oscillation of the microgels. J Phys Chem B 114:2405–2410CrossRef Taniguchi H, Suzuki D, Yoshida R (2010) Characterization of autonomously oscillating viscosity induced by swelling/deswelling oscillation of the microgels. J Phys Chem B 114:2405–2410CrossRef
38.
Zurück zum Zitat Hara Y, Yoshida R (2008) A viscosity self-oscillation of polymer solution induced by the BZ reaction under acid-free condition. J Chem Phys 128:224904CrossRef Hara Y, Yoshida R (2008) A viscosity self-oscillation of polymer solution induced by the BZ reaction under acid-free condition. J Chem Phys 128:224904CrossRef
39.
Zurück zum Zitat Hara Y, Yoshida R (2005) Self-oscillation of polymer chains induced by the Belousov–Zhabotinsky reaction under acid-free conditions. J Phys Chem B 109:9451–9454CrossRef Hara Y, Yoshida R (2005) Self-oscillation of polymer chains induced by the Belousov–Zhabotinsky reaction under acid-free conditions. J Phys Chem B 109:9451–9454CrossRef
40.
Zurück zum Zitat Hara Y, Yoshida R (2005) Control of oscillating behavior for the self-oscillating polymer with pH-control site. Langmuir 21:9773–9776CrossRef Hara Y, Yoshida R (2005) Control of oscillating behavior for the self-oscillating polymer with pH-control site. Langmuir 21:9773–9776CrossRef
41.
Zurück zum Zitat Hara Y, Sakai T, Maeda S, Hashimoto S, Yoshida R (2005) Self-oscillating soluble–insoluble changes of polymer chain including an oxidizing agent induced by the Belousov–Zhabotinsky reaction. J Phys Chem B 109:23316–23319CrossRef Hara Y, Sakai T, Maeda S, Hashimoto S, Yoshida R (2005) Self-oscillating soluble–insoluble changes of polymer chain including an oxidizing agent induced by the Belousov–Zhabotinsky reaction. J Phys Chem B 109:23316–23319CrossRef
42.
Zurück zum Zitat Hara Y, Yoshida R (2008) Self-oscillating polymer fueled by organic acid. J Phys Chem B 112:8427–8429CrossRef Hara Y, Yoshida R (2008) Self-oscillating polymer fueled by organic acid. J Phys Chem B 112:8427–8429CrossRef
43.
Zurück zum Zitat Yashin VV, Balazs AC (2006) Pattern formation and shape changes in self-oscillating polymer gels. Science 314:798–801CrossRef Yashin VV, Balazs AC (2006) Pattern formation and shape changes in self-oscillating polymer gels. Science 314:798–801CrossRef
44.
Zurück zum Zitat Yashin VV, Kuksenok O, Balazs AC (2010) Modeling autonomously ocillating chemo-responsive gels. Prog Polym Sci 35:155–173CrossRef Yashin VV, Kuksenok O, Balazs AC (2010) Modeling autonomously ocillating chemo-responsive gels. Prog Polym Sci 35:155–173CrossRef
45.
Zurück zum Zitat Kuksenok O, Yashin VV, Kinoshita M, Sakai T, Yoshida R, Balazs AC (2011) Exploiting gradients in cross-link density to control the bending and self-propelled motion of active gels. J Mater Chem (in press) Kuksenok O, Yashin VV, Kinoshita M, Sakai T, Yoshida R, Balazs AC (2011) Exploiting gradients in cross-link density to control the bending and self-propelled motion of active gels. J Mater Chem (in press)
46.
Zurück zum Zitat Yoshida R, Omata K, Yamaura K, Ebata M, Tanaka M, Takai M (2006) Maskless microfabrication of thermosensitive gels using a microscope and application to a controlled release microchip. Lab Chip 6:1384–1386CrossRef Yoshida R, Omata K, Yamaura K, Ebata M, Tanaka M, Takai M (2006) Maskless microfabrication of thermosensitive gels using a microscope and application to a controlled release microchip. Lab Chip 6:1384–1386CrossRef
47.
Zurück zum Zitat Hidaka M, Yoshida R (2011) Self-oscillating gel composed of thermosensitive polymer exhibiting higher LCST. J Controlled Release (in press) Hidaka M, Yoshida R (2011) Self-oscillating gel composed of thermosensitive polymer exhibiting higher LCST. J Controlled Release (in press)
48.
Zurück zum Zitat Ueno T, Bundo K, Akagi Y, Sakai T, Yoshida R (2010) Autonomous viscosity oscillation by reversible complex formation of terpyridine-terminated poly(ethylene glycol) in the BZ reaction. Soft Matter 6:6072–6074CrossRef Ueno T, Bundo K, Akagi Y, Sakai T, Yoshida R (2010) Autonomous viscosity oscillation by reversible complex formation of terpyridine-terminated poly(ethylene glycol) in the BZ reaction. Soft Matter 6:6072–6074CrossRef
Metadaten
Titel
Self-oscillating polymer gel as novel biomimetic materials exhibiting spatiotemporal structure
verfasst von
Ryo Yoshida
Publikationsdatum
01.04.2011
Verlag
Springer-Verlag
Erschienen in
Colloid and Polymer Science / Ausgabe 5-6/2011
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-010-2371-y

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