Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Polymer Bulletin
Erschienen in: Polymer Bulletin 8/2012

01.05.2012 | Original Paper

Synthesis and photovoltaic properties of alternative copolymers of benzo[1,2-b:4,5-b′]dithiophene and thiophene

verfasst von: Jie Min, Bo Peng, Youjun He, Maojie Zhang, Zhi-Guo Zhang, Jing Zhang, Xia Guo, Chaohua Cui, Dan Deng, Yongfang Li

Erschienen in: Polymer Bulletin | Ausgabe 8/2012

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Two conjugated polymers containing benzodithiophene (BDT) unit and the unit of thiophene or thieno[3,2-b]thiophene, P(BDT-T) and P(BDT-TT), were synthesized by Pd-catalyzed Stille coupling method. The UV–Vis absorption, thermal, and electrochemical properties of the two polymers were characterized. Photovoltaic properties of the polymers were studied by using the polymers as donor and PC70BM as acceptor with a weight ratio of polymer: PC70BM of 1:1.5. The power conversion efficiencies of the PSC devices based on P(BDT-T) reached 2.05% with an open-circuit voltage of 0.75 V, a short-circuit current of 4.5 mA cm−2, and a fill factor of 0.61, under the illumination of AM1.5, 100 mW cm−2.
Vorheriger Artikel Preparation and properties of photocurable, high refractive, 2-naphthol epoxy-modified urethane acrylate
Nächster Artikel Morphological characterization of branched PP under stretching

