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Polymer Bulletin
Erschienen in: Polymer Bulletin 9/2015

01.09.2015 | Original Paper

Synthesis and characterization of aniline and thiophene and/or alkylthiophenes polymers

verfasst von: María Angélica Pardo, María Angélica del Valle, Fernando Raúl Díaz

Erschienen in: Polymer Bulletin | Ausgabe 9/2015

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Abstract

Three new polymers, obtained by reacting thiophene or 3-alkylthiophenes as electron donors with aniline as acceptor in a donor–acceptor structure, were synthesized via oxidative polymerization using iron(III) chloride (FeCl3). The final products were characterized utilizing conventional techniques such as IR, NMR, UV–Vis spectrometry, which enabled demonstrating that an increase of the aliphatic chain length causes significant solubility increase of the system, without modifying the conductivity. On the other hand, observed an important variation of the thermal stability of the polymer when medium-length aliphatic chains were inserted was observed; in contrast, the addition of a methyl group (short chain length) hardly affected the mentioned properties.
Vorheriger Artikel Calcium sulfate precipitation studies with fluorescent-tagged scale inhibitor for cooling water systems
Nächster Artikel Curing behavior and thermal performance of cyanate ester resin modified by Poly(methyl-benzene diethynylbenzene)Siliane

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Metadaten
Titel
Synthesis and characterization of aniline and thiophene and/or alkylthiophenes polymers
verfasst von
María Angélica Pardo
María Angélica del Valle
Fernando Raúl Díaz
Publikationsdatum
01.09.2015
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 9/2015
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-015-1397-1

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