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Erschienen in: Polymer Bulletin 8/2012

01.05.2012 | Original Paper

Star-branched cationic light-emitting dot with silsesquioxane core, synthesis, and light scattering studies

verfasst von: Yang Xiao, Khine Y. Mya, Beng H. Tan, Chao B. He

Erschienen in: Polymer Bulletin | Ausgabe 8/2012

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Abstract

Novel star-like hydrophobic (M) and hydrophilic (W) hybrid light-emitting dots were synthesized by grafting conjugated arms at eight vertexes of polyhedral oligomeric silsesquioxane (POSS) cage. The water-soluble cationic polymer W contains POSS as a core and two layers shell—an inner layer shell consists of the conjugated organic chain and a long chain of hydrophilic polymer as outer layer shell for solubilization in water. The 3D structure renders non-aggregation properties of W in solution as the wavelength for the absorption and luminescence spectra remains unchanged over different concentrations. The effects of ionic strength and pH on the properties of cationic polymer W were studied using UV, dynamic- and static-light scattering (DLS and SLS).

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Metadaten
Titel
Star-branched cationic light-emitting dot with silsesquioxane core, synthesis, and light scattering studies
verfasst von
Yang Xiao
Khine Y. Mya
Beng H. Tan
Chao B. He
Publikationsdatum
01.05.2012
Verlag
Springer-Verlag
Erschienen in
Polymer Bulletin / Ausgabe 8/2012
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-012-0709-y

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