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Polymer Bulletin
Erschienen in: Polymer Bulletin 8/2018

31.10.2017 | Original Paper

Surface functionalization of graphene oxide with octadecylamine for improved thermal and mechanical properties in polybutylene succinate nanocomposite

verfasst von: Anis Sakinah Zainal Abidin, Kamal Yusoh, Shaidatul Shima Jamari, Abu Hannifa Abdullah, Zulhelmi Ismail

Erschienen in: Polymer Bulletin | Ausgabe 8/2018

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Abstract

Modification of graphene oxide (GO) with long-chain aliphatic amine offers a substantial improvement in high-performance polymer as nanofiller in the composite. In this work, graphene oxide was functionalized with octadecylamine via sonochemical exfoliation method producing mono- to few-layer graphene oxide/octadecylamine (GOODA) nanofiller. Biodegradable polybutylene succinate (PBS) was incorporated with GOODA via solution intercalation method. GOODA does not profoundly affect the crystallinity of PBS/GOODA nanocomposite, but interestingly improves the mechanical and thermal properties. The addition of only 0.1 wt% GOODA nanofiller loading exhibited a sharp increase in tensile strength and Young’s modulus of up to 50 and 58.9%, respectively. The improvement in strength and thermal behavior could be attributed to the successful interfacial interaction between amine group in GOODA and carboxylic group in PBS chain tail via nucleophilic substitution reaction. This improved interphase structure enhanced the dispersion and exfoliation of GOODA in PBS matrix.
Vorheriger Artikel Thermal degradation, dynamic mechanical and morphological properties of PVC stabilized with natural polyphenol-based epoxy resin
Nächster Artikel A powerful tool for preparing peripherally post-functionalized multiarm star block copolymer

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Metadaten
Titel
Surface functionalization of graphene oxide with octadecylamine for improved thermal and mechanical properties in polybutylene succinate nanocomposite
verfasst von
Anis Sakinah Zainal Abidin
Kamal Yusoh
Shaidatul Shima Jamari
Abu Hannifa Abdullah
Zulhelmi Ismail
Publikationsdatum
31.10.2017
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 8/2018
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-017-2217-6

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