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09.02.2016 | Original Paper

Structure–property relationship of new polyimide–organically modified silicate–phosphotungstic acid hybrid material system

verfasst von: Fábio A. S. Ferreira, Thiago Amaral, Orlando Armando Elguera Ysnaga, Marcelo A. Pereira-da-Silva, José H. Lopes, James P. Lewicki, Marcus A. Worsley, José F. Schneider, Germano Tremiliosi-Filho, Ubirajara P. Rodrigues-Filho

Erschienen in: Journal of Materials Science | Ausgabe 10/2016

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Abstract

A new hybrid material system was successfully developed from the combination of polyimide (PI), organically modified silicate (ORMOSIL), and phosphotungstic acid (HPW) from polycondensation reactions and sol–gel process. The materials were obtained in the form of flexible and free-standing films, with the formation of PI and ORMOSIL network confirmed by Fourier transform infrared. Solid-state phosphorus-31 nuclear magnetic resonance evaluated the HPW structure and confirmed its presence and also structural integrity in the materials after synthesis procedure. Thermogravimetric analysis revealed that the materials were thermally stable up to 773 K, and scanning electron microscopy images and X-ray micro-fluorescence mapping showed very good compatibility between the organic and inorganic phases with ORMOSIL improving the HPW dispersion. Furthermore, both ORMOSIL and HPW enhanced the permittivity of the materials from 2.5 to 4.3, compared to the neat PI, appointing them as potential candidates for electric and electronic applications.

Vorheriger Artikel The formation of crystalline phases in metakaolin-based geopolymers in the presence of sodium nitrate

Nächster Artikel Clean preparation of tailored microcellular foams of polystyrene using nucleating agents and supercritical CO2

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Kickelbick G (2003) Concepts for the incorporation of inorganic building blocks into organic polymers on a nanoscale. Prog Polym Sci 28:83–114. doi:10.1016/S0079-6700(02)00019-9 CrossRef

Sanchez C, Shea KJ, Kitagawa S (2011) Hybrid materials themed issue. Chem Soc Rev 40:696–753. doi:10.1039/C0CS00136H CrossRef

Liaw D-J, Wang K-L, Huang Y-C et al (2012) Advanced polyimide materials: syntheses, physical properties and applications. Prog Polym Sci 37:907–974. doi:10.1016/j.progpolymsci.2012.02.005 CrossRef

Morikawa A, Yamaguchi H, Kakimoto M, Imaj Y (1994) Formation of interconnected globular structure of silica phase in polyimide-silica hybrid films prepared by the sol-gel process. Chem Mater 6:913–917. doi:10.1021/cm00043a009 CrossRef

Tripathi VS, Kandimalla VB, Ju H (2006) Preparation of ormosil and its applications in the immobilizing biomolecules. Sensors Actuators B 114:1071–1082. doi:10.1016/j.snb.2005.07.037 CrossRef

Mackenzie JD, Bescher EP (1998) Structures, properties and potential applications of ormosils. J Sol Gel Sci Technol 13:371–377CrossRef

Ahmad Z, Al Sagheer F, Al Arbash A, Ali AAM (2009) Synthesis and characterization of chemically cross-linked polyimide–siloxane hybrid films. J Non-Cryst Solids 355:507–517. doi:10.1016/j.jnoncrysol.2009.01.019 CrossRef

Min C, Wu T, Yang W, Chen C (2008) Functionalized mesoporous silica/polyimide nanocomposite thin films with improved mechanical properties and low dielectric constant. Compos Sci Technol 68:1570–1578. doi:10.1016/j.compscitech.2007.09.021 CrossRef

Kim Y, Kang E, Kwon YS, Korea S (1997) Electrical properties of silica-polyimide composite dielectric thin Ghns prepared via sol-gel reaction and thermal imidization. Synth Met 85:1399–1400. doi:10.1016/S0379-6779(97)80291-3 CrossRef

10.

Tsai M, Whang W (2001) Low dielectric polyimide/poly (silsesquioxane)-like nanocomposite material. Polymer (Guildf) 42:4197–4207. doi:10.1016/S0379-6779(97)80291-3 CrossRef

11.

