Skip to main content
Erschienen in: Cellulose 7/2017

12.05.2017 | Original Paper

Surface modification of PCC filled cellulose paper by MOF-5 (Zn3(BDC)2) metal–organic frameworks for use as soft gas adsorption composite materials

verfasst von: Qiang Yang, Meiyun Zhang, Shunxi Song, Bin Yang

Erschienen in: Cellulose | Ausgabe 7/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

In this paper, composite materials made of cellulose paper and MOF-5 (Zn3(BDC)2) Metal organic frameworks (paper@MOF-5) materials, were prepared by an in situ synthesis method using precipitated calcium carbonate (PCC) filled cellulose papers. PCC fillers in the cellulose paper led to decreased inter-fiber bonds, thus facilitating the formation of small-sized MOF-5 crystals. The resultant cellulose paper@MOF-5 composites exhibited zeolite-like frameworks with high specific surface areas. The composite materials were characterized by XRD, ATR-FTIR, SEM and nitrogen adsorption analysis. The results supported the conclusion that the prepared cellulose paper@MOF-5 composite materials have great potential in gas (N2, CH4, H2, CO2, etc.) adsorption.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Literatur
Zurück zum Zitat Abbasi AR, Yousefshahi M, Azadbakht A (2016) Synthesis and characterization of azine-functionalized zinc cation metal–organic frameworks nanostructures upon silk fibers under ultrasound irradiation, study of pores effect on morphine adsorption affinity. Colloids Surf A Physicochem Eng Asp 498:58–65. doi:10.1016/j.colsurfa.2016.02.038 CrossRef Abbasi AR, Yousefshahi M, Azadbakht A (2016) Synthesis and characterization of azine-functionalized zinc cation metal–organic frameworks nanostructures upon silk fibers under ultrasound irradiation, study of pores effect on morphine adsorption affinity. Colloids Surf A Physicochem Eng Asp 498:58–65. doi:10.​1016/​j.​colsurfa.​2016.​02.​038 CrossRef
Zurück zum Zitat Aguado S, Canivet J, Farrusseng D (2010) Facile shaping of an imidazolate-based MOF on ceramic beads for adsorption and catalytic applications. Chem Commun 46:7999–8001. doi:10.1039/c0cc02045a CrossRef Aguado S, Canivet J, Farrusseng D (2010) Facile shaping of an imidazolate-based MOF on ceramic beads for adsorption and catalytic applications. Chem Commun 46:7999–8001. doi:10.​1039/​c0cc02045a CrossRef
Zurück zum Zitat Bae TH, Lee JS, Qiu W, Koros WJ, Jones CW, Nair S (2010) A high-performance gas-separation membrane containing submicrometer-sized metal–organic framework crystals. Angew Chem Int Ed Engl 49(51):9863–9866. doi:10.1002/anie.20100614 CrossRef Bae TH, Lee JS, Qiu W, Koros WJ, Jones CW, Nair S (2010) A high-performance gas-separation membrane containing submicrometer-sized metal–organic framework crystals. Angew Chem Int Ed Engl 49(51):9863–9866. doi:10.​1002/​anie.​20100614 CrossRef
Zurück zum Zitat Cheng T, Asano K, Duan Z et al (2014) Design and optimization of tellurite hybrid microstructured optical fiber with high nonlinearity and low flattened chromatic dispersion for optical parametric amplification. Opt Commun 318:105–111. doi:10.1016/j.optcom.2013.12.073 CrossRef Cheng T, Asano K, Duan Z et al (2014) Design and optimization of tellurite hybrid microstructured optical fiber with high nonlinearity and low flattened chromatic dispersion for optical parametric amplification. Opt Commun 318:105–111. doi:10.​1016/​j.​optcom.​2013.​12.​073 CrossRef
Zurück zum Zitat Cook TR, Zheng YR, Stang PJ (2013) Metal–organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal–organic materials. Chem Rev 113:734–777. doi:10.1021/cr3002824 CrossRef Cook TR, Zheng YR, Stang PJ (2013) Metal–organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal–organic materials. Chem Rev 113:734–777. doi:10.​1021/​cr3002824 CrossRef
