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Journal of Nanoparticle Research

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01.05.2018 | Research Paper

Single-layer graphdiyne-covered Pt(111) surface: improved catalysis confined under two-dimensional overlayer

verfasst von: Xi Chen, Zheng-Zhe Lin

Erschienen in: Journal of Nanoparticle Research | Ausgabe 5/2018

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Abstract

In recent years, two-dimensional confined catalysis, i.e., the enhanced catalytic reactions in confined space between metal surface and two-dimensional overlayer, makes a hit and opens up a new way to enhance the performance of catalysts. In this work, graphdiyne overlayer was proposed as a more excellent material than graphene or hexagonal boron nitride for two-dimensional confined catalysis on Pt(111) surface. Density functional theory calculations revealed the superiority of graphdiyne overlayer originates from the steric hindrance effect which increases the catalytic ability and lowers the reaction barriers. Moreover, with the big triangle holes as natural gas tunnels, graphdiyne possesses higher efficiency for the transit of gaseous reactants and products than graphene or hexagonal boron nitride. The results in this work would benefit future development of two-dimensional confined catalysis.

Vorheriger Artikel Click polymerization for the synthesis of reduction-responsive polymeric prodrug

Nächster Artikel Melting and solidification behavior of Cu/Al and Ti/Al bimetallic core/shell nanoparticles during additive manufacturing by molecular dynamics simulation

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Titel: Single-layer graphdiyne-covered Pt(111) surface: improved catalysis confined under two-dimensional overlayer
verfasst von: Xi Chen
Zheng-Zhe Lin
Publikationsdatum: 01.05.2018
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 5/2018
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-018-4236-0

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