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Journal of Materials Science
Erschienen in: Journal of Materials Science 6/2018

20.11.2017 | Energy materials

Solvothermally synthesized Ti-rich LiMnTiO4 as cathode material for high Li storage

verfasst von: Thangaian Kesavan, Chenrayan Senthil, Manickam Sasidharan

Erschienen in: Journal of Materials Science | Ausgabe 6/2018

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Abstract

Ti-doped LiMn1.8Ti0.2O4 and LiMnTiO4 spinel materials as cathode for Li-ion batteries are synthesized by solvothermal method using ethylene glycol as solvent. Structural and morphological features of spinel materials are evaluated with X-ray diffraction, field emission scanning electron microscope, and high-resolution transmission electron microscope techniques. Energy-dispersive X-ray and X-ray photoelectron spectroscopy analyzes confirm the presence of different elements in the Ti-doped spinel. Electrochemical Li insertion properties are evaluated by potentiostatic and galvanostatic modes between 1.5 and 4.8 V versus Li/Li+ where the Ti-rich LiMnTiO4 (Mn/Ti = 1) exhibits high specific capacity of 173 mAh g−1 after 50 charge/discharge cycles compared to LiMn1.8Ti0.2O4 (Mn/Ti = 9, 132 mAh g−1) with less Ti content. The titanium-rich LiMnTiO4 exhibits a well-defined voltage profile, higher specific capacity, and enhanced electrochemical performance over Ti-poor LiMn1.8Ti0.2O4 which could be attributed to high microstructural stability of Mn cations with suppressed Jahn–Teller distortion and facilitation of Mn2+/Mn4+ redox couple during the electrochemical charge/discharges.
Vorheriger Artikel Facile synthesis of 3D binder-free N-doped carbon nanonet derived from silkworm cocoon for Li–O2 battery
Nächster Artikel Nano-dynamic mechanical analysis (nano-DMA) of creep behavior of shales: Bakken case study

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Metadaten
Titel
Solvothermally synthesized Ti-rich LiMnTiO4 as cathode material for high Li storage
verfasst von
Thangaian Kesavan
Chenrayan Senthil
Manickam Sasidharan
Publikationsdatum
20.11.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 6/2018
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-1819-6

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