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Dennler G, Scharber MC, Brabec CJ (2009) Polymer-fullerene bulk-heterojunction solar cells. Adv Mater 21:1323CrossRef
2.
Cheng Y-J, Yang S-H, Hsu C-S (2009) Synthesis of conjugated polymers for organic solar cell applications. Chem Rev 109:5868CrossRef
3.
Chen JW, Cao Y (2009) Development of novel conjugated donor polymers for high-efficiency bulk-heterojunction photovoltaic devices. Acc Chem Res 42:1709CrossRef
4.
Krebs FC (2009) Fabrication and processing of polymer solar cells: a review of printing and coating techniques. Sol Energy Mater Sol Cells 93:394CrossRef
5.
Yu G, Gao J, Hummelen JC, Wudl F, Heeger AJ (1995) Polymer photovoltaic cells: enhanced efficiencies via a network of internal donor-acceptor heterojunctions. Science 270:1789CrossRef
6.
Li G, Shrotriya V, Huang JS, Yao Y, Moriarty Y, Emery K, Yang Y (2005) High-efficiency solution processable polymer. Nat Mater 4:864CrossRef
7.
Ma WL, Yang CY, Gong X, Lee KH, Heeger AJ (2005) Thermally stable, efficient polymer soar cells with nanoscale control of the interpenetrating network morphology. Adv Funct Mater 15:1617CrossRef
8.
Hou JH, Chen HY, Zhang SQ, Chen RI, Yang Y, Wu Y, Li G (2009) Synthesis of a low band gap polymer and its application in highly efficient polymer solar cells. J Am Chem Soc 131:15586CrossRef
9.
Chen HY, Hou JH, Zhang SQ, Liang YY, Yang GW, Yang Y, Yang LP, Wu Y, Li G (2009) Polymer solar cells with enhanced open-circuit voltage and efficiency. Nat Photonics 3:649CrossRef
10.
Liang YY, Wu Y, Feng DQ, Tsai ST, Son HJ, Li G, Yu LP (2009) Development of new semiconducting polymers for high performance solar cells. J Am Chem Soc 131:56CrossRef
11.
Liang YY, Xu Z, Xia JB, Tsai ST, Wu Y, Li G, Ray C, Yu LP (2010) For the bright future-bulk heterojunction polymer solar cells with power conversion efficiency of 7.4%. Adv Mater 22:E135CrossRef
12.
Chu T, Lu J, Beaupr S, Zhang Y, Pouliot J, Wakim S, Zhou J, Leclerc M, Li Z, Ding J, Tao Y (2011) Bulk heterojunction solar cells using Thieno[3,4-c]pyrrole-4,6-dione and Dithieno[3,2-b:2′,3′-d]silole copolymer with a power conversion efficiency of 7.3%. J Am Chem Soc 133:4250CrossRef
13.
Zhang MJ, Guo X, Li YF (2011) Synthesis and characterization of a copolymer based on thiazolothiazole and dithienosilole for polymer solar cells. Adv Energy Mater 1:557CrossRef
14.
He YJ, Li YF (2011) Fullerene derivative acceptors for high performance polymer soalr cells. Phys Chem Chem Phys 13:1970CrossRef
15.
He YJ, Chen HY, Hou JH, Li YF (2010) Indene-C60 bisadduct: a new acceptor for high-performance polymer solar cells. J Am Chem Soc 132:1377CrossRef
16.
Zhao GJ, He YJ, Li YF (2010) 6.5% efficiency of polymer solar cells based on poly(3-hexylthiophene) and indene-C60 bisadduct by device optimization. Adv Mater 22:4355CrossRef
17.
Hou JH, Park MH, Zhang SQ, Yao Y, Chen LM, Li JH, Yang Y (2008) Bandgap and molecular energy level control of conjugated polymer photovoltaic materials based on Benzo[1,2-b:4,5-b′]dithiophene. Macromolecules 41:6012CrossRef
18.
Huang Y, Huo LJ, Zhang SQ, Guo X, Han CC, Li YF, Hou JH (2011) Sulfonyl: a new application of electron-withdrawing substituent in highly efficient photovoltaic polymer. Chem. Commun 47:8904CrossRef
19.
Huo LJ, Zhang SQ, Guo X, Xu F, Li YF, Hou JH (2011) Replacing alkoxy groups with alkylthienyl groups: a feasible approach to improve the properties of photovoltaic polymers. Angew Chem Int Ed 50:9697
20.
Zou YP, Naiari A, Berrouard P, Beaupre S, Aich BR, Tao Y, Leclerc M (2010) A thieno[3,4-c]pyrrole-4,6-dione-based copolymer for efficient solar cells. J Am Chem Soc 132:5330CrossRef
21.
Zhang GB, Fu YY, Zhang Q, Xie ZY (2010) Benzo[1,2-b:4,5-b′]dithiophene-dioxopyrrolothiophen copolymers for high performance solar cells. Chem Commun 46:4997CrossRef
22.
Piliego C, Holcombe TW, Douglas JD, Woo CH, Beaujuge PM, Frechet MJ (2010) Synthetic control of structural order in N-alkylthieno[3,4-c]pyrrole-4,6-dione-based polymers for efficient solar cells. J Am Chem Soc 132:7595CrossRef
23.
Zhang Y, Hau SK, Yip HL, Sun Y, Acton O, Jen AK (2010) Efficient polymer solar cells based on the copolymers of benzodithiophene and thienopyrroledione. Chem Mater 22:2696CrossRef
24.
Huo LJ, Hou JH, Zhang SQ, Chen HY, Yang Y (2010) A polybenzo[1,2-b:4,5-b′]dithiophene derivative with deep HOMO Level and its application in high-performance polymer solar cells. Angew Chem Int Ed 49:1500CrossRef
25.
Huo LJ, Guo X, Zhang SQ, Li YF, Hou JH (2011) PBDTTTZ: a broad band gap conjugated polymer with high photovoltaic performance in polymer solar cells. Macromolecules 44:4035CrossRef
26.
