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07.12.2022 | Original Research

Synthesis and application of functionalized ionic liquids-based imidazolium as solvent for cotton fibre cellulose dissolution

verfasst von: Kaoutar Aghmih, Abderrahim Bouftou, Mehdi El Bouchti, Aicha Boukhriss, Said Gmouh, Sanaa Majid

Erschienen in: Cellulose | Ausgabe 3/2023

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Abstract

Cotton fibre dissolution has been investigated using ionic liquids having a functionalized imidazolium cation. Two ionic liquids, 3-butyric acid-1-methyl imidazolium chloride [HOOC₄MIM][Cl] (IL-acid) and 3-N,N-diethyl-butyramide-1-methyl imidazolium chloride [(Et)₂NOC₄MIM][Cl] (IL-amide), were synthesized by passing both through the intermediate 1-(3-Ethoxycarbonyl-propyl)-1-methyl imidazolium bromide. Their chemical structures were then confirmed using NMR and FTIR. 5 wt% cotton fibers have been completely dissolved in both synthesized ionic liquids in 3 h at room temperature. The regenerated cellulose with water, as an anti-solvent, was characterized using XRD, FTIR, TGA, and degree of polymerization (DP) methods. The FTIR and XRD results showed that no other chemical reaction occurred by both synthesized ILs other than the breakage of hydrogen bonds during the dissolution and regeneration processes. In addition, the regenerated cellulose had a reduced crystallinity and a structural transition from cellulose I to cellulose II. TGA results confirmed the low crystallinity of regenerated cellulose by demonstrating its low thermal stability compared to cotton fibers. Furthermore, the DP of cotton fibers was reduced from 805 ± 15 to 737 ± 12 and 765 ± 10 after regeneration from IL-acid and IL-amide, respectively, confirming partial cellulose network degradation. The IL-acid has an oily appearance and a viscosity (44 ± 5 mPa.s at 25 °C), allowing it to dissolve 14.5 wt% cotton fibers at 25 °C, IL-amide can only dissolve 5 wt% in 5 h at 25 °C due to its viscous nature. These results imply that the produced ionic liquids can be considered as competitive solvents for dissolving cellulose.

Graphical abstract

Vorheriger Artikel Increasing 3D elongation potential in fixed blank forming via fiber curlation

Nächster Artikel An efficient pathway to the elaboration of glassy amphiphilic ester based hydroxyethyl cellulose and ionic liquids

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Titel: Synthesis and application of functionalized ionic liquids-based imidazolium as solvent for cotton fibre cellulose dissolution
verfasst von: Kaoutar Aghmih
Abderrahim Bouftou
Mehdi El Bouchti
Aicha Boukhriss
Said Gmouh
Sanaa Majid
Publikationsdatum: 07.12.2022
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 3/2023
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-022-04974-z

Springer Professional

Abstract

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