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Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 8/2015

01.08.2015 | Original Contribution

Spherical and core-shell fluorinated polyacrylate latex particles: preparation and characterization

verfasst von: Wei Yang, Liqun Zhu, Yichi Chen

Erschienen in: Colloid and Polymer Science | Ausgabe 8/2015

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Abstract

Fluorinated polyacrylate particles with spherical (SP) and core-shell (CS) structures have been prepared via emulsion polymerization. Morphologies of SP and CS latex particles were observed by transmission electron microscope (TEM). The copolymer and the film were characterized by Fourier transform infrared spectroscopy (FT-IR), 19F NMR, atomic force microscope (AFM), X-ray photoelectron spectroscopy (XPS), and thermogravimetry (TG-DSC) analyses. Fluorinated components in the copolymer were found to aggregate at the film surface, and the core-shell structure of latex particles contributes to occurrence of phase separation at the film surface. The film prepared from core-shell latex particles exhibits more satisfied water repellency than that obtained from spherical latex particles. Fluorine components at SP and CS film surfaces present significantly different aggregation behaviors.
Vorheriger Artikel Fabrication of a thermo-sensitive poly(N-acetyl-L-glutamic acid-co-lysine ester) with excellent biocompatibility
Nächster Artikel Preparation of vinyl silica-based organic/inorganic nanocomposites and superhydrophobic polyester surfaces from it

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Metadaten
Titel
Spherical and core-shell fluorinated polyacrylate latex particles: preparation and characterization
verfasst von
Wei Yang
Liqun Zhu
Yichi Chen
Publikationsdatum
01.08.2015
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 8/2015
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-015-3583-y

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