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Erschienen in: Cellulose 15/2022

09.08.2022 | Original Research

Shape memory and underwater superelastic mof@cellulose aerogels for rapid and large-capacity adsorption of metal ions

verfasst von: Meng Wang, Lupeng Shao, Mengying Jia

Erschienen in: Cellulose | Ausgabe 15/2022

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Abstract

Cellulose aerogels have been used in widespread areas, such as absorbents, thermal insulation material and medical material. Herein, we propose an effective strategy to fabricate elastic cellulose aerogels by combining cellulose nanofibers with polyvinyl alcohol (PVA) “glue”. The CA not only had a robust chemical-bond cross-link network, but also had a strong H-bond, which enhanced underwater mechanical properties. Moreover, the compressible CA provided a large number of nucleation sites for the growth of Metal–organic framework nanoparticles (ZIF-67 and ZIF-8) through interface self-assemble. The obtained aerogels with a low density of 9.8–11.2 mg cm−3 and highly porous of 99.4–99.5% possessed excellent elasticity both in air and underwater. The adsorption capacities of the MOF@CA for Pb2+ and Cu2+ are up to 123 mg g−1 and 70.53 mg g−1, respectively. The novel MOF@CA adsorbents with excellent mechanical properties display application prospects in the removal of heavy metals from wastewater.

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Metadaten
Titel
Shape memory and underwater superelastic mof@cellulose aerogels for rapid and large-capacity adsorption of metal ions
verfasst von
Meng Wang
Lupeng Shao
Mengying Jia
Publikationsdatum
09.08.2022
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 15/2022
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-022-04774-5

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