Deng H, Lin L, Ji M et al (2014) Progress on the morphological control of conductive network in conductive polymer composites and the use as electroactive multifunctional materials. Prog Polym Sci 39:627–655. doi:10.1016/j.progpolymsci.2013.07.007 CrossRef

12.

Gao H, Tian Q, Lian K (2010) Polyvinyl alcohol-heteropoly acid polymer electrolytes and their applications in electrochemical capacitors. Solid State Ionics 181:874–876. doi:10.1016/j.ssi.2010.05.006 CrossRef

13.

Maranas JK (2012) Polymers for energy storage and delivery: polyelectrolytes for batteries and fuel cells. ACS Symp Series. doi:10.1021/bk-2012-1096

14.

Suppes GM, Cameron CG, Freund MS (2010) A polypyrrole/phosphomolybdic acid|poly(3,4-ethylenedioxythiophene)/phosphotungstic acid asymmetric supercapacitor. J Electrochem Soc 157:A1030. doi:10.1149/1.3464802 CrossRef

15.

Cuentas-Gallegos AK, Lira-Cantú M, Casañ-Pastor N, Gómez-Romero P (2005) Nanocomposite hybrid molecular materials for application in solid-state electrochemical supercapacitors. Adv Funct Mater 15:1125–1133. doi:10.1002/adfm.200400326 CrossRef

16.

Venkat N, Dang TD, Bai Z et al (2010) High temperature polymer film dielectrics for aerospace power conditioning capacitor applications. Mater Sci Eng B 168:16–21. doi:10.1016/j.mseb.2009.12.038 CrossRef

17.

López X, Carbó JJ, Bo C, Poblet JM (2012) Structure, properties and reactivity of polyoxometalates: a theoretical perspective. Chem Soc Rev 41:7537–7571. doi:10.1039/c2cs35168d CrossRef

18.

Coronado E, Gómez-García CJ (1998) Polyoxometalate-based molecular materials. Chem Rev 98:273–296. doi:10.1021/cr970471c CrossRef

19.

Dolbecq A, Dumas E, Mayer CR, Mialane P (2010) Hybrid organic-inorganic polyoxometalate compounds: from structural diversity to applications. Chem Rev 110:6009–6048. doi:10.1021/cr1000578 CrossRef

20.

Mastikhin VM, Kulikov SM, Nosov AV et al (1990) 1H and 31P MAS NMR studies of solid heteropolyacids and H3PW12O40 supported on SiO₂. J Mol Catal 60:65–70. doi:10.1016/0304-5102(90)85068-S CrossRef

21.

Micek-Ilnicka A (2009) The role of water in the catalysis on solid heteropolyacids. J Mol Catal A 308:1–14. doi:10.1016/j.molcata.2009.04.003 CrossRef

22.

Katsoulis DE (1998) A survey of applications of polyoxometalates. Chem Rev 98:359–388CrossRef

23.

Solé VA, Papillon E, Cotte M et al (2007) A multiplatform code for the analysis of energy-dispersive X-ray fluorescence spectra. Spectrochim Acta B 62:63–68. doi:10.1016/j.sab.2006.12.002 CrossRef

24.

Chang C, Chen W (2002) Synthesis and optical properties of polyimide-silica hybrid thin films. Chem Mater 14:4242–4248CrossRef

25.

Chen Y, Iroh JO (1999) Synthesis and characterization of polyimide/silica hybrid composites. Chem Mater 11:1218–1222CrossRef

26.

Son M, Ha Y, Choi M-C et al (2008) Microstructure and properties of polyamideimide/silica hybrids compatibilized with 3-aminopropyltriethoxysilane. Eur Polym J 44:2236–2243. doi:10.1016/j.eurpolymj.2008.04.037 CrossRef

27.

Son M, Han S, Han D et al (2008) Organic/inorganic hybrid composite films from polyimide and organosilica: effect of the type of organosilica precursors. Polym Bull 60:713–723. doi:10.1007/s00289-008-0904-z CrossRef

28.

Bhure MH, Kumar I, Natu AD et al (2008) Phosphotungstic acid on silica with modified acid sites as a solid catalyst for selective cleavage of tert-butyldimethylsilyl ethers. Catal Commun 9:1863–1868. doi:10.1016/j.catcom.2008.03.017 CrossRef

29.

De Oliveira M, de Souza AL, Schneider J, Rodrigues-Filho UP (2011) Local structure and photochromic response in ormosils containing dodecatungstophosphoric acid. Chem Mater 23:953–963. doi:10.1021/cm1022272 CrossRef

30.

Snyder RW, Thomson B, Bartges B et al (1989) FTIR studies of polyimides: thermal curing. Macromolecules 22:4166–4172. doi:10.1021/ma00201a006 CrossRef

31.

Shin TJ, Lee B, Youn HS et al (2001) Time-resolved synchrotron X-ray diffraction and infrared spectroscopic studies of imidization and structural evolution in a microscaled film of PMDA-3,4′-ODA poly(amic acid). Langmuir 17:7842–7850. doi:10.1021/la0108656 CrossRef

32.

Diaham S, Locatelli ML, Lebey T, Malec D (2011) Thermal imidization optimization of polyimide thin films using Fourier transform infrared spectroscopy and electrical measurements. Thin Solid Films 519:1851–1856. doi:10.1016/j.tsf.2010.10.031 CrossRef

33.

Bridgeman AJ (2003) Density functional study of the vibrational frequencies of Keggin heteropolyanions. Chem Phys 287:55–69. doi:10.1016/S0301-0104(02)00978-3 CrossRef

34.

De Oliveira M, Rodrigues-Filho UP, Schneider J (2014) Thermal transformations and proton species in 12-phosphotungstic acid hexahydrate studied by 1 H and 31 P solid-state nuclear magnetic resonance. J Phys Chem C 118:11573–11583. doi:10.1021/jp501887x CrossRef

35.

Essayem N, Tong YY, Jobic H, Vedrine JC (2000) Characterization of protonic sites in H 3 PW 12 O 40 and Cs 1.9 H 1.1 PW 12 O 40: a solid-state 1 H, 2 H, 31 P MAS-NMR and inelastic neutron scattering study on samples prepared under standard reaction conditions. Appl Catal A 195:109–122CrossRef

36.

Deleplanque J, Hubaut R, Bodart P et al (2009) 1H and 31P solid-state NMR of trimethylphosphine adsorbed on heteropolytungstate supported on silica. Appl Surf Sci 255:4897–4901. doi:10.1016/j.apsusc.2008.12.031 CrossRef

37.

Bragg HW (1913) The reflection of X-rays by crystals. R Soc 17:43

38.

Perrin FX (2011) Linear and branched alkyl substituted octakis(dimethylsiloxy)octasilsesquioxanes: WAXS and thermal properties. Eur Polym J 47:1370–1382. doi:10.1016/j.eurpolymj.2011.04.004 CrossRef

39.

Ferreira-neto EP, Ullah S, De CF et al (2015) Preparation, characterization and photochromic behavior of phosphotungstic acid-ormosil nanocomposites. Mater Chem Phys 153:410–421CrossRef

40.

Jiang L, Wang W, Wei X et al (2007) Effects of water on the preparation, morphology, and properties of polyimide/silica nanocomposite films prepared by sol–gel process. J Appl Polym Sci 104:1579–1586. doi:10.1002/app.25692 CrossRef

41.

Celia JA (1992) Degradation and stability of polyimides. Polymer Degradation 36:99–110CrossRef

42.

Jeong S, Kim D, Lee S et al (2007) Organic thin-film transistors using thin ormosil-based hybrid dielectric. Thin Solid Films 515:7701–7705. doi:10.1016/j.tsf.2006.11.143 CrossRef

43.

Chisca S, Musteata VE, Sava I, Bruma M (2011) Dielectric behavior of some aromatic polyimide films. Eur Polym J 47:1186–1197. doi:10.1016/j.eurpolymj.2011.01.008 CrossRef

Titel: Structure–property relationship of new polyimide–organically modified silicate–phosphotungstic acid hybrid material system
verfasst von: Fábio A. S. Ferreira
Thiago Amaral
Orlando Armando Elguera Ysnaga
Marcelo A. Pereira-da-Silva
José H. Lopes
James P. Lewicki
Marcus A. Worsley
José F. Schneider
Germano Tremiliosi-Filho
Ubirajara P. Rodrigues-Filho
Publikationsdatum: 09.02.2016
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 10/2016
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-016-9773-2

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