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Polymer Bulletin
Erschienen in: Polymer Bulletin 7/2019

26.10.2018 | Original Paper

Studies on graphene oxide/BMI-reinforced polybenzoxazine nanocomposites

verfasst von: P. Thirukumaran, A. Shakila Parveen, R. Balasubramanian, V. Ramkumar, A. Selvamani, V. V. Srinivasan, C. M. Babu, Seong-Cheol Kim

Erschienen in: Polymer Bulletin | Ausgabe 7/2019

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Abstract

Polybenzoxazine (PBz)/BMI/reduced graphene oxide (rGO) nanocomposites were prepared by varying the weight percentage of rGO from 1 to 5 wt%. The exfoliated sheet morphology of rGO makes it well-dispersed in the PBz/BMI matrix. The curing process monitored by DSC analysis showed two exothermic curves. Of which one is due to the reaction between BMI and furan ring and the other due to ring-opening polymerization. The nanocomposites did not show any agglomeration even at higher loadings (5 wt%) of rGO nanofillers. The degree of dispersion of rGO nanofillers resulted in enhancement of mechanical and thermal properties of PBz/BMI/rGO nanocomposites. A very low percentage of the nanofillers of about 5 wt% could tremendously increase the thermal stability, storage modulus and dielectric properties of the nanocomposites.
Vorheriger Artikel Synergistic effects of plant extracts and polymers on structural and antibacterial properties for wound healing
Nächster Artikel Synthesis and characterization of rigid polyurethane foam with dimer fatty acid-based polyols

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Literatur
1.
Yusuf Y, Baris K, Narendra Nath G (2009) Recent advancement on polybenzoxazine: a newly developed high performance thermoset. J Polym Sci Part A Polym Chem 47:5565–5576CrossRef
2.
Holly FW, Cope AC (1944) Condensation products of aldehydes and ketones with o-aminobenzyl alcohol and o-hydroxybenzylamine. J Am Chem Soc 66:1875–1879CrossRef
3.
Liu Y, Yue Z, Gao J (2010) Synthesis characterization and thermally activated polymerization behavior of bisphenol-S/aniline based benzoxazine. Polymer 51:3722–3729CrossRef
4.
Santhoshkumar KS, Regunadhan Nair CP (2010) Polybenzoxazines: chemistry and properties. Shrewsbury, Smithers Rapra Technology
5.
Jin L, Agag T, Ishida H (2010) Bis(benzoxazine-maleimide)s as a novel class of high performance resin: synthesis and properties. Eur Polym J 46:354–563CrossRef
6.
Liu YL, Hsu CW, Chou CI (2007) Silicon-containing benzoxazines and their polymers: copolymerization and copolymer properties. J Polym Sci Part A Polym Chem 45:1007–1015CrossRef
7.
Thirukumaran P, Shakila Parveen A, Sarojadevi M (2014) Synthesis and characterization of novel bio-based benzoxazines from eugenol. RSC Adv 4:7959–7966CrossRef
8.
Takeichi T, Kawauchi T, Agag T (2008) High performance polybenzoxazines as a novel type of phenolic resin. Polym J 40:1121–1131CrossRef
9.
Dumas L, Bonnaud L, Olivier M, Poorteman M, Dubois P (2016) Arbutin-based benzoxazine: en route to an intrinsic water soluble biobased resin. Green Chem 18:4954–4960CrossRef
10.
Calo E, Maffezzoli A, Mele G, Martina F, Mazzetto SE, Tarzia A, Stifani C (2007) Synthesis of a novel cardanol-based benzoxazine monomer and environmentally sustainable production of polymers and bio-composites. Green Chem 9:754–759CrossRef
11.
Lu Y, Li M, Zhang Y, Hu D, Ke L, Xu W (2011) Synthesis and curing kinetics of benzoxazine containing fluorene and furan groups. Thermochim Acta 515:32–37CrossRef
12.
Sini NK, Bijwe J, Varma IK (2014) Renewable benzoxazine monomer from Vanillin: synthesis, characterization, and studies on curing behavior. J Polym Sci Part A Polym Chem 52:7–11CrossRef
13.
Zúñiga C, Lligadas G, Ronda JC, Galià M, Cádiz V (2012) Renewable polybenzoxazines based in diphenolic acid. Polymer 53:1617–1623CrossRef
14.
Wang C, Sun J, Liu X, Sudo A, Endo T (2012) Synthesis and copolymerization of fully bio-based benzoxazines from guaiacol, furfurylamine and stearylamine. Green Chem 14:2799–2806CrossRef
15.
Dumas L, Bonnaud L, Olivier M, Poorteman M, Dubois P (2015) Eugenol-based benzoxazine: from straight synthesis to taming of the network properties. J Mater Chem A 3:6012–6018CrossRef
16.
Thirukumaran P, Shakila Parveen A, Sarojadevi M, Kim SC (2016) Replacing bisphenol-A with bisguaiacol-F to synthesize polybenzoxazines for a pollution-free environment. New J Chem 40:9313–9319CrossRef
17.
Alhassan SM, Qutubuddin S, Schiraldi DA, Agag T, Ishida H (2013) Preparation and thermal properties of graphene oxide/main chain benzoxazine polymer. Eur Polymer J 49:3825–3833CrossRef
18.
Meng F, Ishida H, Liu X (2014) Introduction of benzoxazine onto the grapheme oxide surface by click chemistry and the properties of graphene oxide reinforced polybenzoxazine nanohybrids. RSC Adv 4:9471–9475CrossRef
19.
Du X, Zhou H, Sun W, Liu HY, Zhou G, Zhou H, Mai YW (2017) Graphene/epoxy interleaves for delamination toughening and monitoring of crack damage in carbon fibre/epoxy composite laminates. Compos Sci Technol 140:123–133CrossRef
20.
Xing W, Li H, Huang G, Cai LH, Wu J (2017) Graphene oxide induced crosslinking and reinforcement of elastomers. Compos Sci Technol 144:223–229CrossRef
21.
Hernandez ED, Bassett AW, Sadler JM, La Scala JJ, Stanzione JF (2016) Synthesis and characterization of bio-based epoxy resins derived from vanillyl alcohol. ACS Sustain Chem Eng 4:4328–4339CrossRef
22.
Hong H, Harvey BG, Palmese GR, Stanzione JF, Ng HW, Sakkiah S, Tong W, Sadler JM (2016) Experimental data extraction and in silico prediction of the estrogenic activity of renewable replacements for bisphenol A. Int J Environ Res Public Health 13(705):1–16
23.
Hummers WS, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80:1339CrossRef
24.
Thirukumaran P, Shakila Parveen A, Sarojadevi M (2014) Synthesis and copolymerization of fully biobased benzoxazines from renewable resources. ACS Sustain Chem Eng 2:2790–2801CrossRef
25.
Agag T, Takeichi T (2003) Synthesis and characterization of novel benzoxazine monomers containing allyl groups and their high performance thermosets. Macromolecules 36:6010–6017CrossRef
26.
Li S, Yan S, Yu J, Yu B (2011) Synthesis and characterization of new benzoxazine-based phenolic resins from renewable resources and the properties of their polymers. J Appl Polym Sci 122:2843–2848CrossRef
27.
Dumas L, Bonnaud L, Olivier M, Poorteman M, Dubois P (2015) Bio-based high performance thermosets: stabilization and reinforcement of eugenol-based benzoxazine networks with BMI and CNT. Eur Polym J 67:494–502CrossRef
28.
Santhosh Kumar KS, Reghunadhan Nair CP, Sadhana R, Ninan KN (2007) Benzoxazine–bismaleimide blends: curing and thermal properties. Eur Polym J 43:5084–5096CrossRef
29.
Dumas L, Bonnaud L, Olivier M, Poorteman M, Dubois P (2014) High performance benzoxazine/CNT nanohybrid network—an easy and scalable way to combine attractive properties. Eur Polym J 58:218–225CrossRef
30.
Ke L, Hu D, Lu Y, Feng S, Xie Y, Xu W (2012) Copolymerization of maleimide-based benzoxazine with styrene and the curing kinetics of the resultant copolymer. Polym Degrad Stab 97:132–138CrossRef
31.
Zeng M, Wang J, Li R, Liu J, Chen W, Xu Q, Gu Y (2013) The curing behavior and thermal property of graphene oxide/benzoxazine nanocomposites. Polymer 54:3107–3116CrossRef
32.
Liu C, Ye S, Feng J (2017) Promoting the dispersion of graphene and crystallization of poly (lactic acid) with a freezing-dried graphene/PEG masterbatch. Compos Sci Technol 144:215–222CrossRef
33.
Zhang Y, Lin G (2017) Wu, Polylactide-based nanocomposites with stereocomplex networks enhanced by GO-g-PDLA Dongge. Compos Sci Technol 138:57–67CrossRef
34.
Wan YJ, Zhu PL, Yu SH, Yang WH, Sun R, Wong CP, Liao WH (2017) Barium titanate coated and thermally reduced graphene oxide towards high dielectric constant and low loss of polymeric composites. Compos Sci Technol 141:48–55CrossRef
35.
Li M, Huang X, Wu C, Xu H, Jiang P, Tanaka T (2012) Fabrication of two-dimensional hybrid sheets by decorating insulating PANI on reduced graphene oxide for polymer nanocomposites with low dielectric loss and high dielectric constant. J Mater Chem 22:23477–23484CrossRef
36.
Luo S, Yu S, Sun R, Wong CP (2014) Nano Ag-deposited BaTiO3 hybrid particles as fillers for polymeric dielectric composites: toward high dielectric constant and suppressed loss. ACS Appl Mater Interfaces 6:176–182CrossRefPubMed
37.
Biru I, Damian CM, Gârea SA, Iovu H (2016) Benzoxazine-functionalized graphene oxide for synthesis of new nanocomposites. Eur Polym J 83:244–255CrossRef
38.
Alhwaige AA, Alhassan SM, Katsiotis MS, Ishida H, Qutubuddin S (2015) Interactions, morphology and thermal stability of graphene-oxide reinforced polymer aerogels derived from star-like telechelic aldehyde-terminal benzoxazine resin. RSC Adv 5:92719–92731CrossRef
39.
Xu Q, Zeng M, Feng Z, Yin D, Huang Y, Chen Y, Yan C, Lia R, Gu Y (2016) Understanding the effects of carboxylated groups of functionalized graphene oxide on the curing behavior and intermolecular interactions of benzoxazine nanocomposites. RSC Adv 6:31484–31496CrossRef
40.
Mythili CV, Retna AM, Gopalakrishnan S (2004) Synthesis, mechanical, thermal and chemical properties of polyurethanes based on cardanol. Bull Mater Sci 27:235–241CrossRef
41.
Isikgora FH, Becer CR (2015) Lignocellulosic biomass: a sustainable platform for the production of bio-based chemicals and polymers. Polym. Chem. 6:4497–4559CrossRef
Metadaten
Titel
Studies on graphene oxide/BMI-reinforced polybenzoxazine nanocomposites
verfasst von
P. Thirukumaran
A. Shakila Parveen
R. Balasubramanian
V. Ramkumar
A. Selvamani
V. V. Srinivasan
C. M. Babu
Seong-Cheol Kim
Publikationsdatum
26.10.2018
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 7/2019
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-018-2573-x

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