Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Bücher
Zeitschriften
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
MTZ-Fachkongress

Antriebe und Energiesysteme von morgen


Austausch von Automobil- und Energiewirtschaft

Am 14./15. Mai geht es in Chemnitz um die Mobilitätswende durch Elektro- und Wasserstofffahrzeuge.
Erweiterte Suche
Anmelden
nach oben
Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 8/2015

01.08.2015 | Original Contribution

Preparation of vinyl silica-based organic/inorganic nanocomposites and superhydrophobic polyester surfaces from it

verfasst von: Lihui Xu, Yong Shen, Liming Wang, Ying Ding, Zaisheng Cai

Erschienen in: Colloid and Polymer Science | Ausgabe 8/2015

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

A fluoropolymer/silica (FP/SiO2) organic–inorganic nanocomposite was synthesized by copolymerization of butyl acrylate (BA), methyl methacrylate (MMA), 2-hydroxyethyl acrylate (HEA), and dodecafluoroheptyl methacrylate (DFMA) based on vinyl nano-silica (V-SiO2) using emulsion polymerization. The V-SiO2 was prepared via water-based sol–gel reaction with vinyl trimethoxy silane (VTMS) as the precursor in the presence of the composite surfactant. The preparation of V-SiO2, influence of the composite surfactant on V-SiO2, effect of composite emulsifier on the properties of FP/SiO2, and the formation of the FP/SiO2 nanocomposite were analyzed. The resulting V-SiO2 and FP/SiO2 were characterized by particle size analyzer, transmission electron microscopy (TEM), Fourier-transform infrared spectrometry (FTIR), and X-ray photoelectron spectroscopy (XPS). The obtained FP/SiO2 nanocomposites were applied to coat onto the flexible polyester fabrics by dip-pad-cure process. The results showed that the V-SiO2 nanoparticles had been introduced into the FP/SiO2 nanocomposites and superhydrophobic polyester surfaces were achieved by the cooperation of the rough surface structure provided by the silica nanoparticles and the low surface energy caused by fluoropolymer.
Vorheriger Artikel Spherical and core-shell fluorinated polyacrylate latex particles: preparation and characterization
Nächster Artikel Effect of ionic liquid C2mimBr on rheological behavior of Gemini surfactant 12-2-12 aqueous solution