Wang M, Hu X, Liu P, Li W, Gong X, Huang F, Cao Y (2011) Donor–acceptor conjugated polymer based on naphtho[1,2-c:5,6-c]bis[1,2,5]thiadiazole for high-performance polymer solar cells. J Am Chem Soc 133:9638CrossRef
27.
Zhang MJ, Fan HJ, Guo X, He YJ, Zhang ZG, Min J, Zhang J, Zhan XW, Li YF (2010) Synthesis and Photovoltaic properties of a copolymer of benzo[1,2-b:4,5-b′]dithiophene and bithiazole. Macromolecules 43:8714CrossRef
28.
He YJ, Zhou Y, Zhao GJ, Min J, Guo X, Zhang B, Zhang MJ, Zhang J, Li YF, Zhang FL, Inganas O (2010) Poly(4,8-bis(2-ethylhexyloxy)benzo[1,2-b:4,5-b′]dithiophene vinylene): synthesis, optical and photovoltaic properties. J Polym Sci A 48:1822CrossRef
29.
McCullch I, Heeney M, Bailey C, Genevicius K, Macdonald I, Shkunov M, Sparrowe D, Tierney S, Wagner R, Zhang WM, Chabinyc ML, Kline RJ, McGehee MD, Toney MF (2006) Liquid-crystalline semiconducting polymers with high charge-carrier mobility. Nat Mater 5:328CrossRef
30.
Chabinyc ML, Toney MF, Kline RJ, McCulloch I, Heeney M (2007) X-ray scattering study of thin films of poly(2,5-bis(3-alkylthiophen-2-yl)thieno[3,2-b]thiophene). J Am Chem Soc 129:3226CrossRef
31.
He YJ, Wu WP, Zhao GJ, Liu YQ, Li YF (2008) Poly(3,6-dihexyl-thieno[3,2-b]thiophene vinylene): synthesis, field-effect transistors, and photovoltaic properties. Macromolecules 41:9760CrossRef
32.
Li Y, Wu Y, Liu P, Birau M, Pan H, Ong BS (2006) Poly(2,5-bis(2-thienyl)-3,6-dialkylthieno[3,2-b]thiophene)s-high-mobility semiconductors for thin-film transistors. Adv Mater 18:3029CrossRef
33.
Muhlbacher D, Scharber M, Morana M, Zhu ZG, Waller D, Gaudiana R, Brabec CJ (2006) High photovoltaic performance of a low-bandgap polymer. Adv Mater 18:2884CrossRef
34.
He MQ, Zhang FX (2007) Synthesis and structure of alkyl-substituted fused thiophenes containing up to seven rings. J Org Chem 72:442CrossRef
35.
He YJ, Zhang MJ, Min J, Zhao GJ, Li YF (2009) Influence of sulfur oxidation on the absorption and electronic energy levels of poly(thienothiophene) derivatives. J Phys Chem B 113:14981CrossRef
36.
Beimling P, Komehl G (1986) Synthesis of benzo[1,2-b′:4,5-b′]dithiophene and its 4,8-Dimethoxy and 4,8-dimethyl derivatives. Chem Ber 119:3198CrossRef
37.
Seitz DE, Lee SH, Hanson RN, Bottaro JC (1983) Synthesis and reactivity of the 2,5-bis(Trimethylstannyl) derivatives of thiophene and furan. Synth Commun 13:121CrossRef
38.
Heeney M, Bailey C, Genevicius K, Shkunov M, Sparrowe D, Tierney S, McCulloch I (2005) Stable polythiophene semiconductors incorporating thieno[2,3-b]thiophene. J Am Chem Soc 127:1078CrossRef
39.
Li YF, Cao Y, Gao J, Wang DL, Yu G, Heeger AJ (1999) Electrochemical properties of luminescent polymers and polymer light-emitting electrochemical cells. Synth Met 99:243CrossRef
40.
Sun QJ, Wang HQ, Yang CH, Li YF (2003) Synthesis and electroluminescence of novel copolymers containing crown ether spacers. J Mater Chem 13:800CrossRef
41.
Hou JH, Tan ZA, Yan Y, He YJ, Yang CH, Li YF (2006) Synthesis and photovoltaic properties of two-dimensional conjugated polythiophenes with bi(thienylenevinylene) side chains. J Am Chem Soc 128:4911CrossRef
42.
Johansson T, Mammo W, Svensson M, Andersson MR, Inganas O (2003) Electrochemical bandgaps of substituted polythiophenes. J Mater Chem 13:1316CrossRef
43.
Chen WC, Liu CL, Yen CT, Tsai FC, Tonzola CJ, Olson N, Jenekhe SA (2004) Theoretical and experimental characterization of small band gap poly(3,4-ethylenedioxythiophene methine)s. Macromolecules 37:5959CrossRef
Metadaten
Titel
Synthesis and photovoltaic properties of alternative copolymers of benzo[1,2-b:4,5-b′]dithiophene and thiophene
verfasst von
Jie Min
Bo Peng
Youjun He
Maojie Zhang
Zhi-Guo Zhang
Jing Zhang
Xia Guo
Chaohua Cui
Dan Deng
Yongfang Li
Publikationsdatum
01.05.2012
Verlag
Springer-Verlag
Erschienen in
Polymer Bulletin / Ausgabe 8/2012
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-011-0672-z

Weitere Artikel der Ausgabe 8/2012

Polymer Bulletin 8/2012 Zur Ausgabe

Original Paper

Morphological characterization of branched PP under stretching

Original Paper

Star-branched cationic light-emitting dot with silsesquioxane core, synthesis, and light scattering studies

Original Paper

Nanosized colloidal particles from thermosensitive poly(methoxydiethyleneglycol methacrylate)s in aqueous media

Original Paper

Improving rheological properties of covalently MWCNT/epoxy nanocomposites via surface re-modification

Original Paper

The influence of additive property on performance of organic bulk heterojunction solar cells

Original Paper

Studies on fast functionalization of HDPE by ultraviolet irradiation and functionalized HDPE/CaCO3 composites

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise