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Erschienen in: Cellulose 3/2013

01.06.2013 | Original Paper

Superelastic percolation network of polyacrylamide (PAAm)–kappa carrageenan (κC) composite

verfasst von: G. Akin Evingür, Ö. Pekcan

Erschienen in: Cellulose | Ausgabe 3/2013

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Abstract

The elasticity of the polyacrylamide (PAAm)-kappa carrageenan (κC) composite was determined as a function of (w/v-%) κC content at 40 °C. The gel composites studied contained various percentages (w/v-%) of κC. The elasticity of the swollen PAAm-κC composite was characterized by using the tensile testing technique. This study investigated the elasticity and the percolation threshold of PAAm-κC composite as a function of κC content. It is understood that the compressive elastic modulus decreases up to 1 (w/v-%) of κC and then increases at contents above 1(w/v-%) of κC. The critical exponent of elasticity y was determined between 1 and 1.6 (w/v-%) of κC and found to be 0.68. The observed elastic percolation threshold is consistent with the suggested values of the superelastic percolation network.

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Literatur
Zurück zum Zitat Aktaş DK, Evingür GA, Pekcan Ö (2006) Universal behaviour of gel formation from acrylamide-carrageenan mixture around the gel point: a fluorescence study. J Biomol Struct Dyn 24(1):83–90CrossRef Aktaş DK, Evingür GA, Pekcan Ö (2006) Universal behaviour of gel formation from acrylamide-carrageenan mixture around the gel point: a fluorescence study. J Biomol Struct Dyn 24(1):83–90CrossRef
Zurück zum Zitat Anseth KS, Bowman CN, Peppas LB (1996) Mechanical properties of hydrogels and their experimental determination. Biomaterials 17:1647–1657CrossRef Anseth KS, Bowman CN, Peppas LB (1996) Mechanical properties of hydrogels and their experimental determination. Biomaterials 17:1647–1657CrossRef
Zurück zum Zitat Arbabi S, Sahimi M (1993) Mechanics of disordered solids. I. percolation on elastic networks with central forces. Phys Rev B 47(2):695–702CrossRef Arbabi S, Sahimi M (1993) Mechanics of disordered solids. I. percolation on elastic networks with central forces. Phys Rev B 47(2):695–702CrossRef
Zurück zum Zitat Berkowitz B, Balberg I (1993) Percolation theory and its application to groundwater hydrology. Water Res 29(4):775–794CrossRef Berkowitz B, Balberg I (1993) Percolation theory and its application to groundwater hydrology. Water Res 29(4):775–794CrossRef
Zurück zum Zitat Çakır E, Foegeding EA (2011) Combining protein micro protein micro phase separation and protein-polysaccharide segregative phase separation to produce gel structures. Food Hydrocoll 25:1538–1546CrossRef Çakır E, Foegeding EA (2011) Combining protein micro protein micro phase separation and protein-polysaccharide segregative phase separation to produce gel structures. Food Hydrocoll 25:1538–1546CrossRef
Zurück zum Zitat Colby RH, Gillmor JR, Rubinstein M (1993) Dynamics of near critical polymer gels. Phys Rev E 48(5):3712–3716CrossRef Colby RH, Gillmor JR, Rubinstein M (1993) Dynamics of near critical polymer gels. Phys Rev E 48(5):3712–3716CrossRef
Zurück zum Zitat de Gennes PG (1976) On the relation between percolation theory and the elasticity of gels. Le J de Phys Lett 37:L1–L2CrossRef de Gennes PG (1976) On the relation between percolation theory and the elasticity of gels. Le J de Phys Lett 37:L1–L2CrossRef
Zurück zum Zitat Erman B, Flory PJ (1986) Critical phenomena and transitions in swollen polymer networks and in linear macromolecules. Macromol 19:2342–2353CrossRef Erman B, Flory PJ (1986) Critical phenomena and transitions in swollen polymer networks and in linear macromolecules. Macromol 19:2342–2353CrossRef
Zurück zum Zitat Evingür GA, Pekcan Ö (2011) Drying of polyacrylamide composite gels formed with various kappa carrageenan content. J Fluo 21:1531–1537CrossRef Evingür GA, Pekcan Ö (2011) Drying of polyacrylamide composite gels formed with various kappa carrageenan content. J Fluo 21:1531–1537CrossRef
Zurück zum Zitat Evingür GA, Pekcan Ö (2012a) Elastic percolation of swollen polyacrylamide (PAAm)-multiwall carbon nanotubes (MWNTs) composite. Ph Transitions 85:553–564CrossRef Evingür GA, Pekcan Ö (2012a) Elastic percolation of swollen polyacrylamide (PAAm)-multiwall carbon nanotubes (MWNTs) composite. Ph Transitions 85:553–564CrossRef
Zurück zum Zitat Evingür GA, Pekcan Ö (2012b) Temperature effect on the swelling of PAAm–kcarrageenan composites. J Appl Polym Sci 123:1746–1754CrossRef Evingür GA, Pekcan Ö (2012b) Temperature effect on the swelling of PAAm–kcarrageenan composites. J Appl Polym Sci 123:1746–1754CrossRef
Zurück zum Zitat Feng S, Sen PN (1984) Percolation on elastic networks: new exponent and threshold. Phys Rev Lett 52(3):216–219CrossRef Feng S, Sen PN (1984) Percolation on elastic networks: new exponent and threshold. Phys Rev Lett 52(3):216–219CrossRef
Zurück zum Zitat Friedrich K, Fakirov S, Zhang Z (2005) Polymer composites from nano to macro scale. Springer, USA Friedrich K, Fakirov S, Zhang Z (2005) Polymer composites from nano to macro scale. Springer, USA
Zurück zum Zitat Kantor Y, Webman I (1984) Elastic properties of random percolating systems. Phys Rev Lett 52(21):1891–1894CrossRef Kantor Y, Webman I (1984) Elastic properties of random percolating systems. Phys Rev Lett 52(21):1891–1894CrossRef
Zurück zum Zitat Loret C, Ribelles P, Lundin L (2009) Mechanical properties of k-carrageenan in high concentration of sugar solutions. Food Hydrocoll 23:823–832CrossRef Loret C, Ribelles P, Lundin L (2009) Mechanical properties of k-carrageenan in high concentration of sugar solutions. Food Hydrocoll 23:823–832CrossRef
Zurück zum Zitat Muniz EC, Geuskens G (2001) Compressive elastic modulus of polyacrylamide hydrogels and semi-IPN’s with poly (N-isoproplacrylamide). Macromolecules 34:4480–4484 Muniz EC, Geuskens G (2001) Compressive elastic modulus of polyacrylamide hydrogels and semi-IPN’s with poly (N-isoproplacrylamide). Macromolecules 34:4480–4484
Zurück zum Zitat Nielsen LE, Lawrence RF (1994) Mechanical properties of polymers and composites. Marcel Dekker, New York Nielsen LE, Lawrence RF (1994) Mechanical properties of polymers and composites. Marcel Dekker, New York
Zurück zum Zitat Rubinstein RH, Colby H (1994) Elastic modulus and equilibrium swelling of near critical gels. Macromolecules 27:3184–3190CrossRef Rubinstein RH, Colby H (1994) Elastic modulus and equilibrium swelling of near critical gels. Macromolecules 27:3184–3190CrossRef
Zurück zum Zitat Sahimi M (1994) Application of percolation theory. Taylor and Francis, London Sahimi M (1994) Application of percolation theory. Taylor and Francis, London
Zurück zum Zitat Schriemer HP, Pachet NG, Page JH (1996) Ultrasonic investigation of the vibrational modes of a sintered glass-bead percolation system. Waves Random Media 6:361–386CrossRef Schriemer HP, Pachet NG, Page JH (1996) Ultrasonic investigation of the vibrational modes of a sintered glass-bead percolation system. Waves Random Media 6:361–386CrossRef
Zurück zum Zitat Spagnol C, Rodrigues FHA, Pereira AGB, Fajardo AR, Rubira AF, Muniz EC (2012a) Superabsorbent hydrogel composite made of cellulose nanofibrils and chitosan-graft-poly (acrylic acid). Carbohydr Polym 87(3):2038–2045CrossRef Spagnol C, Rodrigues FHA, Pereira AGB, Fajardo AR, Rubira AF, Muniz EC (2012a) Superabsorbent hydrogel composite made of cellulose nanofibrils and chitosan-graft-poly (acrylic acid). Carbohydr Polym 87(3):2038–2045CrossRef
Zurück zum Zitat Spagnol C, Rodrigues FHA, Pereira AGB, Fajardo AR, Rubira AF, Muniz EC (2012b) Superabsorbent hydrogel nanocomposites based on starch-g-poly(sodium acrylate) matrix filled with cellulose nanowhiskers. Cellulose 19(4):1225–1237CrossRef Spagnol C, Rodrigues FHA, Pereira AGB, Fajardo AR, Rubira AF, Muniz EC (2012b) Superabsorbent hydrogel nanocomposites based on starch-g-poly(sodium acrylate) matrix filled with cellulose nanowhiskers. Cellulose 19(4):1225–1237CrossRef
Metadaten
Titel
Superelastic percolation network of polyacrylamide (PAAm)–kappa carrageenan (κC) composite
verfasst von
G. Akin Evingür
Ö. Pekcan
Publikationsdatum
01.06.2013
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 3/2013
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-013-9903-9

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