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Wood TJ, Ward LJ, Badyal JPS (2013) Super-adhesive polymer-silica nanocomposite layers. ACS Appl Mater Interfaces 5:9678–9683CrossRef
2.
Raveh M, Liu L, Mandler D (2013) Electrochemical co-deposition of conductive polymer-silica hybrid thin films. Phys Chem Chem Phys 15:10876–10884CrossRef
3.
Zhou X, Shao H, Liu HR (2013) Preparation and characterization of film-forming raspberry-like polymer/silica nanocomposites via soap-free emulsion polymerization and the sol–gel process. Colloid Polym Sci 291:1181–1190CrossRef
4.
Yoda S, Ohara M, Takebayashi Y, Sue K, Hakuta Y, Furuya T, Yamada M, Otake K (2013) A porous polymer-silica composite with a “vespula-like” structure for thermal insulating materials prepared via high pressure phase control. J Mater Chem A 1:9620–9623CrossRef
5.
Watanabe T, Tateishi T, Sakai T, Toyama K, Hayakawa Y, Ono T (2013) Fluorinated polymer/silica composites with remarkable mechanical and antifouling properties-design for artificial teeth with improved durability and esthetics. Kobunshi Ronbunshu 70:166–174CrossRef
6.
Ribeiro T, Baleizao C, Farinha JPS (2014) Functional films from silica/polymer nanoparticles. Materials 7:3881–3900CrossRef
7.
Zou H, Wu SS, Shen J (2008) Polymer/silica nanocomposites: Preparation, characterization, properties, and applications. Chem Rev 108:3893–3957CrossRef
8.
Lakshmi RV, Bharathidasan T, Bera P, Basu BJ (2012) Fabrication of superhydrophobic and oleophobic sol–gel nanocomposite coating. Surf Coat Technol 206:3888–3894CrossRef
9.
Yang H, Hu XJ, Chen R, Liu ST, Pi PH, Yang ZR (2013) Fluoropolymer/SiO2 composite films with switchable superoleophilicity and high oleophobicity for “on-off” oil permeation. Appl Surf Sci 280:113–116CrossRef
10.
Wang SJ, Song LY, Chen PP, Zhou YF, Nie WY (2014) Weak acid–base interaction induced assembly for the formation of rambutan-like poly(styrene-alt-maleic anhydride)/silica composite microspheres. Colloid Polym Sci 292:2465–2473CrossRef
11.
Zheng W, He L, Liang JY, Chang G, Wang N (2011) Preparation and properties of core-shell nanosilica/poly(methyl methacrylate-butyl acrylate-2,2,2-trifluoroethyl methacrylate) latex. J Appl Polym Sci 120:1152–1161CrossRef
12.
Zenerino A, Amigoni S, de Givenchy ET, Josse D, Guittard F (2013) New fluorinated hybrid organic/inorganic water soluble polymeric network. Polymer 54:6089–6095CrossRef
13.
Audouin F, Heise A (2014) Synthesis of polymer-silica hybrid polyHIPEs by double in situ polymerization of concentrated water in oil emulsion. Polymer 55:403–409CrossRef
14.
Cui X, Zhong S, Yan J, Wang C, Zhang H, Wang H (2010) Synthesis and characterization of core-shell SiO2-fluorinated polyacrylate nanocomposite latex particles containing fluorine in the shell. Colloids Surf A 360:41–46CrossRef
15.
Qu AL, Wen XF, Pi PH, Cheng J, Yang ZR (2008) Morphologies and superhydrophobicity of hybrid film surfaces based on silica and fluoropolymer. J Mater Sci Technol 24:693–699CrossRef
16.
Wei HS, Kuo CC, Jaing CC, Chang YC, Lee CC (2014) Highly transparent superhydrophobic thin film with low refractive index prepared by one-step coating of modified silica nanoparticles. J Sol-Gel Sci Technol 71:168–175CrossRef
17.
Sun XL, Fan ZP, Zhang LD, Wang L, Wei ZJ, Wang XQ, Liu WL (2011) Superhydrophobicity of silica nanoparticles modified with polystyrene. Appl Surf Sci 257:2308–2312CrossRef
18.
Hao LF, An QF, Xu W (2012) Facile fabrication of superhydrophobic cotton fabric from stearyl methacrylate modified polysiloxane/silica nanocomposite. Fibers Polym 13:1145–1153CrossRef
19.
Yazdanshenas ME, Shateri-Khalilabad M (2013) One-step synthesis of superhydrophobic coating on cotton fabric by ultrasound irradiation. Ind Eng Chem Res 52:12846–12854CrossRef
20.
Wu L, Zhang J, Li B, Wang A (2013) Mimic nature, beyond nature: Facile synthesis of durable superhydrophobic textiles using organosilanes. J Mater Chem B 1:4756–4763CrossRef
21.
Bredereck K, Effenberger F, Tretter M (2011) Preparation and characterization of silica aquasols. J Colloid Interface Sci 360:408–414CrossRef
22.
Deng TS, Zhang QF, Zhang JY, Shen X, Zhu KT, Wu JL (2009) One-step synthesis of highly monodisperse hybrid silica spheres in aqueous solution. J Colloid Interface Sci 329:292–299.3CrossRef
23.
Haldorai Y, Long PQ, Noh SK, Lyoo WS, Shim JJ (2011) Ultrasonically assisted in situ emulsion polymerization: a facile approach to prepare conducting copolymer/silica nanocomposites. Polym Adv Technol 22:781–787CrossRef
24.
Nagappan S, Park SS, Ha C-S (2014) Recent advances in superhydrophobic nanomaterials and nanoscale systems. J Nanosci Nanotechnol 14:1441–1462CrossRef
25.
Guo ZG, Liu WM, Su BL (2011) Superhydrophobic surfaces: from natural to biomimetic to functional. J Colloid Interface Sci 353:335–355CrossRef
26.
Liu KS, Yao X, Jiang L (2010) Recent developments in bio-inspired special wettability. Chem Soc Rev 39:3240–3255CrossRef
27.
Hsieh CT, Chang BS, Lin JY (2011) Improvement of water and oil repellency on wood substrates by using fluorinated silica nanocoating. Appl Surf Sci 257:7997–8002CrossRef
28.
Yu HJ, Luo ZH (2010) Novel superhydrophobic silica/poly(siloxane- fluoroacrylate) hybrid nanoparticles prepared via two-step surface-initiated ATRP: Synthesis, characterization, and wettability. J Polym Sci Polym Chem 48:5570–5580CrossRef
29.
Zhou H, Wang H, Niu H, Gestos A, Lin T (2013) Robust, self-healing superamphiphobic fabrics prepared by two-step coating of fluoro-containing polymer, fluoroalkyl silane, and modified silica nanoparticles. Adv Funct Mater 23:1664–1670CrossRef
30.
Zimmermann J, Seeger S, Reifler FA (2009) Water shedding angle: a new technique to evaluate the water-repellent properties of superhydrophobic surfaces. Text Res J 79:1565–1570CrossRef
31.
Arriagada FJ, Osseo-Asare K (1999) Synthesis of nanosize silica in a nonionic water-in-oil microemulsion: Effects of the water/surfactant molar ratio and ammonia concentration. J Colloid Interface Sci 211:210–220CrossRef
32.
Mullin JW (1997) Crystallization, 3rd edn. Oxford Univ. Press, Oxford
33.
Spanhel L, Anderson MA (1991) Semiconductor clusters in the sol–gel process: Quantized aggregation, gelation, and crystal growth in concentrated zinc oxide colloids. J Am Chem Soc 113:2826–2833CrossRef
34.
LaMer VK, Dinegar RH (1950) Theory, production and mechanism of formation of monodispersed hydrosols. J Am Chem Soc 72:4847–4854CrossRef
35.
Rios L, Hidalgo M, Cavaille JY, Guillot J, Guyot A, Pichot C (1991) Polystyrene(1)/poly(butyl acrylate-methacrylic acid)(2) core-shell emulsion polymers. Part I. Synthesis and colloidal characterization. Colloid Polym Sci 269:812–824CrossRef
36.
Mills MF, Gilbert RG, Napper DH (1990) Effect of polymerization kinetics on particle morphology in heterogeneous systems. Macromolecules 23:4247–4257CrossRef
37.
Okubo M, Yamaguchi S, Matsumoto T (1986) Morphology of composite polymer emulsion particles consisting of two kinds of polymers between which ionic bonding intermolecular interaction operates. J Appl Polym Sci 31:1075–1082CrossRef
38.
Okubo M, Yamaguchi S, Matsumoto T (1985) Effect of interaction between different polymers on the formation of heterogeneous structure in composite polymer emulsion particles produced by seeded emulsion polymerization. Kobunshi Ronbunshu 42:17–22CrossRef
39.
Hoefnagels HF, Wu D, de With G, Ming W (2007) Biomimetic superhydrophobic and highly oleophobic cotton textiles. Langmuir 23:13158–13163CrossRef
40.
Tuteja A, Choi W, Ma ML, Mabry JM, Mazzella SA, Rutledge GC, McKinley GH, Cohen RE (2007) Designing superoleophobic surfaces. Science 318:1618–1622CrossRef
41.
Hsieh CT, Wu FL, Chen WY (2010) Superhydrophobicity and superoleophobicity from hierarchical silica sphere stacking layers. Mater Chem Phys 121:14–21CrossRef
42.
Zou H, Lin S, Tu Y, Liu G, Hu J, Li F, Miao L, Zhang G, Luo H, Liu F, Hou C, Hu M (2013) Simple approach towards fabrication of highly durable and robust superhydrophobic cotton fabric from functional diblock copolymer. J Mater Chem A 1:11246–11260CrossRef
43.
Gao Y, Huang YG, Feng SJ, Gu GT, Qing FL (2010) Novel superhydrophobic and highly oleophobic PFPE-modified silica nanocomposite. J Mater Sci 45:460–466CrossRef
44.
Patankar NA (2004) Mimicking the lotus effect: Influence of double roughness structures and slender pillars. Langmuir 20:8209–8213CrossRef
45.
Ming W, Wu D, van Benthem R, de With G (2005) Superhydrophobic films from raspberry-like particles. Nano Lett 5:2298–2301CrossRef
Metadaten
Titel
Preparation of vinyl silica-based organic/inorganic nanocomposites and superhydrophobic polyester surfaces from it
verfasst von
Lihui Xu
Yong Shen
Liming Wang
Ying Ding
Zaisheng Cai
Publikationsdatum
01.08.2015
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 8/2015
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-015-3624-6

Weitere Artikel der Ausgabe 8/2015

Colloid and Polymer Science 8/2015 Zur Ausgabe

Original Contribution

Synthesis and structure formation of block copolymers of poly(ethylene glycol) with homopolymers and copolymers of l-glutamic acid γ-benzyl ester and l-leucine in water

Short Communication

Fabrication of composite polymer particles by stabilizer-free seeded polymerization

Original Contribution

Reactive poly(ethylene-co-vinyl alcohol) monoliths with tunable pore morphology for enzyme immobilization

Original Contribution

Suspension “click” polymerizations: thiol-ene polymer particles prepared with natural gum stabilizers

Original Contribution

Effect of ionic liquid C2mimBr on rheological behavior of Gemini surfactant 12-2-12 aqueous solution

Original Contribution

Amphiphilic polymer-Ag composite microgels with tunable catalytic activity and selectivity

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise