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02.12.2021 | Original Research

Surfactant-free cellulose filaments stabilized oil in water emulsions

verfasst von: Amir Varamesh, Ragesh Prathapan, Ali Telmadarreie, Jia Li, Keith Gourlay, Gurminder Minhas, Qingye Lu, Steven L. Bryant, Jinguang Hu

Erschienen in: Cellulose | Ausgabe 2/2022

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Abstract

There has been significant interest over recent years in the production and application of sustainable and green materials. Among these, nanocellulose has incurred great interest because of its exceptional properties and wide range of potential applications, including in Pickering emulsions. However, the production cost of these cellulosic materials has limited their application. In this study, the capability of a new type of cheaper cellulosic material, cellulose filaments (CFs), in formulating stable oil in water Pickering emulsions was investigated and compared with three conventional nanocelluloses, namely cellulose nanocrystals (CNCs), cellulose nanofibrils (CNFs) and TEMPO-oxidized CNFs (TEMPO-CNFs). Results showed that CFs can provide stable surfactant-free emulsions over wide ranges of salt concentration (0–500 mM) and pH (2–10), as indicated by the near-constant oil droplet size and dewatering index of the emulsions. This is due to the ability of CFs to strongly adsorb to the oil and water interface, as evidenced by Cryo-SEM and visualized through labelled CFs with engineered carbohydrate-binding module (CBM2a) conjugated with green fluorescent protein (CBM2a-eGFP) under fluorescent microscopy. Compared to the emulsions stabilized by other types of nanocelluloses, the CF-stabilized emulsion demonstrated a larger average droplet size and comparable (with CNFs) or better (than CNCs and TEMPO-CNFs) stability, which is partially attributed to the higher viscosity of continuous phase in the presence of CFs. The results of this study demonstrate the use of CFs as a novel and cheaper cellulosic material for stabilizing emulsions, which opens the door to a range of markets from the food industry to engineering applications.

Graphical abstract

Vorheriger Artikel Protonation and dip-coating synergistically enhancing dimensional stability of multifunctional cellulose-based films

Nächster Artikel Remarkable durability of the antibacterial function achieved via a coordination effect of Cu(II) ion and chitosan grafted on cotton fibers

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Titel: Surfactant-free cellulose filaments stabilized oil in water emulsions
verfasst von: Amir Varamesh
Ragesh Prathapan
Ali Telmadarreie
Jia Li
Keith Gourlay
Gurminder Minhas
Qingye Lu
Steven L. Bryant
Jinguang Hu
Publikationsdatum: 02.12.2021
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 2/2022
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-021-04320-9

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