Zurück zum Zitat da Silva Pinto M, Sierra-Avila CA, Hinestroza JP (2012) In situ synthesis of a Cu-BTC metal–organic framework (MOF-199) onto cellulosic fibrous substrates: cotton. Cellulose 19:1771–1779. doi:10.1007/s10570-012-9752-y CrossRef da Silva Pinto M, Sierra-Avila CA, Hinestroza JP (2012) In situ synthesis of a Cu-BTC metal–organic framework (MOF-199) onto cellulosic fibrous substrates: cotton. Cellulose 19:1771–1779. doi:10.​1007/​s10570-012-9752-y CrossRef
Zurück zum Zitat Fan J, Li T, Ren YZ, Qian XR, Wang QW, Shen J, Ni YH (2017) Interaction between two oppositely charged starches in an aqueous medium containing suspended mineral particles as a basis for the generation of cellulose-compatible composites. Ind Crop Prod 97:417–424. doi:10.1016/j.indcrop.2016.12.048 CrossRef Fan J, Li T, Ren YZ, Qian XR, Wang QW, Shen J, Ni YH (2017) Interaction between two oppositely charged starches in an aqueous medium containing suspended mineral particles as a basis for the generation of cellulose-compatible composites. Ind Crop Prod 97:417–424. doi:10.​1016/​j.​indcrop.​2016.​12.​048 CrossRef
Zurück zum Zitat Gándara F, Furukawa H, Lee S, Yaghi OM (2014) High methane storage capacity in aluminum metal–organic frameworks. J Am Chem Soc 136(14):5271–5274. doi:10.1021/ja501606h CrossRef Gándara F, Furukawa H, Lee S, Yaghi OM (2014) High methane storage capacity in aluminum metal–organic frameworks. J Am Chem Soc 136(14):5271–5274. doi:10.​1021/​ja501606h CrossRef
Zurück zum Zitat Gaudreault R, Di Cesare N, Van De Ven TGM, Weitz DA (2015) Structure and strength of flocs of precipitated calcium carbonate induced by various polymers used in papermaking. Ind Eng Chem Res 54:6234–6246. doi:10.1021/acs.iecr.5b00818 CrossRef Gaudreault R, Di Cesare N, Van De Ven TGM, Weitz DA (2015) Structure and strength of flocs of precipitated calcium carbonate induced by various polymers used in papermaking. Ind Eng Chem Res 54:6234–6246. doi:10.​1021/​acs.​iecr.​5b00818 CrossRef
Zurück zum Zitat Jahan MS, He Z, Ni Y (2010) Using precipitated calcium carbonate (PCC) as an alkali source in d1 and d2 brightening of a hardwood kraft pulp. Appita J 63(2):126–130 Jahan MS, He Z, Ni Y (2010) Using precipitated calcium carbonate (PCC) as an alkali source in d1 and d2 brightening of a hardwood kraft pulp. Appita J 63(2):126–130
Zurück zum Zitat Lange LE, Obendorf SK (2015) Functionalization of cotton fiber by partial etherification and self-assembly of polyoxometalate encapsulated in Cu3(BTC)2 metal–organic framework. ACS Appl Mater Interfaces 7:3974–3980. doi:10.1021/am506510q CrossRef Lange LE, Obendorf SK (2015) Functionalization of cotton fiber by partial etherification and self-assembly of polyoxometalate encapsulated in Cu3(BTC)2 metal–organic framework. ACS Appl Mater Interfaces 7:3974–3980. doi:10.​1021/​am506510q CrossRef
Zurück zum Zitat Laurila E, Thunberg J, Argent SP et al (2015) Enhanced synthesis of metal–organic frameworks on the surface of electrospun cellulose nanofibers. Adv Eng Mater 17:1282–1286. doi:10.1002/adem.201400565 CrossRef Laurila E, Thunberg J, Argent SP et al (2015) Enhanced synthesis of metal–organic frameworks on the surface of electrospun cellulose nanofibers. Adv Eng Mater 17:1282–1286. doi:10.​1002/​adem.​201400565 CrossRef
Zurück zum Zitat Liang X, Zhang F, Zhao H et al (2014) A proton-conducting lanthanide metal–organic framework integrated with a dielectric anomaly and second-order nonlinear optical effect. Chem Commun 50:6513–6516. doi:10.1039/C4CC00458B CrossRef Liang X, Zhang F, Zhao H et al (2014) A proton-conducting lanthanide metal–organic framework integrated with a dielectric anomaly and second-order nonlinear optical effect. Chem Commun 50:6513–6516. doi:10.​1039/​C4CC00458B CrossRef
Zurück zum Zitat Meilikhov M, Yusenko K, Schollmeyer E, Mayer C, Buschmann HJ, Fischer RA (2011) Stepwise deposition of metal organic frameworks on flexible synthetic polymer surfaces. Dalton Trans 40(40):4838–4841. doi:10.1039/c0dt01820a CrossRef Meilikhov M, Yusenko K, Schollmeyer E, Mayer C, Buschmann HJ, Fischer RA (2011) Stepwise deposition of metal organic frameworks on flexible synthetic polymer surfaces. Dalton Trans 40(40):4838–4841. doi:10.​1039/​c0dt01820a CrossRef
Zurück zum Zitat Na K, Choi KM, Yaghi OM, Somorjai GA (2014) Metal nanocrystals embedded in single nanocrystals of MOFs give unusual selectivity as heterogeneous catalysts. Nano Lett 14:5979–5983. doi:10.1021/nl503007h CrossRef Na K, Choi KM, Yaghi OM, Somorjai GA (2014) Metal nanocrystals embedded in single nanocrystals of MOFs give unusual selectivity as heterogeneous catalysts. Nano Lett 14:5979–5983. doi:10.​1021/​nl503007h CrossRef
Zurück zum Zitat Nan J, Dong X, Wang W et al (2011) Step-by-step seeding procedure for preparing HKUST-1 membrane on porous α-alumina support. Langmuir 27:4309–4312. doi:10.1021/la200103w CrossRef Nan J, Dong X, Wang W et al (2011) Step-by-step seeding procedure for preparing HKUST-1 membrane on porous α-alumina support. Langmuir 27:4309–4312. doi:10.​1021/​la200103w CrossRef
Zurück zum Zitat Sampson WW, Urquhart SJ (2008) The contribution of out-of-plane pore dimensions to the pore size distribution of paper and stochastic fibrous materials. J Porous Mater 15(4):411–417. doi:10.1007/s10934-006-9088-9 CrossRef Sampson WW, Urquhart SJ (2008) The contribution of out-of-plane pore dimensions to the pore size distribution of paper and stochastic fibrous materials. J Porous Mater 15(4):411–417. doi:10.​1007/​s10934-006-9088-9 CrossRef
Zurück zum Zitat Shi FN, Hu Y, Wang X, Sun X, Lu M, Shi G et al (2017) MOF decomposed for the preparation of nanoporous Co3O4 fibres and sheets with excellent microwave absorption and photocatalysis properties. Dalton Trans. doi:10.1039/C6DT04571E Shi FN, Hu Y, Wang X, Sun X, Lu M, Shi G et al (2017) MOF decomposed for the preparation of nanoporous Co3O4 fibres and sheets with excellent microwave absorption and photocatalysis properties. Dalton Trans. doi:10.​1039/​C6DT04571E
Zurück zum Zitat Song S, Zhang M, He Z et al (2012) Investigation on a novel fly ash based calcium silicate filler: effect of particle size on paper properties. Ind Eng Chem Res 51(50):16377–16384. doi:10.1021/ie3028813 CrossRef Song S, Zhang M, He Z et al (2012) Investigation on a novel fly ash based calcium silicate filler: effect of particle size on paper properties. Ind Eng Chem Res 51(50):16377–16384. doi:10.​1021/​ie3028813 CrossRef
Zurück zum Zitat Subramanian R, Fordsmand H, Paulapuro H (2007) Precipitated calcium carbonate (PCC)—cellulose composite fillers: effects of PCC particle structure on the production and properties of uncoated fine paper. BioRes 2(1):91–105 Subramanian R, Fordsmand H, Paulapuro H (2007) Precipitated calcium carbonate (PCC)—cellulose composite fillers: effects of PCC particle structure on the production and properties of uncoated fine paper. BioRes 2(1):91–105
Zurück zum Zitat Torad NL, Li Y, Ishihara S, Ariga K, Kamachi Y, Lian HY, Yamauchi Y (2014) MOF-derived nanoporous carbon as intracellular drug delivery carriers. Chem Lett 43(5):717–719. doi:10.1246/cl.131174 CrossRef Torad NL, Li Y, Ishihara S, Ariga K, Kamachi Y, Lian HY, Yamauchi Y (2014) MOF-derived nanoporous carbon as intracellular drug delivery carriers. Chem Lett 43(5):717–719. doi:10.​1246/​cl.​131174 CrossRef
Zurück zum Zitat Wang C, Qian X, An X (2015) In situ green preparation and antibacterial activity of copper-based metal–organic frameworks/cellulose fibers (HKUST-1/CF) composite. Cellulose 22:3789–3797. doi:10.1007/s10570-015-0754-4 CrossRef Wang C, Qian X, An X (2015) In situ green preparation and antibacterial activity of copper-based metal–organic frameworks/cellulose fibers (HKUST-1/CF) composite. Cellulose 22:3789–3797. doi:10.​1007/​s10570-015-0754-4 CrossRef
Zurück zum Zitat Wong-Foy AG, Matzger AJ, Yaghi OM (2006) Exceptional H2 saturation uptake in microporous metal–organic frameworks. J Am Chem Soc 128:3494–3495. doi:10.1021/ja058213h CrossRef Wong-Foy AG, Matzger AJ, Yaghi OM (2006) Exceptional H2 saturation uptake in microporous metal–organic frameworks. J Am Chem Soc 128:3494–3495. doi:10.​1021/​ja058213h CrossRef
Zurück zum Zitat Xiang S, He Y, Zhang Z, Wu H, Zhou W, Krishna R, Chen B (2012) Microporous metal–organic framework with potential for carbon dioxide capture at ambient conditions. Nat Commun 3:954–956. doi:10.1038/ncomms1956 CrossRef Xiang S, He Y, Zhang Z, Wu H, Zhou W, Krishna R, Chen B (2012) Microporous metal–organic framework with potential for carbon dioxide capture at ambient conditions. Nat Commun 3:954–956. doi:10.​1038/​ncomms1956 CrossRef
Zurück zum Zitat Yang S, Ramirez-Cuesta AJ, Newby R et al (2014) Supramolecular binding and separation of hydrocarbons within a functionalized porous metal–organic framework. Nat Chem 7:121–129. doi:10.1038/nchem.2114 CrossRef Yang S, Ramirez-Cuesta AJ, Newby R et al (2014) Supramolecular binding and separation of hydrocarbons within a functionalized porous metal–organic framework. Nat Chem 7:121–129. doi:10.​1038/​nchem.​2114 CrossRef
Zurück zum Zitat Zhang H, Hui L, Ni Y (2010a) Adsorption behaviors of optical brightening agents and precipitated calcium carbonate onto pulp fibers. Ind Eng Chem Res 49:9407–9412. doi:10.1021/ie1003976 CrossRef Zhang H, Hui L, Ni Y (2010a) Adsorption behaviors of optical brightening agents and precipitated calcium carbonate onto pulp fibers. Ind Eng Chem Res 49:9407–9412. doi:10.​1021/​ie1003976 CrossRef
Zurück zum Zitat Zhang H, Hu H, Hou Q, Ni Y (2010b) Effect of fines from high-yield pulp on filler retention and paper formation in fine paper production. J Biobased Mater Bioenergy 4(4):372–377. doi:10.1166/jbmb.2010.1103 CrossRef Zhang H, Hu H, Hou Q, Ni Y (2010b) Effect of fines from high-yield pulp on filler retention and paper formation in fine paper production. J Biobased Mater Bioenergy 4(4):372–377. doi:10.​1166/​jbmb.​2010.​1103 CrossRef
Zurück zum Zitat Zhang M, Song S, Wang J et al (2013) Using a novel fly ash based calcium silicate as a potential paper filler. BioRes 8:2768–2779 Zhang M, Song S, Wang J et al (2013) Using a novel fly ash based calcium silicate as a potential paper filler. BioRes 8:2768–2779
Zurück zum Zitat Zhang J-W, Zhang H-T, Du Z-Y et al (2014) Water-stable metal–organic frameworks with intrinsic peroxidase-like catalytic activity as a colorimetric biosensing platform. Chem Commun (Camb) 50:1092–1094. doi:10.1039/c3cc48398c CrossRef Zhang J-W, Zhang H-T, Du Z-Y et al (2014) Water-stable metal–organic frameworks with intrinsic peroxidase-like catalytic activity as a colorimetric biosensing platform. Chem Commun (Camb) 50:1092–1094. doi:10.​1039/​c3cc48398c CrossRef
Zurück zum Zitat Zhao J, Gong B, Nunn WT et al (2015) Conformal and highly adsorptive metal–organic framework thin films via layer-by-layer growth on ALD-coated fiber mats. J Mater Chem A 3:1458–1464. doi:10.1039/C4TA05501B CrossRef Zhao J, Gong B, Nunn WT et al (2015) Conformal and highly adsorptive metal–organic framework thin films via layer-by-layer growth on ALD-coated fiber mats. J Mater Chem A 3:1458–1464. doi:10.​1039/​C4TA05501B CrossRef
Zurück zum Zitat Zhu T, Yu K, Bhutto MA et al (2017) Synthesis of RGD-peptide modified poly(ester-urethane) urea electrospun nanofibers as a potential application for vascular tissue engineering. Chem Eng J 315:177–190. doi:10.1016/j.cej.2016.12.134 CrossRef Zhu T, Yu K, Bhutto MA et al (2017) Synthesis of RGD-peptide modified poly(ester-urethane) urea electrospun nanofibers as a potential application for vascular tissue engineering. Chem Eng J 315:177–190. doi:10.​1016/​j.​cej.​2016.​12.​134 CrossRef
Metadaten
Titel
Surface modification of PCC filled cellulose paper by MOF-5 (Zn3(BDC)2) metal–organic frameworks for use as soft gas adsorption composite materials
verfasst von
Qiang Yang
Meiyun Zhang
Shunxi Song
Bin Yang
Publikationsdatum
12.05.2017
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 7/2017
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-017-1331-9

Weitere Artikel der Ausgabe 7/2017

Cellulose 7/2017 Zur Ausgabe